圆盘状裂纹前缘塑性区尺寸及张开位移估计

将Ｄｕｇｄａｌｅ模型推广到三维裂纹问题计算了圆盘状裂纹前缘塑性区尺寸,并结合断裂力学中的Ｂａｒｅｎｂｌａｔｔ－Ｄｕｇｄａｌｅ裂纹模型和三维Ｊ－积分原理计算了圆盘状裂纹前缘张开位移,得到了Ｊ－积分与裂纹张开位移的关系,最后用非线性有限元方法对圆盘状裂纹的前缘塑性区尺寸作了数值分析,确定了公式中的未知常数,并对其正确性作了数值验证,本文的工作推广了Ｄｕｇｄａｌｅ模型的应用范围。     

Carbon-assisted morphological manipulation of CdS nanostructures and their cathodoluminescence properties

CdS nanostructures with different morphologies and sizes were successfully fabricated through a facile and effective carbon-assisted thermal evaporation method. Through simply changing the positions of silicon substrates, the temperatures and the effects of carbon in different zones were modified, and thus the morphologies of CdS nanostructures were varied from multipods to nanobrushes to nanocups. These nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectrometry (EDS), X-ray powder diffraction (XRD) and Raman spectroscopy. Cathodoluminescence (CL) measurement shows that the as-grown CdS nanostructures display different luminescent properties. CdS multipods and nanocups show mainly green emission centered at 496 nm. However, nanobrushes exhibit predominant red emission band peaking at 711 nm. These interesting results show that carbon not only affected the growth process but also influenced the properties of CdS nanostructures.     

准晶数学弹性理论和某些有关研究的进展(下)

本文对固体准晶力学性能和准晶数学弹性, 塑性, 断裂以及有关研究的进展作了评论, 尤其对材料常数和塑性变形行为的测量, 一维、二维、三维准晶弹性理论, 动力学、非线性、缺陷理论、准晶弹性新型偏微分方程的推导和精确分析解, 复分析方法, 变分原理和有限元方法, 有限差分方法这些宏观问题和它们的数学方法进行了分析, 同时对准晶晶格动力学问题的数学理论也作了初步讨论. 近来在软物质中发现了12 次和18次对称准晶, 意义重大, 这里也做了初步介绍. 文中重点讨论此领域最近这些年来中国科学工作者的工作.     

纳米级稠化剂颗粒沉积膜在乏脂润滑中的作用机制研究

利用双光束干涉法对点接触区乏脂润滑成膜特性规律以及接触区附近润滑剂的微观迁移特性进行了观测.在试验条件下,接触区会经历充分润滑—乏脂—沉积膜润滑—分离油润滑等润滑状态.借助原子力显微镜,探测到沉积膜是润滑脂的稠化剂被碾压破碎而沉积在滚压轨道表面的一层纳米级颗粒薄膜;而分离油是在剪切过程中润滑脂内逐渐释放基础油.试验初始,接触区周围的润滑脂池因乏脂而迅速消失,但分离油会逐渐形成"第二相油池"以实现回流补给.沉积膜增大了基础油在滚动轨道表面的接触角,阻碍回流补给,但其会随运动逐渐磨损,此后分离油将进入接触区补充润滑膜.初步发现,当分离油不充足时,沉积膜有利于保护润滑轨道.     

Evaluation of force implementation in pseudopotential-based multiphase lattice Boltzmann models

The Lattice Boltzmann method (LBM) has proven to be a promising approach in handling multiphase flow problems. In the most widely applied pseudopotential-based LBM multiphase models, multiphase effects can be added in the form of forces, which is further divided into two aspects of force incorporation scheme and force expression. However, the effect of both aspects on coexistence densities and spurious current has not been evaluated systematically. In this paper, Modified Yuan-type and Zhang-type force expressions are chosen, and then they are incorporated into the lattice Boltzmann equation by the Shan–Chen and exact difference method force incorporation scheme to recover the Carnahan–Starling equation of state (EOS) with an additional surface tension term. Based on the computational results of two phases coexisting at a steady state, it can be observed that the force incorporation scheme affects the coexistence densities implicitly with different relaxation times and does not lead to a large difference in values. Force expression is found to greatly affect the achievable highest density ratio, of which the discrete gradient operator of the pseudopotential plays a crucial role. Spurious current is observed to be related to both the force expression and force incorporation scheme, and in our simulation a different force incorporation scheme brings about a large difference. Moreover, our modification on Yuan-type force expression not only improves the accuracy in capturing coexistence densities at low temperatures, but also provides the possibility of tuning the density ratio and surface tension independently at high density ratios.     

