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131.
Yongcheng Liu Xin Chen Jianghong Qian Haiying Liu Zhengzhong Shao Jiaqi Deng Tongyin Yu 《Applied biochemistry and biotechnology》1997,62(2-3):105-117
The structure and properties of the blend of regenerated silk fibroin (RSF) and poly(vinyl alcohol) (PVA) were investigated.
The two polymers in the blend are in the state of phase segregation. Infrared (IR) spectra indicate that the RSF in the blend
maintains its intrinsic properties, thus, ethanol treatment can transfer silk I structure of RSF to silk II structure. The
water absorption property and mechanical property of the blend are improved in comparison with those of RSF. The blend maintains
the major merit of RSF, that is, it can immobilize glucose oxidase on the basis of the conformational transition from silk
I structure to silk II structure. The properties of the immobilized enzyme are examined. Moreover, the second generation of
glucose sensor based on the immobilized enzyme is fabricated and it has a variety of advantages including easy maintenance
of enzyme, simplicity of construction, fast response time and high stability. 相似文献
132.
Hui CY Tang T Lin YY Chaudhury MK 《Langmuir : the ACS journal of surfaces and colloids》2004,20(14):6052-6064
A new cohesive zone model is developed in order to study the mechanisms of adhesive and cohesive failures of soft rubbery materials. The fracture energy is estimated here using a strategy similar to that of Lake and Thomas (LT) by considering the dissipation of stored elastic energy followed by the extension and relaxation of polymer chains. The current model, however, departs from that of LT in that the force needed to break an interfacial bond does not have a fixed value; instead, it depends on the thermal state of the system and the rate at which the force is transmitted to the bond. While the force required to rupture a chain is set by the rules of thermomechanically activated bond dissociation kinetics, extension of a polymer chain is modeled within both the linear and nonlinear models of chain elasticity. Closed form asymptotic solutions are obtained for the dependence of crack propagation speed on the energy release rate, which are valid in two regimes: (I) slow crack velocity or short relaxation time for bond dissociation; (II) fast crack velocity or long relaxation time for bond dissociation. The rate independent and the zero temperature limit of this theory correctly reduces to the fracture model of LT. Detailed comparisons are made with a previous work by Chaudhury et al. which carried out an approximate analysis of the same problem. 相似文献
133.
A new isocoumarin, 3-acetyl-3,4-dihydro-5,6-dimethoxy-1H-2-benzopyran-1-one, was isolated from the cortex of Phellodendron chinense schneid. The structure was determined on the basis of spectroscopic evidences. 相似文献
134.
Xu-Chun Wang Jian-Feng Li He-Ping Chen Jie-Ying Wu Hong-Ping Zhou Jia-Xiang Yang Bao-Kang Jin Yu-Peng Tian 《Transition Metal Chemistry》2007,32(5):551-557
The novel compound, 3-(E)-ferrocenyl-vinyl-N-hexylcarbazole (FVHC) was first synthesized and fully characterized by elemental analysis, IR, 1H-NMR, single-crystal X-ray diffraction, ultraviolet (UV) absorption, cyclic voltammograms (CV) and optical limiting (OL)
measurements. The result of single crystal X-ray diffraction for the compound reveals that the ferrocenyl and carbazole groups
are approximately coplanar, and bridged by double-bond with E configuration, showing that there is a well-delocalized π-electron
system in the molecule. The electrochemical investigation indicated that the electron in the FVHC may partially be delocalized
over the π-conjugated system and CT process in functionalized carbazole systems. Besides, the compound exhibited strong UV
absorption and large optical limiting effect, indicating promising potential applications as useful OL materials. 相似文献
135.
Staphylionosides A-K: megastigmane glucosides from the leaves of Staphylea bumalda DC 总被引:1,自引:0,他引:1
Chemical investigation of leaves of Staphylea bumalda DC., collected in the suburbs of Hiroshima City, afforded 11 new megastigmane glucosides, named staphylionosides A-K (3-13), along with two known megastigmane glucosides (1, 2). The relative structures were elucidated from spectroscopic evidence, and the absolute structures of the aglycones were determined by means of the combination of beta-D-glucosylation-induced shift-trends and the modified Mosher's method. 相似文献
136.
Two kinds of thio-heterocyclic fused naphthalene carboxamides, 3a-b, 4a-b, were designed, synthesized and quantitatively evaluated as efficient antitumor and DNA photocleaving agents. Compound 3a or 3b, having the thiophene ring, intercalated into DNA more strongly than compound 4a or 4b, having the thioxanthene ring. Compound 4a or 4b, photocleaved DNA more efficiently than 3a or 3b via superoxide anion. Compound 4a was the strongest inhibitor for P388 (murine leukemia cell), while 3a was the most cytotoxic one against A549 (human lung cancer cell). Each new compound showed stronger DNA photocleaving activity than corresponding naphthalimide. 相似文献
137.
138.
本文报道新的Tweezer(1)的合成,用^1HNMR研究了新的Tweezer分子和对硝基苯甲酸盐的配位效应,结果表明它兴通过氢键,静电引力和芳环夹心堆叠作用而自动缔合。 相似文献
139.
Yoshimitsu H Nishida M Qian ZZ Lei ZH Nohara T 《Chemical & pharmaceutical bulletin》2000,48(6):828-831
Four new triterpene glycosides were isolated from the dried aerial parts of Thalictrum squarrosum (Ranunculaceae). They were designated as squarroside I, being a cycloartane-type glycoside, and squarrosides II, III and IV, being oleanene-type glycosides. Their structures were established by using two dimensional (2D) NMR techniques. 相似文献
140.
The hydrothermal reaction of VOSO4, As2O5, piperazine and H2O produces [H2N(CH2)4NH2]4[β‐As8V14O42(SO4)]·2HSO4 ( 1 ), which is the first arsenic‐vanadium cluster containing a spherical β‐As8V14O42 shell. The structure of this compound was characterized by single crystal X‐ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1 : Orthorhombic, Cmcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å3, Z = 4. 相似文献