全文获取类型
收费全文 | 15044篇 |
免费 | 2316篇 |
国内免费 | 2431篇 |
专业分类
化学 | 10827篇 |
晶体学 | 218篇 |
力学 | 900篇 |
综合类 | 235篇 |
数学 | 1982篇 |
物理学 | 5629篇 |
出版年
2024年 | 32篇 |
2023年 | 177篇 |
2022年 | 366篇 |
2021年 | 435篇 |
2020年 | 452篇 |
2019年 | 526篇 |
2018年 | 473篇 |
2017年 | 471篇 |
2016年 | 690篇 |
2015年 | 736篇 |
2014年 | 945篇 |
2013年 | 1149篇 |
2012年 | 1207篇 |
2011年 | 1350篇 |
2010年 | 1072篇 |
2009年 | 1113篇 |
2008年 | 1205篇 |
2007年 | 1089篇 |
2006年 | 1045篇 |
2005年 | 920篇 |
2004年 | 736篇 |
2003年 | 594篇 |
2002年 | 728篇 |
2001年 | 514篇 |
2000年 | 429篇 |
1999年 | 295篇 |
1998年 | 200篇 |
1997年 | 144篇 |
1996年 | 130篇 |
1995年 | 88篇 |
1994年 | 79篇 |
1993年 | 63篇 |
1992年 | 58篇 |
1991年 | 48篇 |
1990年 | 38篇 |
1989年 | 41篇 |
1988年 | 36篇 |
1987年 | 20篇 |
1986年 | 16篇 |
1985年 | 18篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 14篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1974年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
YongJIANG PengFeiTU 《中国化学快报》2002,13(4):335-336
Two new xanthone glycosides,polygalaxanthone IV and V were isolated from the roots of Polygala tenuifolia Willd. Their structures were established as 6-O-[α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl]-1-hydroxy-3,7-dimethoxyxanthone(polygalaxanthone IV), and 6-O-[α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl]-1,3-dihydroxyl-7-methoxyxanthone (polyga-laxanthone V),respectively, on the basis of chemical and spectral evidence. 相似文献
102.
103.
An improved method for constructing a full-length enriched cDNA library using small amounts of total RNA as a starting material 总被引:1,自引:0,他引:1
We have developed an improved method for constructing a full-length cDNA library using small quantity of material by modifying the original oligo-capping method. In our devised method, total RNAs are used in sequential oligo-capping steps directly without preliminary mRNA purification. Using this method, we constructed full- length cDNA libraries from 100 mg of total RNA. These libraries contained 8x10(5) to 8x10(6) independent clones with average insert sizes of 2.0 kb. Moreover, the number of full-length cDNAs containing the translation initiation codon ATG in the constructed libraries was estimated to 60-70%. In addition, 54% of the known cDNAs had a longer 5' end than the corresponding genes in the public database. Our results show that the method can be effectively used to construct full-length enriched cDNA libraries, especially, if starting material is limited. 相似文献
104.
XiaoXiaWANG YongMinZHANG 《中国化学快报》2002,13(6):499-500
The α,β vicinal dibrome carboxylic acid and its derivatives were debrominated with Sm/HOAc system to afford the corresponding cinnamic acid and its derivatives in good yields under mild conditions. 相似文献
105.
Lysophosphatidic acid (LPA, 1- or 2-acyl-sn-glycerol 3-phosphate) is an important phospholipid mediator produced by activated platelets and by ovarian cancer cells. Efforts to understand LPA signaling through G-protein-coupled receptors are hampered by the facile acyl migration that results in equilibration to a mixture of the 1- or 2-acyl species under physiological conditions. We describe a new and efficient route to enantiomerically homogeneous lysophospholipid analogues from D-mannitol 1,2:5,6-bis-acetonide to give two 1,1-difluorodeoxy analogues of (2R)-acyl-sn-glycerol 3-phosphate. These compounds are migration-blocked analogues of the labile sn-2 LPA species. The (19)F NMR of diastereotopic fluorines of the difluoromethyl group shows an unexpected solvent dependence. 相似文献
106.
GuoXiangCHENG GuangLingPEI LingGangZENG LiYongZHANG ChaoLIU 《中国化学快报》2004,15(2):242-245
In this paper, the surface imprinted cross-linked polystyrene beads were prepared via suspension polymerization with styrene (St), divinylbezene (DVB), polyvinyl alcohol (PVA1788),the mixture of Span 85 and xylene or the mixture of Span 85 and paraffin as monomer,cross-linking agent, dispersion stabilizer and templates, respectively. The results indicate that there are dense cavities on the surface of beads, and the diameter and density of cavity are related with the composition and amount of emulsion template. The forming mechanism of cavity from thermodynamics and dynamics was proposed. 相似文献
107.
Xiangfu Zhang Fei XieZhonglin Pen Yong ZhangYinxi Zhang Wen Zhou 《European Polymer Journal》2002,38(1):1-6
The effect of the sorbital nucleating agent on properties of the ethylene-octene copolymer (POE) toughened polypropylene (PP) was studied. The results show that the addition of POE increases notched Izod and Charpy impact strength significantly but impair the tensile strength and flexural modulus. As a nucleating agent (1,3,2,4-di(p-methylbenzylidene) sorbitol, DM) was added, the toughness and stiffness of toughed PP increased simultaneously at the same content of POE. This result shows that the toughness and stiffness of toughed PP are in balance. Polarized light microscopy analysis shows that with the addition of POE and nucleating agent, only a low level of PP spherulites were observed. 相似文献
108.
加速剂对化学镀镍层组成与结构的影响 总被引:3,自引:0,他引:3
加速剂对化学镀镍层组成与结构的影响方景礼,武勇,韩克平,张敏(南京大学应用化学研究所配位化学国家重点实验室南京210093)关键词化学镀镍,Ni0P合金,加速剂,硫脲化学镀镍磷合金具有耐蚀性、可焊性、厚度均匀和硬度高等优点,已得到广泛应用。为提高生产... 相似文献
109.
110.
高效液相色谱法测定橡胶促进剂TBBS 总被引:3,自引:0,他引:3
采用反相高效液相色谱法(HPLC)测定了橡胶促进剂N-叔丁基-2-苯并噻唑次磺酰胺(TBBS)的纯度,标准偏差小于0.3。 相似文献