The {001} facets-dependent high photoactivity of BiOCl nanosheets

BiOCl nanosheets (BiOCl NSs) were synthesized by hydrolyzing a hierarchical flowerlike molecular precursor (Bi(n)(Tu)(x)Cl(3n), Tu = thiourea). High photoactivity of {001} facets of BiOCl NSs was observed, and the mechanism was discussed.     

Exact solutions of the generalized Dugdale model of two-dimensional decagonal quasicrystals

The basic properties of the generalized Dugdale model of quasicrystals have significance in the theory of fracture mechanics of this solids. This study suggests a conformal mapping which transforms the complicated region in physical plane onto the exterior of the unit circle in the ζ plane, then in terms of Cauchy integral theory, the complicated boundary value problem is solved, and the solutions are expressed in close form exactly. The crack tip opening displacement (CTOD), cohesive force zone and the most important physical quantity, stress intensity factor, are obtained with exact analytic form, which are useful in materials science and engineering.     

Investigation of the Effect of the In-Cylinder Tumble Motion on Cycle-to-Cycle Variations in a Direct Injection Spark Ignition (DISI) Engine Using Large Eddy Simulation (LES)

Cycle-to-cycle variations (CCVs) limit the extension of the operating range by inducing load variations and even misfire and/or knock for direct injection spark ignition (DISI) engines and hence need to be controlled. One of the effective and flexible ways to reduce CCV is to employ a charge motion control valve. This study is aimed to analyze the flow characteristics and CCV using large eddy simulation (LES) and fast Fourier transform (FFT) in a non-reacting, DISI engine equipped with a tumble flap (i.e., a specific type of charge motion control valve) inside the intake port. The in-cylinder flow characteristics are analyzed in detail, and the possible effects of multi-scale structures of the fluid field on the subsequent ignition and combustion processes are also discussed. Computational results indicate that closing the tumble flap helps enhance the intensity of the coherent structures and increase the total integral length scale (ILS) while decreasing the Kolmogorov scale and stabilizing the flow field by suppressing the CCV of tumble ratio and tumble center. Furthermore, based on a newly developed FFT triple decomposition, each instantaneous flow field is decomposed into three subfields, termed ensemble mean part and low- and high-spatial frequency parts, respectively. It is found that switching the tumble flap position greatly affects the first two subfields, but it has negligible effect on the last part. With the closed tumble flap, the energy portion of the mean part increases, the rate of energy decay reduces, and the CCV of the low- and high-spatial frequency parts decreases.     

基于多变体的控制软件异构冗余与动态重构技术研究

针对控制软件的防篡改需求,提出利用多变体技术和虚拟化技术实现软件运行态异构冗余、动态重构及多余度表决的动态目标防御方法,介绍了技术路线、系统架构、动态重构策略、表决算法和同步机制。研究结果表明,该技术在提高控制系统可靠性的同时,实现了信息安全主动防御,能够部分解决目前工控系统面临的安全问题。     

Sr6Cd2Sb6O7S10: Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups

A new nonlinear optical (NLO) oxysulfide, Sr₆Cd₂Sb₆O₇S₁₀, which contains the functional groups [SbO_xS_5?x]^7? (x=0, 1) with a 5s² electron configuration, is synthesized by a solid‐state reaction. This compound displays a phase‐matchable second harmonic generation (SHG) response four times stronger than AgGaS₂ (AGS) under laser irradiation at 2.09 μm. Single‐crystal‐based optical measurements reveal a SHG intensity that can be tuned by temperature and novel photoluminescence properties. Theoretical analyses demonstrate that tetragonal [SbOS₄]^7? and [SbS₅]^7? pyramids make the predominant contribution to the enhanced SHG effect. Among those, the [SbOS₄]^7? units with mixed anions make a larger contribution. This work proposes that oxysulfide groups with an ns² electron configuration can serve as new functional building units in NLO materials and opens a new avenue for the design of other optoelectronic materials.     

