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排序方式: 共有359条查询结果,搜索用时 15 毫秒
51.
Nilo Zanatta Deise M. Borchhardt Darlene C. Flores Helena S. Coelho Tiago M. Marchi Alex F. C. Flores Helio G. Bonacorso Marcos A. P. Martins 《Journal of heterocyclic chemistry》2008,45(2):335-341
This paper describes the synthesis and characterization of a new series of 4‐substituted‐3‐ethoxycarbonyl‐6‐trifluoromethyl‐(1,2,3)‐oxathiazinane‐S‐oxides and 3‐(4,6‐diphenyl‐pyrimidin‐2‐yl)‐6‐trifluoromethyl‐(1,2,3)oxathiazinane‐S‐oxides from the cyclization reaction of 4,4,4‐trifluoro‐3‐hydroxybutylcarbamates and 4‐(4,6‐diphenyl‐pyrimidin‐2‐ylamino)‐1,1,1‐trifluoro‐butan‐2‐ols with thionyl chloride. The analysis of the NMR data allowed us to define important features of the molecular structure. Significant chemical and structural differences were observed between the trifluoromethylated oxathiazinanes obtained in this work from other analogue compounds reported in the literature. 相似文献
52.
Dr. Yanira Méndez Dr. Aldrin V. Vasco Galway Ivey Ana Laura Dias Dr. Peter Gierth Bárbara B. Sousa Dr. Claudio D. Navo Angel Torres-Mozas Dr. Tiago Rodrigues Dr. Gonzalo Jiménez-Osés Prof. Gonçalo J. L. Bernardes 《Angewandte Chemie (International ed. in English)》2023,62(44):e202311186
Multicomponent reactions are of utmost importance at generating a unique, wide, and complex chemical space. Herein we describe a novel multicomponent approach based on the combination of the isonitrile-tetrazine (4+1) cycloaddition and the Ugi four-component reaction to generate pyrazole amide derivatives. The scope of the reaction as well as mechanistic insights governing the 4H-pyrazol-4-imine tautomerization are provided. This multicomponent process provides access to a new chemical space of pyrazole amide derivatives and offers a tool for peptide modification and stapling. 相似文献
53.
Quantum control spectroscopy (QCS) is used as a tool to study, address selectively and enhance vibrational wavepacket motion in large solvated molecules. By contrasting the application of Fourier-limited and phase-modulated excitation on different electronic states, the interplay between the controllability of vibrational coherence and electronic resonance is revealed. We contrast control on electronic ground and excited state by introducing an additional pump beam prior to a DFWM-sequence (Pump-DFWM). Via phase modulation of this initial pump pulse, coherent control is extended to structural evolution on the vibrationally hot ground state (hot-S0) and lowest lying excited state (S1) of β-carotene. In an open loop setup, the control scenarios for these different electronic states are compared in their effectiveness and mechanism. 相似文献
54.
Stefan Bode Claudia C. Quentmeier Pen-Nan Liao Tiago Barros Peter J. Walla 《Chemical physics letters》2008,450(4-6):379-385
The Car S1 → Chl energy transfer efficiency, ΦTransfer, in xanthophyll-cycle mutants of living plants and LHC II was investigated by selective Car S1 two-photon excitation. Before high-light illumination ΦTransfer, of the violaxanthin deficient mutant npq2 is 30% smaller than the corresponding value for wild type plants. For the zeaxanthin deficient mutant, npq1, ΦTransfer is 30% larger. Wild type Arabidopsis thaliana is the only variant which is capable of a light-dependent decrease of up to 40% and complete recovery to the original ΦTransfer values. In contrast, ΦTransfer remains constant during dark adaptation in both mutants. Surprisingly, changes in ΦTransfer of LHC II preparations were less than 5% only, when substituting violaxanthin by zeaxanthin. 相似文献
55.
Back Cover: Imaging Glycosylation In Vivo by Metabolic Labeling and Magnetic Resonance Imaging (Angew. Chem. Int. Ed. 4/2016) 下载免费PDF全文
Dr. André A. Neves Dr. Yéléna A. Wainman Dr. Alan Wright Dr. Mikko I. Kettunen Dr. Tiago B. Rodrigues Sarah McGuire Dr. De‐En Hu Flaviu Bulat Dr. Simonetta Geninatti Crich Dr. Henning Stöckmann Dr. Finian J. Leeper Prof. Kevin M. Brindle 《Angewandte Chemie (International ed. in English)》2016,55(4):1566-1566
56.
