Infrared spectrum of D2O vibrationally decoupled in H2O ice Ic

The study of D₂O isolated in amorphous H₂O (ice Iv) has been extended to the determination of the bending mode frequency (1230 cm^?1) and to the measurement of the vibrational spectrum of the cubic ice phase (ice Ic). The vibrationally decoupled stretching frequencies (ν₁ = 2367 cm^?1 and ν₃ = 2444 cm^?1) for D₂O in the H₂O (Ic) have been obtained and an estimate of the exchange activation energy is given.     

Final-state effects in the 3d and 4d X-Ray photoelectron spectra of CeO2

The complex 3d and 4d X-ray photoelectron spectra of CeO₂ arc re-interpreted with the aid of multiple scattering Xα and intermediate coupling calculations. Features in the 3d spectrum are identified with Ce 3d⁹4f⁰, 3d⁹4f¹VB^?1, and 3d⁹5p⁵np final-state configurations. Multiplet coupling in the 3d⁹4f¹ system is found to be significant.     

Capacitance and Structure of Electric Double Layers: Comparing Brownian Dynamics and Classical Density Functional Theory

Journal of Solution Chemistry - We present a study of the structure and differential capacitance of electric double layers of aqueous electrolytes. We consider electric double layer capacitors...