ZnO and ZnS Nanostructures: Ultraviolet-Light Emitters,Lasers, and Sensors

ZnO and ZnS, well-known direct bandgap II–VI semiconductors, are promising materials for photonic, optical, and electronic devices. Nanostructured materials have lent a leading edge to the next generation technology due to their distinguished performance and efficiency for device fabrication. As two of the most suitable materials with size- and dimensionality-dependent functional properties, wide bandgap semiconducting ZnO and ZnS nanostructures have attracted particular attention in recent years. For example, both materials have been assembled into nanometer-scale visible-light-blind ultraviolet (UV) light sensors with high sensitivity and selectivity, in addition to other applications such as field emitters and lasers. Their high-performance characteristics are particularly due to the high surface-to-volume ratios (SVR) and rationally designed surfaces. This article provides a comprehensive review of the state-of-the-art research activities in ZnO and ZnS nanostructures, including their syntheses and potential applications, with an emphasis on one-dimensional (1D) ZnO and ZnS nanostructure-based UV light emissions, lasers, and sensors. We begin with a survey of nanostructures, fundamental properties of ZnO and ZnS, and UV radiation–based applications. This is followed by detailed discussions on the recent progress of their synthesis, UV light emissions, lasers, and sensors. Additionally, developments of ZnS/ZnO composite nanostructures, including core/shell and heterostructures, are discussed and their novel optical properties are reviewed. Finally, we conclude this review with the perspectives and outlook on the future developments in this area. This review explores the possible influences of research breakthroughs of ZnO and ZnS nanostructures on the current and future applications for UV light–based lasers and sensors.     

冲击载荷下含表面裂纹圆柱壳体的动态断裂

动态载荷下含表面裂纹的有限尺寸构件的断裂问题在工程实践中有着重要意义,但由于此类问题非常复杂,目前还不能求得解析解。本文针对含轴向半椭圆盘状表面裂纹的圆柱壳体,应用有限元法研究了动态载荷下其断裂问题,计算了动态应力强度因子与静态应力强度因子的比值KdIyn(t)/KsIta。从计算结果可以得出,比值KdIyn(t)/KsIta与结构和裂纹的尺寸有关,而与冲击载荷的大小无关。本文所得结果在一定程度上揭示了圆柱壳体表面、裂纹面、物质惯性和弹性波的相互作用及其对动态断裂的影响。     

Direct determination of trace copper and chromium in silicon nitride by fluorinating electrothermal vaporization inductively coupled plasma atomic emission spectrometry with the slurry sampling technique

A method has been developed for the determination of trace impurities in silicon nitride (Si₃N₄) powders by fluorination assisted electrothermal vaporization (ETV) /ICP-AES using the slurry sampling technique. Polytetrafluoroethylene (PTFE) emulsion as a fluorinating reagent not only effectively destroys the skeleton of Si₃N₄, but also carries out selective volatilization between the impurity elements (Cu, Cr) and the matrix (Si). The experimental parameters influencing fluorination reactions were optimized. The detection limits for Cu and Cr are 1.05 ng/mL ( Cu) and 1.58 ng/mL (Cr), the RSDs are in the range of 1.9–4.2%. The proposed method has been applied to the determination of Cu and Cr in Si₃N₄ ceramic powders. The analytical results were compared with those obtained by independent methods.     

Preparative separation of rhein from Chinese traditional herb by repeated high-speed counter-current chromatography

High-speed counter-current chromatography (HSCCC) was repeatedly used for isolation and purification of rhein from Rheum officinale Baill (Dahuang) with a two-phase solvent system composed of n-hexane-ethyl acetate-methanol-water (3:7:5:5, v/v), which had been selected by analytical (HSCCC). Using two preparative units of the HSCCC centrifuge, about a 500 mg amount of the crude extract was separated, yielding 6.7 mg of rhein at a high purity of over 97%.     

Preparative isolation and purification of two isoflavones from Astragalus membranaceus Bge. var. mongholicus (Bge.) Hsiao by high-speed counter-current chromatography

Two isoflavones, calycosin-7-O-beta-D-glycoside and formononetin-7-O-beta-D-glycoside, were separated from n-butanol extract of the root of Astragalus membranaceus Bge. var. mongholicus (Bge.) Hsiao by high-speed counter-current chromatography in two steps using two different solvent systems composed of ethyl acetate-ethanol-n-butanol-water (30:10:6:50, v/v) and ethyl acetate-ethanol-water (5:1:5, v/v). From 200 mg of crude extract, calycosin-7-O-beta-D-glycoside (12 mg) and formononetin-7-O-beta-D-glycoside (10 mg) were isolated at over 95% purity by HPLC analyses, and their structures were identified by MS, 1H NMR and 13C NMR.