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521.
Omer Sise Melike Ulu Mevlut Dogan Genoveva Martinez Theo J.M. Zouros 《Journal of Electron Spectroscopy and Related Phenomena》2010
In this paper we present numerical modeling results for fringing field optimization of hemispherical deflector analyzers (HDAs), simulated using boundary-element and finite-difference numerical methods. Optimization of the fringing field aberrations of HDAs is performed by using a biased optical axis and an optimized entry position offset (paracentric) from the center position used in conventional HDAs. The described optimization achieves first-order focusing thus also further improving the energy resolution of HDAs. 相似文献
522.
Theo Fromme Lucie K. Tintrop Dr. Sven Reichenberger Prof. Dr. Torsten C. Schmidt Prof. Dr. Stephan Barcikowski 《Chemphyschem》2023,24(11):e202300089
Laser ablation in liquids has been established as a scalable preparation method of nanoparticles for various applications. Particularly for materials prone to oxidation, it is established to suppress oxidation by using organic solvents as a liquid medium. While this often functionalizes the nanoparticles with a carbon shell, the related chemical processes that result from laser-induced decomposition reactions of the organic solvents remain uncertain. Using a systematic series of C6 solvents complemented by n-pentane and n-heptane during the nanosecond laser ablation of gold, the present study focuses on the solvent-dependent influence on gas formation rates, nanoparticle productivity, and gas composition. Both the permanent gas and hydrogen formation was found to be linearly correlated with ablation rate, ΔHvap, and pyrolysis activation energy. Based on this, a decomposition pathway linked to pyrolysis is proposed allowing the deduction of first selection rules for solvents that influence the formation of carbon or permanent gases. 相似文献
523.
Ralph J.S. van Mechelen Jarno E.J. Wolters Sebastian Fredrich Christian J.F. Bertens Marion J.J. Gijbels Albert P.H.J. Schenning Leonard Pinchuk Theo G.M.F. Gorgels Henny J.M. Beckers 《Macromolecular bioscience》2023,23(10):2300075
Fibrosis of the filtering bleb is one of the main causes of failure after bleb-forming glaucoma surgery. Intraoperative application of mitomycin C (MMC) is the current gold standard to reduce the fibrotic response. However, MMC is cytotoxic and one-time application is often insufficient. A sustained-release drug delivery system (DDS), loaded with MMC, may be less cytotoxic and equally or more effective. Two degradable (polycaprolactone (PCL) and polylactic-co-glycolic acid (PLGA)) MMC-loaded DDSs are developed. Release kinetics are first assessed in vitro followed by rabbit implants in conjunction with the PRESERFLO MicroShunt. As a control, the MicroShunt is implanted with adjunctive use of a MMC solution. Rabbits are euthanized at postoperative day (POD) 28 and 90. The PLGA and PCL DDSs release (on average) 99% and 75% of MMC, respectively. All groups show functioning blebs until POD 90. Rabbits implanted with a DDS show more inflammation with avascular thin-walled blebs when compared to the control. However, collagen is more loosely arranged. The PLGA DDS shows less inflammation, less foreign body response (FBR), and more complete degradation at POD 90 when compared to the PCL DDS. Further optimization with regard to dosage is required to reduce side effects to the conjunctiva. 相似文献
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