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81.
Nguyen Tle A Devic T Mialane P Rivière E Sonnauer A Stock N Demir-Cakan R Morcrette M Livage C Marrot J Tarascon JM Férey G 《Inorganic chemistry》2010,49(22):10710-10717
A high-throughput methodology combined with X-ray powder diffraction measurements was used to investigate the reactivity of the TetraThiaFulvalene TetraCarboxylic acid ((TTF-TC)H(4)) with divalent metals (M = Ni, Co) under various reaction conditions (stoichiometry, pH, temperature). Two new crystalline phases were identified and then studied by single crystal X-ray diffraction. Whereas the first one appears to be a simple salt, the second one, formulated {[M(H(2)O)(4)](2)(TTF-TC)}·4H(2)O, is built of 2:1 M:TTF-TC molecular complexes and labeled MIL-136(Ni, Co) (MIL stands for Materials Institute Lavoisier). The combination of thermogravimetric analysis and thermodiffraction studies reveals that MIL-136(Ni) exhibits a complex dehydration behavior. Indeed, a partial dehydration/rehydration process led to the single-crystal-to-single-crystal transformation of the molecular compound in a two-dimensional coordination polymer formulated {[Ni(2)(H(2)O)(5)(TTF-TC)]}·H(2)O (MIL-136'(Ni)). Magnetic and redox properties of MIL-136(Ni, Co) were investigated. Magnetic measurements indicate that all the magnetic coupling, intra- and intermolecular, are very weak; thus, the magnetic data of MIL-136(Ni, Co) have been interpreted in term of single-ion spin orbit coupling. Solid state cyclic voltammetry of MIL-136(Ni, Co) presents three reversible waves which were assigned to the redox activity of the TTF core and the metallic cations. In contrast to solids based on TTF linkers and alkaline ions, the MIL-136(Ni, Co) complexes do not act as excellent positive electrode materials for Li batteries, but present two reversible electron oxidation of the TTF core. These observations were tentatively related to the strength of the metal-carboxylate bond. 相似文献
82.
83.
Luu Viet Hung O. D. Maslov M. V. Gustova Trinh Thi Thu My Phung Khac Nam Ho 《Physics of Particles and Nuclei Letters》2011,8(4):412-416
The leaves, stem, and roots of two types of shrubs (tea (Camellia sinensis) and sweet leaf (Sauropus androgynus)) and two types of herbs (vetiver grass (Vetiveria zizanioides L. Nash) and maize (Zea mays L)) and the Thucuc soil where the plants were growing were collected to be studied. The contents of 22 elements in the samples
were determined by three methods: X-Ray fluorescence analysis (XRFA), gamma activation analysis (GAA), and the tracking method
to study the distribution of these elements in plants and the soil-plant relationship. This study was carried out at the Flerov
Laboratory of Nuclear Reactions (FLNR), Joint Institute for Nuclear Research (JINR), Dubna, Russia. The distribution of the
elements in the soil-plant system was studied. 相似文献
84.
Nguyen Thi Van Hang 《Set-Valued and Variational Analysis》2014,22(2):299-312
We show that the finite-dimensional Fritz John multiplier rule, which is based on the limiting/Mordukhovich subdifferential, can be proved by using differentiable penalty functions and the basic calculus tools in variational analysis. The corresponding Kuhn–Tucker multiplier rule is derived from the Fritz John multiplier rule by imposing a constraint qualification condition or the exactness of an ?1 penalty function. Complementing the existing proofs, our proofs provide another viewpoint on the fundamental multiplier rules employing the Mordukhovich subdifferential. 相似文献
85.
A sliced inverse regression approach for data stream 总被引:1,自引:0,他引:1
Marie Chavent Stéphane Girard Vanessa Kuentz-Simonet Benoit Liquet Thi Mong Ngoc Nguyen Jérôme Saracco 《Computational Statistics》2014,29(5):1129-1152
In this article, we focus on data arriving sequentially by blocks in a stream. A semiparametric regression model involving a common effective dimension reduction (EDR) direction \(\beta \) is assumed in each block. Our goal is to estimate this direction at each arrival of a new block. A simple direct approach consists of pooling all the observed blocks and estimating the EDR direction by the sliced inverse regression (SIR) method. But in practice, some disadvantages appear such as the storage of the blocks and the running time for large sample sizes. To overcome these drawbacks, we propose an adaptive SIR estimator of \(\beta \) based on the optimization of a quality measure. The corresponding approach is faster both in terms of computational complexity and running time, and provides data storage benefits. The consistency of our estimator is established and its asymptotic distribution is given. An extension to multiple indices model is proposed. A graphical tool is also provided in order to detect changes in the underlying model, i.e., drift in the EDR direction or aberrant blocks in the data stream. A simulation study illustrates the numerical behavior of our estimator. Finally, an application to real data concerning the estimation of physical properties of the Mars surface is presented. 相似文献
86.
Mustapha Hellou Thi Diep Phuong Bach 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2011,11(3):135-147
The purpose of this study is to calculate Stokes flow structures in relation to flow rate distribution in a junction of four orthogonal channels. Particular attention was paid to the existence of recirculation flow inside the channels for low Reynolds numbers. The presence of this recirculation flow may be observed, but only when the flow rate is relatively low in at least one of the branches. 相似文献
87.
Nguyen Thi Van Hang 《Numerical Functional Analysis & Optimization》2013,34(3):364-386
This article shows that finite-dimensional multiplier rules, which are based on the limiting subdifferential, can be proved by Ekeland's variational principle and some basic calculus tools of the generalized differentiation theory introduced by B. S. Mordukhovich. Consequences of a limiting constraint qualification, which yields the normal form of the multiplier rules, stability and calmness of optimization problems, are investigated in detail. 相似文献
88.
89.
Le Thi Phuong Ngoc Nguyen Anh Triet Nguyen Thanh Long 《Nonlinear Analysis: Theory, Methods & Applications》2010,72(3-4):1865-1885
The paper is devoted to the study of a linear wave equation with a nonlinear boundary condition of viscoelastic type. The existence of a weak solution is proved by using the Faedo–Galerkin method. The uniqueness, regularity and asymptotic expansion of the solution are also discussed. 相似文献
90.
Globally solving a nonlinear UAV task assignment problem by stochastic and deterministic optimization approaches 总被引:1,自引:0,他引:1
In this paper, we consider a task allocation model that consists of assigning a set of m unmanned aerial vehicles (UAVs) to a set of n tasks in an optimal way. The optimality is quantified by target scores. The mission is to maximize the target score while satisfying capacity constraints of both the UAVs and the tasks. This problem is known to be NP-hard. Existing algorithms are not suitable for the large scale setting. Scalability and robustness are recognized as two main issues. We deal with these issues by two optimization approaches. The first approach is the Cross-Entropy (CE) method, a generic and practical tool of stochastic optimization for solving NP-hard problem. The second one is Branch and Bound algorithm, an efficient classical tool of global deterministic optimization. The numerical results show the efficiency of our approaches, in particular the CE method for very large scale setting. 相似文献