57.
Tiago Carvalho Marco Antônio Teixeira Durval José Tonon 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(2):31
The paper deals with the analysis of the behavior of a nonsmooth three-dimensional vector field around a typal singularity. We focus on a class of generic one-parameter families \({Z_{\lambda}}\) of Filippov systems and address the persistence problem for the asymptotic stability when the parameter varies near the bifurcation value \({\lambda = 0}\). 相似文献
58.
In this work we show that if is a linear differential operator of order ν with smooth complex coefficients in from a complex vector space E to a complex vector space F, the Sobolev a priori estimate holds locally at any point if and only if is elliptic and the constant coefficient homogeneous operator is canceling in the sense of Van Schaftingen for every which means that Here is the homogeneous part of order ν of and is the principal symbol of . This result implies and unifies the proofs of several estimates for complexes and pseudo‐complexes of operators of order one or higher proved recently by other methods as well as it extends —in the local setup— the characterization of Van Schaftingen to operators with variable coefficients. 相似文献
59.
Ferreira TL Paixão TR Richter EM El Seoud OA Bertotti M 《The journal of physical chemistry. B》2007,111(43):12478-12484
A new approach for the determination of diffusion coefficient, D, of redox species is presented. It is based on the use of a home-constructed twin electrode within a thin-layered cell (TETLC) filled with a solution of electroactive species. Values of D are readily calculated, provided that the time required for the electrochemically generated species (produced at the generator electrode) to reach the collector electrode and the distance between both electrodes are known. Other parameters typically required to calculate D, e.g., concentration of the redox species, area of the electrode, and number of electrons transferred, are not needed. Diffusion coefficients of Fe(CN)(6)(3-), Ru(NH3)(6)(2+), and quinone were determined in water and, for Fe(CN)(6)(4-), in binary mixtures with glycerol. The results obtained were in good agreement with literature values. Aqueous glycerol solutions are microheterogeneous, as shown by the dependence on medium composition of the empirical solvent polarity scale, ET(30), determined by the solvatochromic probe RB. The responses of RB and the electrochemically generated species (Fe(CN)(6)(4-)) to the composition of aqueous glycerol mixtures were found to be remarkably similar. Measurements of D of ferrocene in micellar solutions of the cationic surfactant CTABr were also performed. Values of D for ferrocene and the ferrocenium cation are very different, in agreement with the chemical affinity of both species for the cationic micelle. 相似文献
60.
Amarie S Standfuss J Barros T Kühlbrandt W Dreuw A Wachtveitl J 《The journal of physical chemistry. B》2007,111(13):3481-3487
Nonphotochemical quenching (NPQ) is a fundamental mechanism in photosynthesis which protects plants against excess excitation energy and is of crucial importance for their survival and fitness. Recently, carotenoid radical cation (Car*+) formation has been discovered to be a key step for the feedback deexcitation quenching mechanism (qE), a component of NPQ, of which the molecular mechanism and location is still unknown. We have generated and characterized carotenoid radical cations by means of resonant two color, two photon ionization (R2C2PI) spectroscopy. The Car*+ bands have maxima located at 830 nm (violaxanthin), 880 nm (lutein), 900 nm (zeaxanthin), and 920 nm (beta-carotene). The positions of these maxima depend strongly on solution conditions, the number of conjugated C=C bonds, and molecular structure. Furthermore, R2C2PI measurements on the light-harvesting complex of photosystem II (LHC II) samples with or without zeaxanthin (Zea) reveal the violaxanthin (Vio) radical cation (Vio*+) band at 909 nm and the Zea*+ band at 983 nm. The replacement of Vio by Zea in the light-harvesting complex II (LHC II) has no influence on the Chl excitation lifetime, and by exciting the Chls lowest excited state, no additional rise and decay corresponding to the Car*+ signal observed previously during qE was detected in the spectral range investigated (800-1050 nm). On the basis of our findings, the mechanism of qE involving the simple replacement of Vio with Zea in LHC II needs to be reconsidered. 相似文献