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51.
Abstract The infrared spectra (700–100 cm?1) of the complexes [M(ox)2(H2O)2] (ox = 8-hydroxyquinolinate anion, M = Mn, Fe, Co, Ni, Cu, Zn) are discussed. For the purposes of assignment of the metal ligand modes, deuterated 8-hydroxyquinoline-d 7 was prepared by the Skraup synthesis and the spectra of the deuterated complexes were compared with those of the unlabelled species. Furthermore, [64Zn(ox)2(H2O)2] and [68Zn(ox)2(H2O)2] were prepared by reaction of 64ZnSO4 and 68ZnSO4 with 8-hydroxyquinoline and the effects of metal isotope labelling on the spectra were examined and compared with earlier isotopic data on the nickel and zinc complexes. 相似文献
52.
Philip S. Hall Graham E. Jackson John R. Moss David A. Thornton Paul F. M. Verhoeven Gareth M. Watkins 《光谱学快报》2013,46(7):1247-1267
Abstract The infrared spectra (4000 - 50 cm?1) of the square planar rhodium(I) complexes cis-[Rh(CO)2 (pyridine) (X)] (X = Cl, Br) and their isotopomers with pyridine-d 5 and 13CO have been determined. Assignments are based on earlier studies on pyridine and its complexes and on the shifts in infrared bands which are caused by the isotopic substitutions employed. Normal coordinate analysis following the procedure of Becher and Mattes has been used to confirm the empirical assignments. The two v(RhC) bands are observed near 490 and 450 cm?1. v(RhN) is found near 210 cm?1 and v(RhX) occurs at 310 (X = Cl) and 235 (X = Br) cm?1. At frequencies below 200 cm?1, the bands are assigned to bending modes in the following sequence: δ (RhN) > δ (CRhC) > δ (RhCl) > γ (RhCl) > γ (RhN). 相似文献
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We present a detailed theoretical analysis for the determination of the total internal loss in Fabry-Perot resonators based on Fourier analysis of the emission or transmission spectrum. The observation of higher-order harmonics and their relative height in the Fourier-transformed spectrum allow us to quantify the total resonator loss. Because this new method considers both contrast and shape of the Fabry-Perot fringes it is especially well suited for the evaluation of high-finesse laser resonators such as those of vertical cavity surface-emitting lasers in terms of propagation loss/gain. 相似文献
54.
A. F. Joseph F. P. Treadwell W. T. Hall F. Sutton L. L. de Koninck J. M. Kolthoff F. W. Küster Fr. L. Hahn H. Windisch W. Böttger C. Russo A. Monnier O. Hackl W. M. Thornton jr. J. E. Chapman L. Brandt E. Knecht Eva Hibbert O. Tomiček E. Polidori B. Diethelm F. Foerster W. M. Thornton L. Moser W. A. Hicks K. Schröder 《Analytical and bioanalytical chemistry》1926,68(9-10):369-384
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In this study, methanol extracts (MEs) and essential oil (EO) of Angelica purpurascens (Avé-Lall.) Gill obtained from different parts (root, stem, leaf, and seed) were evaluated in terms of antioxidant activity, total phenolics, compositions of phenolic compound, and essential oil with the methods of 2,2-azino-bis(3ethylbenzo-thiazoline-6-sulfonic acid (ABTS•+), 2,2-diphenyl-1-picrylhydrazil (DPPH•) radical scavenging activities, and ferric reducing/antioxidant power (FRAP), the Folin–Ciocalteu, liquid chromatography−tandem mass spectrometry (LC−MS/MS), and gas chromatography-mass spectrometry (GC−MS), respectively. The root extract of A. purpurascens exhibited the highest ABTS•+, DPPH•, and FRAP activities (IC50: 0.05 ± 0.0001 mg/mL, IC50: 0.06 ± 0.002 mg/mL, 821.04 ± 15.96 µM TEAC (Trolox equivalent antioxidant capacity), respectively). Moreover, EO of A. purpurascens root displayed DPPH• scavenging activity (IC50: 2.95 ± 0.084 mg/mL). The root extract had the highest total phenolic content (438.75 ± 16.39 GAE (gallic acid equivalent), µg/mL)). Twenty compounds were identified by LC−MS/MS. The most abundant phenolics were ferulic acid (244.39 ± 15.64 μg/g extract), benzoic acid (138.18 ± 8.84 μg/g extract), oleuropein (78.04 ± 4.99 μg/g extract), and rutin (31.21 ± 2.00 μg/g extract) in seed, stem, root, and leaf extracts, respectively. According to the GC−MS analysis, the major components were determined as α-bisabolol (22.93%), cubebol (14.39%), α-pinene (11.63%), and α-limonene (9.41%) among 29 compounds. Consequently, the MEs and EO of A. purpurascens can be used as a natural antioxidant source. 相似文献
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Malcolm A. Halcrow Colin A. Kilner Mark Thornton‐Pett 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(2):213-214
The title compound, C13H7F6N5, is one of a series of hindered tris‐imine ligands for meridonial coordination to transition metals. The molecule has crystallographic C2 symmetry, the pyrazole and pyridine rings adopting a near‐coplanar transoid conformation. 相似文献