New Quenching Procedure for Preservation of Initial Polymer/Catalyst Particle Morphology in Ziegler–Natta Olefin Polymerization

Preservation of initial polymer/catalyst particle morphology under air, was examined using stopped‐flow Ziegler–Natta polymerization with various quenching conditions and post‐chemical treatments. The exposure of the initial particles to air caused the fast formation of cracks on the surface, finally leading to significant reformation of the particle shape, when polymerizing particles were washed with heptane at ?65 °C under N₂ or under CO₂. On the other hand, when the particles were washed with heptane containing an appropriate amount of tetrahydrofuran under CO₂, the particle morphology under air was almost completely maintained even after 1 h exposure. The present results are useful for various ex situ characterizations of unstable initial polymer/catalyst particles.

     

An ant-based algorithm for coloring graphs

This paper presents an ant-based algorithm for the graph coloring problem. An important difference that distinguishes this algorithm from previous ant algorithms is the manner in which ants are used in the algorithm. Unlike previous ant algorithms where each ant colors the entire graph, each ant in this algorithm colors just a portion of the graph using only local information. These individual coloring actions by the ants form a coloring of the graph. Even with the lack of pheromone laying capacity by the ants, the algorithm performed well on a set of 119 benchmark graphs. Furthermore, the algorithm produced very consistent results, having very small standard deviations over 50 runs of each graph tested.     

Radiolysis of 1-naphthol in aqueous solutions

The effects of absorbed doses, initial pH and 1-naphthol concentration onto its radiolysis in aqueous sulphuric and hydrochloric acids by gamma rays from ⁶⁰Co were investigated. Under the experimental conditions, 1-naphthol degradation yields increased with increasing the absorbed doses (0.3–3.0 kGy) and with decreasing the initial 1-naphthol concentration (20–1 ppm). It was found out that the hydrated electrons did not play any significant roles in 1-naphthol radiolysis, as the degradation yields were higher at pH₀ ~ 0.46 compared to those at pH₀ ~ 2.0–5.0. The corresponding radiolytic yields G(−1-naphthol) were (6.13 ± 1.00)) × 10⁻² and (5.11 ± 0.22) × 10⁻² μmol/J in sulphuric acids, (15.61 ± 3.85) × 10⁻² and (4.76 ± 0.48) × 10⁻² μmol/J in hydrochloric acids. 1-Naphthol degradation rates could be described by the kinetic equations of pseudo-first-order reactions. An empirical relation between the observed reaction constants k _D and the initial 1-naphthol concentrations was established, enabling to predict the absorbed doses required for a given treatment efficiency. Three products of 1-naphthol degradation were revealed using an HPLC/UV procedure.     

Reaction of t-butoxy radicals with norbornadiene

95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time.     

The Kirkendall Effect for Engineering Oxygen Vacancy of Hollow Co3O4 Nanoparticles toward High‐Performance Portable Zinc–Air Batteries

Structure and defect control are widely accepted effective strategies to manipulate the activity and stability of catalysts. On a freestanding hierarchically porous carbon microstructure, the tuning of oxygen vacancy in the embedded hollow cobaltosic oxide (Co₃O₄) nanoparticles is demonstrated through the regulation of nanoscale Kirkendall effect. Starting with the embedded cobalt nanoparticles, the concentration of oxygen‐vacancy defect can vary with the degree of Kirkendall oxidation, thus regulating the number of active sites and the catalytic performances. The optimized freestanding catalyst shows among the smallest reversible oxygen overpotential of 0.74 V for catalyzing oxygen reduction/evolution reactions in 0.1 m KOH. Moreover, the catalyst shows promise for substitution of noble metals to boost cathodic oxygen reactions in portable zinc–air batteries. This work provides a strategy to explore catalysts with controllable vacancy defects and desired nano‐/microstructures.     

New indications of potential rat intestinal α-glucosidase inhibition by Syzygium zeylanicum (L.) and its hypoglycemic effect in mice

Research on Chemical Intermediates - Natural α-glucosidase inhibitors (aGIs) have been considered effective agents for type 2 diabetes management. In this study, Syzygium zeylanicum (L.)...     

A TQFT Associated to the LMO Invariant of Three-Dimensional Manifolds

We construct a Topological Quantum Field Theory associated to the universal finite-type invariant of 3-dimensional manifolds, as a functor from a category of 3-dimensional manifolds with parametrized boundary, satisfying some additional conditions, to an algebraic-combinatorial category. This is built together with its truncations with respect to a natural grading, and we prove that these TQFTs are non-degenerate and anomaly-free. The TQFT(s) induce(s) a (series of) representation(s) of a subgroup of the Mapping Class Group that contains the Torelli group. The N = 1 truncation is a TQFT for the Casson-Walker-Lescop invariant. The results of this article were obtained when the authors were at the Department of Mathematics, State University of New York at Buffalo, Buffalo, NY 14260-2900, USA.     

On denominators of the Kontsevich integral and the universal perturbative invariant of 3-manifolds

 The integrality of the Kontsevich integral and perturbative invariants is discussed. It is shown that the denominator of the degree n part of the Kontsevich integral of any knot or link is a divisor of (2!3!…n!)⁴(n+1)!. We prove this by establishing the existence of a Drinfeld's associator in the space of chord diagrams with special denominators. We also show that the denominator of the degree n part of the universal perturbative invariant of homology 3-spheres is not divisible by any prime greater than 2n+1. Oblatum 20-VI-1997 & 28-IV-1998 / Published online: 12 November 1998