全文获取类型
收费全文 | 1473篇 |
免费 | 56篇 |
国内免费 | 11篇 |
专业分类
化学 | 911篇 |
晶体学 | 12篇 |
力学 | 35篇 |
数学 | 310篇 |
物理学 | 272篇 |
出版年
2023年 | 12篇 |
2022年 | 62篇 |
2021年 | 67篇 |
2020年 | 47篇 |
2019年 | 68篇 |
2018年 | 59篇 |
2017年 | 58篇 |
2016年 | 79篇 |
2015年 | 71篇 |
2014年 | 78篇 |
2013年 | 86篇 |
2012年 | 103篇 |
2011年 | 105篇 |
2010年 | 62篇 |
2009年 | 60篇 |
2008年 | 57篇 |
2007年 | 53篇 |
2006年 | 38篇 |
2005年 | 40篇 |
2004年 | 28篇 |
2003年 | 32篇 |
2002年 | 19篇 |
2001年 | 13篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1995年 | 9篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 12篇 |
1990年 | 14篇 |
1989年 | 7篇 |
1988年 | 12篇 |
1987年 | 16篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1972年 | 5篇 |
1964年 | 4篇 |
排序方式: 共有1540条查询结果,搜索用时 15 毫秒
91.
Electrofiltration of hydrosols in fixed-bed filters was studied experimentally. The experimental variables examined included media type, electric field strength, and suspension pH values. The extent of particle removal was found to improve with the application of the electric field, and lower pH values favor particle collection. The filtrate quality displayed the transient behavior of increasing particle concentration with time. A simple model which assumes that the filter coefficient decreases linearly with the extent of deposition was developed and found capable of predicting the observed behavior. Copyright 2000 Academic Press. 相似文献
92.
Nguyen Tle A Devic T Mialane P Rivière E Sonnauer A Stock N Demir-Cakan R Morcrette M Livage C Marrot J Tarascon JM Férey G 《Inorganic chemistry》2010,49(22):10710-10717
A high-throughput methodology combined with X-ray powder diffraction measurements was used to investigate the reactivity of the TetraThiaFulvalene TetraCarboxylic acid ((TTF-TC)H(4)) with divalent metals (M = Ni, Co) under various reaction conditions (stoichiometry, pH, temperature). Two new crystalline phases were identified and then studied by single crystal X-ray diffraction. Whereas the first one appears to be a simple salt, the second one, formulated {[M(H(2)O)(4)](2)(TTF-TC)}·4H(2)O, is built of 2:1 M:TTF-TC molecular complexes and labeled MIL-136(Ni, Co) (MIL stands for Materials Institute Lavoisier). The combination of thermogravimetric analysis and thermodiffraction studies reveals that MIL-136(Ni) exhibits a complex dehydration behavior. Indeed, a partial dehydration/rehydration process led to the single-crystal-to-single-crystal transformation of the molecular compound in a two-dimensional coordination polymer formulated {[Ni(2)(H(2)O)(5)(TTF-TC)]}·H(2)O (MIL-136'(Ni)). Magnetic and redox properties of MIL-136(Ni, Co) were investigated. Magnetic measurements indicate that all the magnetic coupling, intra- and intermolecular, are very weak; thus, the magnetic data of MIL-136(Ni, Co) have been interpreted in term of single-ion spin orbit coupling. Solid state cyclic voltammetry of MIL-136(Ni, Co) presents three reversible waves which were assigned to the redox activity of the TTF core and the metallic cations. In contrast to solids based on TTF linkers and alkaline ions, the MIL-136(Ni, Co) complexes do not act as excellent positive electrode materials for Li batteries, but present two reversible electron oxidation of the TTF core. These observations were tentatively related to the strength of the metal-carboxylate bond. 相似文献
93.
Zhi‐Chang Liu Dr. Chih‐Hsien Chen Dr. Hsian‐Wen Wang Yen‐Chin Huang Ming‐Jui Kao Tsong‐Shin Lim Prof. Tien‐Yau Luh Prof. 《化学:亚洲杂志》2010,5(6):1425-1438
Polynorbornenes appended with porphyrins containing a range of different linkers are synthesized. The use of bisamidic chiral alanine linkers between the pending porphyrins and the polymeric backbone has been shown to bring the adjacent porphyrin chromophores to more suitable orientation for exciton coupling owing to hydrogen bonding between the adjacent linkers. The hydrogen bonding between the adjacent pendants in these polymers may induce a cooperative effect and therefore render single‐handed helical structures for these polymers. Such a cooperative effect is reflected in the enhancement of FRET efficiencies between zinc–porphyrin and free base porphyrin in random copolymers. 相似文献
94.
Binh Thi Thanh Nguyen Jin Qiang Ang Chee-Seng Toh 《Electrochemistry communications》2009,11(10):1861-1864
A model K+ sensor using Prussian blue nanotubes is fabricated by electrochemical deposition of Prussian blue (PB) within the nanochannels of a porous metal-coated membrane with partially covered pore openings. The PB nanotube sensor exhibits excellent stability giving reproducible peak potentials up to 500 measurement cycles, a very low detection limit of 2.0 × 10−8 M and extremely wide logarithmic linear ranges between 5.0 × 10−8–7.0 × 10−4 M and 7.0 × 10−4–1.0 M. Negligible interferences by Na+, Mg2+ and Ca2+ are observed and a rapid analysis time of 30 s is readily achieved. The ease of electrodeposition, high stability of PB nanotubes and outstanding analytical performance which surpasses conventional PB voltammetric and potentiometric sensors demonstrates potential sensing applications including ion sensors and biosensors using PB and other metal hexacyanoferrate nanotubes. 相似文献
95.