Facile fabrication of polymer nanocapsules with cross-linked organic-inorganic hybrid walls

A facile method was developed for the fabrication of polymer nanocapsules with organic-inorganic hybrid walls and controllable morphologies from a cross-linkable polymer, poly[3-(trimethoxysilyl)propyl methacrylate] (PTMSPMA). With the combination of emulsion, hydrolysis, and condensation reaction as well as the internal phase separation, cross-linked PTMSPMA nanocapsules with classic hollow structures, collapsed hollow structures with Kippah, and multi-fold morphologies could be successfully obtained by simply mixing the toluene solution of PTMSPMA with water under vigorous stirring for 48 h at different temperatures. The hydrolysis and condensation of methoxysilyl groups resulted in the phase separation of PTMSPMA inside the toluene droplets and the migration of PTMSPMA to the interface of toluene and water. The cross-linking reaction of methoxysilyl groups further fixed the interfacial phase of PTMSPMA, leading the formation of PTMSPMA nanocapsules with robust cross-linked organic-inorganic hybrid walls. Such nanocapsules with robust cross-linking structures may find potential applications for the encapsulations of many functional species.     

Study of the adsorption behavior ¶of heavy metal ions on nanometer-size ¶titanium dioxide with ICP-AES

A new method using nanoparticle TiO₂ as solid-phase extractant coupled with ICP-AES was proposed for simultaneous determination of trace elements. The adsorption behavior of nanometer TiO₂ towards Cu, Cr, Mn and Ni was investigated by ICP-AES, and the adsorption pH curves, adsorption isotherms and adsorption capacities were obtained. It was found that the adsorption rates of the metal ions studied were more than 90% in pH 8.0～9.0, and 2.0 mol L^–1 HCl was sufficient for complete elution. Nanometer TiO₂ possesses a significant capacity for the sorption of the metal ions studied which is higher than the capacity of silica, the commonly used extractant. The method has been applied to the analysis of some environmental samples with satisfactory results.     

In-situ separation of chromium(III) and chromium(VI) and sequential ETV–ICP–AES determination using acetylacetone and PTFE as chemical modifiers

Electrothermal vaporization–inductively coupled plasma–atomic emission spectrometry (ETV–ICP– ES) has been used for the sequential determination of Cr(III) and Cr(VI). The method is based on the difference between the chelate reactions of the two Cr species and acetylacetone. Cr(III) chelate was separated from Cr(VI) and determined with use of acetylacetone as chemical modifier. The retained Cr(VI) in graphite tube was analyzed subsequently, after addition of polytetrafluoroethylene (PTFE) as chemical modifier. The different factors affecting the vaporization behavior of Cr(III) acetylacetonate were investigated in detail. The detection limits for Cr (III) and Cr(VI) were 0.56 and 1.4 ng mL^–1, respectively, and relative standard deviations for 0.1 μg mL^–1 Cr(III) and 0.1 μg mL^–1 Cr(VI) were 2.5% (n = 6) and 4.8% (n = 6), respectively. The linear ranges of the calibration curve for both Cr(III) and Cr(VI) covered three orders of magnitude. The proposed method was used to analyze water samples with satisfactory results.     

The effects of relative density of metal foams on the stresses and deformation of beam under bending

The exact analytic solution of the pure bending beam of metallic foams is given. The effects of relative density of the material on stresses and deformation are revealed with the Triantafillou and Gibson constitutive law (TG model) taken as the analysis basis. Several examples for individual foams are discussed, showing the importance of compressibility of the cellular materials. One of the objects of this study is to generalize Hill’s solution for incompressible plasticity to the case of compressible plasticity, and a kinematics parameter is brought into the analysis so that the velocity field can be determined. The English text was polished by Yunming Chen.     

Water Status and Predictive Models of Moisture Content during Drying of Soybean Dregs Based on LF-NMR

To explore the drying characteristics of soybean dregs and a nondestructive moisture content test method, in this study, soybean dregs were dried with hot air (80 °C), the moisture content was measured using the drying method, water status was analyzed using low-field nuclear magnetic resonance (LF-NMR) and the moisture content prediction models were built and validated. The results revealed that the moisture contents of the soybean dregs were 0.57 and 0.01 g/g(w.b.), respectively, after drying for 5 and 7 h. The effective moisture diffusivity increased with the decrease in moisture content; it ranged from 5.27 × 10⁻⁹ to 6.96 × 10⁻⁸ m²·s⁻¹. Soybean dregs contained bound water (T₂₁), immobilized water (T₂₂) and free water (T₂₃ and T₂₃’). With the proceeding of drying, all of the relaxation peaks shifted left until a new peak (T₂₃’) appeared; then, the structure of soybean dregs changed, and the relaxation peaks reformed, and the peak shifted left again. The peak area may predict the moisture content of soybean dregs, and the gray values of images predict the moisture contents mainly composed of free water or immobilized water. The results may provide a reference for drying of soybean dregs and a new moisture detection method.