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951.
Several procedures for calculating the heat of adsorption from Monte Carlo simulations for a heterogeneous adsorbent are presented. Simulations have been performed to generate isotherms for nitrogen at 77 K and methane at 273.15 K in graphitic slit pores of various widths. The procedures were then applied to calculate the heat of adsorption of an activated carbon with an arbitrary pore size distribution. The consistency of the different procedures shows them to be correct in calculating interaction energy contributions to the heat of adsorption. The currently favored procedure for this type of calculation, from the literature, is shown to be incorrect and in serious error when calculating the heat of adsorption of activated carbon. 相似文献
952.
Kowalczyk P Solarz L Do DD Samborski A MacElroy JM 《Langmuir : the ACS journal of surfaces and colloids》2006,22(21):9035-9040
Novel carbon nanostructures can serve as effective storage media for methane, a source of "clean energy" for the future. We have used Grand Canonical Monte Carlo Simulation for the modeling of methane storage at 293 K and pressures up to 80 MPa in idealized bundles of (10,10) armchair-type single-walled carbon nanotubes and wormlike carbon pores. We have found that these carbon nanomaterials can be treated as the world's smallest high-capacity methane storage vessels. Our simulation results indicate that such novel carbon nanostructures can reach a high volumetric energy storage, exceeding the US FreedomCAR Partnership target of 2010 (5.4 MJ dm(-3)), at low to moderate pressures ranging from 1 to 7 MPa at 293 K. On the contrary, in the absence of these nanomaterials, methane needs to be compressed to approximately 13 MPa at 293 K to achieve the same target. The light carbon membranes composed of bundles of single-walled carbon nanotubes or wormlike pores efficiently physisorb methane at low to moderate pressures at 293 K, which we believe should be particularly important for automobiles and stationary devices. However, above 15-20 MPa at 293 K, all investigated samples of novel carbon nanomaterials are not as effective when compared with compression alone since the stored volumetric energy and power saturate at values below those of the bulk, compressed fluid. 相似文献
953.
954.
For a von Neumann algebra ${\mathcal M}$ , we introduce ${\mathcal M}$ -valued Besicovitch sequences and study the norm and individual convergences of the corresponding weighted ergodic averages. The limits of the averages are examined under the condition that the contraction in question is weakly mixing. 相似文献
955.
Mustafa K. Doğru A. G. de Kok G. J. van Houtum 《Central European Journal of Operations Research》2013,21(3):541-559
This paper considers a one-warehouse multi-retailer inventory system that faces discrete stochastic demand of the customers. Under the so-called balance assumption (also known as the allocation assumption), base stock policies are optimal. Our main contribution is to show that the optimal base stock levels satisfy newsvendor characterizations, which are in terms of inequalities, and to extend the newsvendor equalities known for the continuous demand model. These characterizations are appealing because they (i) are easy to explain to nonmathematical oriented people like managers and MBA students, (ii) contribute to the understanding of optimal control, (iii) help intuition development by providing direct relation between cost and optimal policy parameters. 相似文献
956.
So Han Kim Junseong Lee Da Jung Kim Jung Hee Moon Sungwoo Yoon Hyung Jin Oh Youngkyu Do Young Soo Ko Jin-Heong Yim Youngjo Kim 《Journal of organometallic chemistry》2009,694(21):3409-3417
Several titanium isopropoxides 1–8 have been prepared by the reaction of Ti(O-i-Pr)4 with a series of corresponding tetradentate Salan-type [ONNO] ligands with benzyl or methyl substituents on bridging nitrogen atoms. They have been characterized by 1H NMR, 13C{1H} NMR, and elemental analysis. Solid state structures of compounds 2, 4, 6, and 7 have been determined by X-ray crystallography. X-ray diffraction analysis and 1H NMR confirmed that these titanium complexes were all monomeric species with a six-coordinated central titanium in their solid and solution structures. Complexes 2, 4, 6, and 8 with benzyl substituents on bridging nitrogens gave PLA with higher molecular weight than compounds 1, 3, 5, and 7 with methyl substituents did. 相似文献
957.
Interference effects of co-generated hydrides of arsenic, antimony and bismuth on trapping behavior of selenium hydride (analyte) within an iridium-modified, transversely heated graphite tube atomizer (THGA) were investigated. A twin-channel hydride generation system was used for independent separate generation and introduction of analyte and interferent hydrides, i.e. in a simultaneous and/or sequential analyte–interferent and interferent–analyte mode of operation. The influence of the analyte and modifier mass, interferent amount, trapping temperature and composition of the gaseous phase was studied. A simple approach for the elimination of mutual interference effects by modification of the gaseous phase with oxygen in a substoichiometric ratio to chemically generated hydrogen is proposed and the suppression of these interference effects is demonstrated. A hypothesis on the mechanism of trapping and mutual interference effects is drawn. 相似文献
958.
The moduli spaces of hyperbolic surfaces of genus g with n geodesic boundary components are naturally symplectic manifolds. Mirzakhani proved that their volumes are polynomials in
the lengths of the boundaries by computing the volumes recursively. In this paper, we give new recursion relations between
the volume polynomials.
相似文献
959.
Let G be a compact Lie group. In 1960, P A Smith asked the following question: “Is it true that for any smooth action of G on a homotopy sphere with exactly two fixed points, the tangent G-modules at these two points are isomorphic?” A result due to Atiyah and Bott proves that the answer is ‘yes’ for ? p and it is also known to be the same for connected Lie groups. In this work, we prove that two linear torus actions on S n which are c-cobordant (cobordism in which inclusion of each boundary component induces isomorphisms in ?-cohomology) must be linearly equivalent. As a corollary, for connected case, we prove a variant of Smith’s question. 相似文献
960.
Transition-metal doped double-perovskite structure oxides GdBaCo2/3Fe2/3Ni2/3O5+δ (FN-GBCO), GdBaCo2/3Fe2/3Cu2/3O5+δ (FC-GBCO), GdBaCoCuO5+δ (C-GBCO) and pristine GdBaCo2O5+δ (GBCO) were synthesized via a citrate combustion method. The thermal-expansion coefficient (TEC) and electrochemical performance of the oxides were investigated as potential cathodes for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The TEC exhibited by the FC-GBCO cathode up to 900 °C is 14.6 × 10?6 °C?1, which is lower than the value of GBCO (19.9 × 10?6 °C?1). Area specific resistances (ASR) of 0.165 Ω cm2 at 700 °C and 0.048 Ω cm2 at 750 °C were achieved for the FC-GBCO cathode on a Ce0.9Gd0.1O1.95 (CGO) electrolyte. An electrolyte supported (300 μm thick) single-cell configuration of FC-GBCO/CGO/Ni-CGO attained a maximum power density of 435 mW cm?2 at 700 °C. The unique composition of GBCO co-doped with Fe and Cu ions in the Co sites exhibited reduced TEC and enhancement of electrochemical performance and good chemical compatibility with CGO, and this composition is proving to be a potential cathode for IT-SOFCs. 相似文献