单晶SiNd：YAG激光连续退火的数值计算

应用固相外延模型来模拟单晶Si的连续Nd：YAG激光退火过程,在低功率密度连续激光退火下,用准静态模型模拟辐照区向非辐照区的径向传导散热。在数值计算中，应用部分线性法处理非线性非齐次热传导方程,得到相应的隐格式差分方程，再用追赶法求解隐格式差分方程,得出绝热边界条件下的温度的时间和空间分布，从而得出激光退火的再结晶厚度。当激光波长λ=1．06μm、功率密度io=700W／cm^2。预热温度T0=523K时，经过0．7秒，表面温度度升到1290K左右，再结晶厚度约为0．5μm。     

Asymptotic behavior of vortices in axisymmetric flow without swirl

We investigate the confinement properties of bounded, nonnegative, compactly supported vortices of axisymmetric incompressible Euler flows without swirl. We show that along one direction of the symmetry axis, its support can grow no faster than O[(t log t)^1/2]. The rate at which it approaches the symmetry axis is also estimated. Together with the result of Maffei–Marchioro on the radial growth rate of the support, it is contained in a slowly expanding tubular region. The techniques of the above‐mentioned authors, Iftimie–Lopes–Nussenzveig and Iftimie–Sideris–Gamblin, are used. Copyright © 2008 John Wiley & Sons, Ltd.     

New chiral ionic liquids based on imidazolinium salts

The preparation and application of a new series of chiral ionic liquids are described. The salts are based on imidazolinium cations. Some of the cations also incorporated an axial chirality at the C(2) position next to the central chirality. These cations display a very high rotational barrier along the arene–imidazolinium axis. Furthermore, an analogue with a chiral anion was prepared. The salts have low melting points. Their potential as solvents and as chiral shift reagents was explored, resulting for the first time in an example of a chiral ionic liquid as a shift reagent for a neutral compound.     

PPY催化合成乙酸沉香酯

利用吡啶与二氯亚砜反应 ,制成双吡啶盐 ,进而与四氢吡咯反应 ,一步法合成 4 ( 1 四氢吡咯 )吡啶(PPY)。利用PPY为催化剂进行沉香醇的酰化反应 ,并对影响反应的诸因素进行了讨论 ,醇的转化率为 99% ,酯的收率为 88.2 %。     

An X‐shaped π‐conjugated polymer comprising of fluorene units and anthracene units with high efficiency. Synthesis and optical and electrochemical properties

A new X‐shaped π‐conjugated monomer comprising of fluorene units and anthracene units was synthesized, and it was used to fabricate the new X‐shaped π‐conjugated polymers and investigate the properties of the new polymers. Using different molar ratios between such monomer and a fluorene monomer gave three polymers that showed higher absolute PL quantum yields than the linear polyfluorene (PF) in the solid state. After thermal annealing at 200 °C for 4 h, the linear PF showed an additional bathochromic emission at about 550 nm, whereas such red‐shifted emission was fully eliminated for the X‐shaped polymers. The electroluminescent devices based on the X‐shaped polymers with a configuration of ITO/PEDOT:PSS/polymer/LiF/Ca/Al displayed blue emission with low turn‐on voltage and high brightness. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5616–5625, 2008     

相对平坦模的$\aleph$-积

设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中$0\leq A相似文献   

The steady Navier–Stokes/energy system with temperature‐dependent viscosity—Part 1: Analysis of the continuous problem

In this first part we propose and analyse a model for the study of two‐dimensional incompressible Navier–Stokes equations with a temperature‐dependent viscosity. The flow is supposed in a mixed convection regime and considers an outflow region, leading to a strongly coupled problem between the Navier–Stokes and energy equations, which will be justified theoretically. The coupling in the continuous problem is treated by an outer temperature fixed point strategy. Existence results for a particular variational formulation follows from this study. Further, a particular uniqueness result for small data is also obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

Ytterbium triflate hydrate catalyzed Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds

Catalyzed by ytterbium(Ⅲ) triflate hydrate [Yb(OTf)3.xH2O], the Michael addition and cycloeondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied.