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281.
Cheng-kung Liu John A. Cuculo Thomas C. Allen A. Willem Degroot 《Journal of Polymer Science.Polymer Physics》1991,29(2):181-196
Fiber formation via the cellulose/ammonia/ammonium thiocyanate system by wet spinning has been investigated. This report presents a characterization of the structure and tensile properties of fibers spun under various coagulation conditions. Microscopic observations showed that the molecular size of coagulant was the dominant factor governing the crosssectional shape of the fibers. Density, birefringence, and crystallinity data indicated that a higher cellulose concentration and lower coagulation temperature favored development of a fiber with a denser and more oriented structure. Under optimum conditions, a welldefined fibrillar structure was obtained. Fiber tensile property measurements suggested the existence of a linear relationship between the fiber breaking tenacity and the product of the square of the Hermans' orientation factor and the infrared crystallinity index. 相似文献
282.
283.
Yanlin Huang Kiwan Jang Wanxue Zhao Eunjin Cho Ho Sueb Lee Xigang Wang Dake Qin Ying Zhang Chanfang Jiang Hyo Jin Seo 《Journal of solid state chemistry》2007,180(12):3325-3332
Usually, Sm2+ ions could be reduced by heating the materials in reducing atmospheres. Exposure to ionizing radiations is also known to cause Sm3+→Sm2+ conversion. In this work, BaBPO5 doped with the samarium ion was prepared by high temperature solid-state reaction. Sm2+ ions were obtained by two different reduction methods, i.e., heating in H2 reduced atmosphere and X-ray irradiation. The measurements of X-ray diffraction (XRD), and scanning electron microscope (SEM) were investigated. It is found that the conversion of Sm3+→Sm2+ is very efficient in BaBPO5 hosts after X-ray irradiation. Sm2+ ions under these two reduction methods exhibit different characteristics that were studied by measurements of luminescence and decay. The results showed that the luminescence properties of Sm2+ ions in BaBPO5 were highly dependent on the sample preparation conditions. 相似文献
284.
Gui-Chang Wang Ling Jiang Yoshitada Morikawa Junji Nakamura Zun-Sheng Cai Yin-Ming Pan Xue-Zhuang Zhao 《Surface science》2004,570(3):205-217
The adsorption behavior and thermal activation of carbon dioxide on the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces have been investigated by means of density functional theory calculations and cluster models and periodic slabs. According to the cluster models, the optimized results indicate that the basis set of C and O atoms has a distinct effect on the adsorption energy, but an indistinct one on the equilibrium geometry. For the CO2/Cu(hkl) adsorption systems studied here, the final structure of adsorbed CO2 is near linear and the preferred modes for the adsorption of CO2 onto the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces are the side-on adsorption at the cross bridge site with an adsorption energy of 13.06 kJ/mol, the side-on adsorption at the short bridge site (13.54 kJ/mol), and the end-on adsorption on the on-top site with C–O bonds located along the short bridge site (26.01 kJ/mol), respectively. However, the calculated adsorption energies from periodic slabs are lower as compared to the experimental data as well as the cluster model data, indicating that the periodic slab approach of generalized gradient approximation in the density function theory may be not suitable to obtain quantitative information on the interaction of CO2 with Cu(hkl) surfaces. 相似文献
285.
光纤加速度传感器研究进展 总被引:5,自引:0,他引:5
光纤加速度传感器与传统加速度传感器相比,不但能抗电磁干扰,而且体小、质轻、动态范围宽、精度高、能在恶劣环境下工作,因此受到各先进国家军事与商业领域的极大重视,各种实用的光纤加速度传感器不断涌现。主要有光强调制型和相位调制型两大类。光强调制式有反射式、透射式和偏振式等等。相位调制式有Mach-Zender干涉仪、Michelson干涉仪和Fabry-Perot干涉仪。有一维的,也有二维的;有与水听器组合在一起的,也有与光纤陀螺仪组合的光纤加速度传感器。最小的已经做到2.5cm长,直径仅0.25mm;测量精度已能达到1μg;共振频率可达到10kHz。为了克服温度不稳定性对测量精度的影响,人们采用了3×3耦合器解调法,双光路法,由单臂式改成推挽式等。一旦关键技术得以克服,光纤加速度传感器将会在惯性导航和其它领域发挥更重要的作用。本文将分别介绍目前各种类型光纤加速度传感器的结构、特点、走向实用化存在的问题。 相似文献
286.
在研究小波变换及布朗分形模型的基础上,定义了水平分维数,垂直分维数,对角分维数,并将它们作为纹理特征量来实现纹理的分割.实验结果表明,这些特征量能够很好地反映纹理特征,从而分割时不需有关图象中纹理类别的先验信息,较以往方法在准确度和计算复杂程度上都有很大提高. 相似文献
287.
Summary A new method of evaluating the Tolman cone angle from X-ray structural data available from the Cambridge Crystallographic Data Base has been developed and a statistical analysis of the cone angles of the phosphines PPh3, PMe2Ph, PMePh2, PMe3, PEt3 and PCy3 (Cy = cyclohexyl) in transition metal complexes has been completed. 相似文献
288.
289.
Thomas Andreae 《Results in Mathematics》2002,41(1-2):18-25
Recent results on the immersion relation for graphs are applied to show that there exist (uncountable) graphs A and G such that G contains n disjoint copies of A for each positive integer n, but the graph N0A consisting of infinitely many disjoint copies of A does not embed in G, where by ‘embedding’ we mean ‘immersion in the weak sense’. 相似文献
290.