Hsian‐Wen Wang Zhi‐Chang Liu Chih‐Hsien Chen Dr. Tsong‐Shin Lim Prof. Wunshain Fann Prof. Chih‐Gang Chao Jian‐Yuan Yu Shern‐Long Lee Chun‐hsien Chen Prof. Shou‐Ling Huang Tien‐Yau Luh Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(23):5719-5728
You can append on me! Porphyrin‐appended polynorbornenes derived from 5,6‐endo‐fused N‐arylpyrrolidenonorbornenes have been shown to have coherently aligned pendant groups that exhibit exciton coupling and fluorescence quenching in the absorption and emission profiles (see figure).
96.
Z. Szeglowski L. I. Guseva Dinh Thi Lien V. P. Domanov B. Kubica G. S. Tikhomirowa O. Constantinescu M. Constantinescu A. B. Yakushev 《Journal of Radioanalytical and Nuclear Chemistry》1998,228(1-2):145-150
The short-lived isotopes of W and their descendants have been separated from nuclear reaction products arising in the bombardment of samarium target with24Mg ions at the U-400 cyclotron of JINR-Dubna. Chemical separations were performed using previously elaborated fast and continuous ion exchange. In similar way products of235U fission, obtained at the microtron MT-25 during irradiation of235U target with photoneutrons were separated. 相似文献
97.
98.
Qingsheng Liu Bingyao Deng Chia‐Hsin Tung Meifang Zhu Tien‐Wei Shyr 《Journal of Polymer Science.Polymer Physics》2010,48(21):2288-2295
The poly(3‐hydroxbutyrate‐co‐3‐hydroxyvalerate)/poly(ε‐caprolactone) block copolymers (PHCLs) with three different weight ratios of PCL blocks (38%, named PHCL‐38; 53%, named PHCL‐53; and 60%, named PHCL‐60) were synthesized by using PHBV with two hydroxyl end groups to initiate ring‐opening polymerization of ε‐caprolactone. During DSC cooling process, melt crystallization of PHCL‐53 at relatively high cooling rates (9, 12, and 15 °C min?1) and PHCL‐60 at all the selected cooling rates corresponded to PCL blocks so that PHCL‐53 and PHCL‐60 were used to study the nonisothermal crystallization behaviors of PCL blocks. The kinetics of PCL blocks in PHCL‐53 and PHCL‐60 under nonisothermal crystallization conditions were analyzed by Mo equation. Mo equation was successful in describing the nonisothermal crystallization kinetics of PCL blocks in PHCLs. Crystallization activation energy were estimated using Kissinger's method. The results of kinetic parameters showed that both blocks crystallized more difficultly than corresponding homopolymers. With the increase of PCL content, the crystallization rate of PCL block increased gradually. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010 相似文献
99.
Jihoon Shin Ying Chang Thi Le Thanh Nguyen Seok Kyun Noh Chulsung Bae 《Journal of polymer science. Part A, Polymer chemistry》2010,48(19):4335-4343
Postfunctionalization of high‐molecular‐weight syndiotactic polystyrene (sPS) was achieved via combination of electrophilic bromination at the para‐position of the polymer aromatic ring and subsequent Suzuki–Miyaura cross‐coupling reactions with functionalized phenylboronic acids. The concentration of brominated styrene repeating unit in sPS was conveniently controlled by changing the ratio of added bromine relative to the polymer repeating unit. Brominated sPS (8.5 mol %) was converted quantitatively to other polar functional groups via Suzuki–Miyaura cross‐coupling reactions with various functional group‐substituted phenylboronic acids. The surface properties of functionalized sPS were studied by measuring water contact angles. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4335–4343, 2010 相似文献
100.
MD. Daloar Hossain Le Thi Bao Tran Jong Myung Park Kwon Taek Lim 《Journal of polymer science. Part A, Polymer chemistry》2010,48(22):4958-4964
A new, efficient method for synthesizing stable nanoparticles with poly(ethylene oxide) (PEO) functionalities on the core surface, in which the micellization and crosslinking reactions occur in one pot, has been developed. First, amphiphilic PEO‐b‐PS copolymers were synthesized by reversible addition fragmentation chain transfer (RAFT) radical polymerization of styrene using (PEO)‐based trithiocarbonate as a macro‐RAFT agent. The low molecular weight PEO‐b‐PS copolymer was dissolved in isopropyl alcohol where the block copolymer self‐assembled as core‐shell micelles, and then the core‐shell interface crosslink was performed using divinylbenzene as a crosslinking agent and 2,2′‐azobisisobutyronitrile as an initiator. The design of the amphiphilic RAFT agent is critical for the successful preparation of core‐shell interface crosslinked micellar nanoparticles, because of RAFT functional groups interconnect PEO and polystyrene blocks. The PEO functionality of the nanoparticles surface was confirmed by 1H NMR and FTIR. The size and morphology of the nanoparticles was confirmed by scanning electron microscopy, transmission electron microscopy, and dynamic laser light scattering analysis. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献