特殊半鞅的一个局部性质

本文讨论特殊半鞅的一个局部性质,将局部（平方可积）鞅的结果推广到了一类特殊半鞅的情形。     

小角度纵波水浸超声检测技术在消除锻件结构盲区中的应用

航空发动机中的后轴颈锻件一般采用水浸超声纵波直入射方法检测内部缺陷。由于型面结构的问题,在锻件的直筒和锥形段连接区域存在检测盲区。该文针对某型号发动机中的后轴颈锻件,开展了水浸超声检测工艺研究,提出利用小角度纵波覆盖盲区的思路。通过对含有人工缺陷的模拟样件的检测实验,比较了水浸纵波直入射和小角度纵波斜入射两种检测方法对后轴颈连接区域的覆盖能力。结果表明,该文提出的小角度纵波方法,可以有效检测出水浸纵波直入射检测方法无法发现的人工缺陷,消除由结构引起的检测盲区,保障零件的服役安全。     

环境质量评价热力学方法探讨

对理想气体或理想溶液有:■实际分析中有 X(大气)→1,■考虑评价的任一组分有 E_p=RT■,E_p 取决于 X■的选定和 X_p 环境监测值的大小,以此为基础进行环境质量评价方法探讨.     

KCaA型分子筛制备及其对CO2吸附性能的研究

采用离子交换法,在CaA型分子筛中加入氯化钾水溶液,并搅拌一定时间,将功能K+引入到CaA型分子筛结构中,以调控CaA型分子筛的孔径和增加它的吸附活性位点.考察了离子交换时间和气体吸附压力等条件对制备的KCaA型分子筛的结构、形貌和CO2吸附性能的影响.通过X射线衍射、扫描电子显微镜和CO2吸附等温线等表征手段,结果发现:获得的KCaA型分子筛具有与CaA型分子筛相同的结构与形貌;增大气体吸附压力,分子筛对CO2的吸附量增大;但随着离子交换时间的增长,分子筛对CO2的吸附能力先增大后减小;在室温及1bar气压下对CO2气体的吸附性能比原CaA型分子筛提高了26.7%.     

Measuring the optical parameters of thin films by p-polarized laser beams

The refractive index n_f, extinction coefficient k_f and thickness d_f of a dip coated film are measured by using p-polarized laser beams. A sample is oblique illuminated with a p-polarized laser beam, and then two reflected beams, from the front and back surfaces, are received with a detector. After measuring their intensity ratio versus the angle of incidence, it is convenient to obtain the parameters of the film by means of data fitting. The films of polymethyltriethoxy silane (PMTES), which were made on a BK-7 glass substrate by dip coating, were measured. The method is non-contact, non-destructive and has the advantages of simplicity of both equipment and understanding. It is also shown that the values measured by this method are coincident with those measured by ellipsometry.     

Controllable synthesis of high aspect ratio Mg_2B_2O_5 nanowires and their applications in reinforced polyhydroxyalkanoate composites

Highly pure magnesium borate （Mg2B2O5） nanowires with an average diameter of - 30 nm, an average length of 15 μm, and a high aspect ratio of - 500 have been synthesized on a large scale via a two-step method. MgBO2（OH） nanowires with high aspect ratios were first prepared via a PVP-assisted hydrothermal technique. Using these nanowires as precursors, single crystalline Mg2B205 nanowires were synthesized by post-annealing treatment at a relatively low temperature of 700 ℃. The important effect of the MgBO2（OH）-Mg2B2O5 conversion process on the morphology of the Mg2B2O5 nanowires was investigated and it was indicated that the recrystallization process plays an important role in the protection of the one-dimensional （1D） nanostructure. Moreover, the rigidity and the toughness of the Mg2B2O5 nanowire- reinforced PHA composites were tremendously improved compared to those of the pure PHA. Our results demonstrate the effectiveness of Mg2B2O5 nanowires for reinforcement applications in polymer composites.     

Nonequilibrium thermodynamics and fluctuation relations for small systems

In this review, we give a retrospect of the recent progress in nonequilibrium statistical mechanics and thermodynamics in small dynamical systems. For systems with only a few number of particles, fluctuations and nonlinearity become significant and contribute to the nonequilibrium behaviors of the systems, hence the statistical properties and thermodynamics should be carefully studied. We review recent developments of this topic by starting from the Gallavotti–Cohen fluctuation theorem, and then to the Evans–Searles transient fluctuation theorem, Jarzynski free-energy equality, and the Crooks fluctuation relation. We also investigate the nonequilibrium free energy theorem for trajectories involving changes of the heat bath temperature and propose a generalized free-energy relation. It should be noticed that the non-Markovian property of the heat bath may lead to the violation of the free-energy relation.     

谐振式集成光学陀螺解调特性分析

基于激光器频率谱检测技术,沿着光的传输方向分析了光波在谐振式集成光学陀螺系统中的传播,结合输入信号特征,建立频域内的数学模型,通过数值仿真和实验得到了调频检测系统下的解调曲线。按照光的传输方向：激光器、声光晶体移频器、光波导环形谐振器、探测器,利用贝塞尔函数展开和光场耦合模理论分析了谐振式集成光学陀螺解调特性,及其调频调制检测系统解调输出信号与谐振频率偏差之间的关系。通过数值计算,分析了解调曲线的变化规律,得到了施加在激光器压电陶瓷驱动器上调制波形的最佳调制系数。在实验上搭建了激光器频率调制解调技术系统,得到了解调曲线。数值仿真和实验结果表明,当调制系数M=2时,线性工作区间斜率最大,解调曲线最好。实测形状与理论分析结果相符,从解调信号得到±2×10³ rad/s的陀螺动态范围。     

亚10 μm线宽的投影光刻物镜设计及其成像性能的实验测定

 采用Zemax软件设计出6镜片、数值孔径为0.06、2倍缩小、以405 nm半导体激光器为光源、分辨精度达5 μm、视场12 mm×12 mm 内波像差小于1/4波长、畸变小于0.005%的双远心投影光刻物镜的设计方法。将设计的物镜实物化,并对其光学传递函数(MTF)作精确的实验测定,利用所提出的MTF标准实验测量法,得到该投影物镜的成像性能达亚10 μm线宽。     

Surface-enhanced Raman scattering of 4-mercaptobenzoic acid and hemoglobin adsorbed on self-assembled Ag monolayer films with different shapes

Polyvinylpyrrolidone (PVP)-protected silver nanostructures of various shapes, including nanocubes, nanospheres, and hybrid shapes with nanospheres and nanorods, on the surface of glass or Si substrates (PVP-Ag films) are prepared by using electrostatic self-assembly. With 4-mercaptobenzoic acid (4-MBA) as a probe molecule, it is demonstrated that the PVP-protected silver nanocubes films (PVP-Ag NCs) have better surface-enhanced Raman scattering (SERS) activity with an order of magnitude larger enhancement factors (EF) than the PVP-protected silver nanospheres films and the PVP-protected silver hybrid shapes films, which is confirmed by our numerical simulations. The EF of 4-MBA on the PVP-Ag NCs film are up to ~5.38 × 10⁶, and the detection limit is at least down to ~10^?8 M. The uniformity and reproducibility of the SERS signals on PVP-Ag NCs film are tested by point-to-point and batch-to-batch measurements. Meanwhile, the PVP-Ag films are also shown to be an excellent SERS substrate with good biocompatibility for hemoglobin detection. It is shown that the PVP-Ag NCs films can be used as excellent SERS substrate with good activity, uniformity, reproducibility, and biocompatibility and are promising for a myriad of chemical and biochemical sensing applications.