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331.
Theodor Heczko 《Fresenius' Journal of Analytical Chemistry》1928,73(11):404-411
Ohne Zusammenfassung 相似文献
332.
Theodor Benfey 《Foundations of Chemistry》2000,2(3):195-205
Biology in the popular mind remains tied to the doctrines of the struggle forsurvival and the survival of the fittest. Physics
is linked to the heat deathof the universe – the inexorable march towards greater disorder,increasing entropy. Our field,
on the other hand, focuses on orderedstructures, molecules and crystals, and their aggregates, and what holdsthem together.
The philosophy of chemistry is centered on affinity,cohesion, the architecture of the very small, attraction, harmony, and,
ifyou permit, beauty. Our discipline is the voice of the twenty-first century,a message, a clarion call of life, of hope.
This paper addresses failures ofreductionist and deterministic claims in the face of the cussedness ofchemical facts. It will
examine uncertainty principles, Edmund Whitaker'spostulates of impotence, Gerald Holton's themata, Isaiah Berlin's warning
–and the wisdom of the Chinese. We can teach the world the need for humilityin the face of the wonder and mystery of our world.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Condensation of azetidinone 1 with mercaptan 3 gave compound 5 . Bromination of 5 afforded two isomeric bromohydrins 11a and 11b which differ in the configuration at C(4). Acetylation and reduction with zinc and acetic acid of the above bromohydrins gave 7-deamidocephalosporin lactone ( 14 ). 相似文献
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Theodor W. Güntert Horst H. A. Linde Mohamed S. Ragab Sigrid Spengel 《Helvetica chimica acta》1977,60(2):334-339
Synthesis of a steroidal 17 β-pyrrolinone We describe the synthesis of 4′-(3 β-hydroxy-androst-5-ene-17 β-yl)-3′-pyrrolin-2′-one (6) starting from 3β-acetoxy-21-hydroxy-pregn-5-ene-20-one (1). 相似文献
340.
The potentiometric study of the complexation of Cu2+ with 1,4,7-triazacyclononane ( 1 ), 1,4,8-triazacyclodecane ( 2 ) 1,5,9-triazacyclododecane ( 3 ) has shown that CuL, CuL2 and (CuLOH)2 are the main species present in solution. Their stabilities (Table 1) and their absorption spectra (Table 2) indicate facial coordination of the cyclic triamines in a distorted octahedral geometry. The formation and dissociation kinetics have been measured by stopped-flow techniques. The formation in acetate buffer can be described by the reaction of Cu2+ and CuAcO+ with the monoprotonated species of the ligand. The bimolecular rate constants for these complexations (Table 3) decrease when the ring size increases. In contrast the dissociation induced by acid is only little affected by the ring size. Thus for these complexes the rate of formation and not that of the dissociation determines the overall stability. 相似文献