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31.
P.M.?Kosaka Y.?Kawano M.C.?Salvadori D.F.S.?PetriEmail author 《Cellulose (London, England)》2005,12(4):351-359
The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions
prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy
(AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and
after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close
to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps
dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after
annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation
at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified
in order to evaluate the possibility of applying such films as selective support for biomolecules. 相似文献
32.
Mycotoxins are secondary metabolites, formed by the action of fungi on agricultural crops in the field or during storage. These metabolites are highly toxic to animals and humans and high levels have been measured in agricultural crops. In order to evaluate human risks due to ingestion of mycotoxin-contaminated food different methods have been developed for analysis of mycotoxins in cereals and maize. In this project the focus was on mycotoxins in agricultural soil and the fate of these toxins in the soil-water-plant system. Two different mycotoxins were selected in the study: zearalenone (ZON) produced by species of Fusariumor Aspergillusand ochratoxin A (OTA) produced by species of Penicillium. We developed a method for analysis of these toxins in soil. Soil samples were extracted with methanol-water (9:1) and purified by solid-phase extraction (SPE, C8-columns). The final extract was analysed using high-pressure liquid chromatography (HPLC) with fluorescence detection. A Phenyl Hexyl column was used to separate the toxins. The detection limits obtained were 0.1 and 1.0 microg kg(-1) dry weight (dw) for OTA and ZON, respectively. The developed method has been used for analysis of different soils in connection with growth chamber experiments. The soil types used in the growth chamber experiments were a sandy soil, a sandy clay soil, and a soil with high content of organic matter. The recovery was determined as 85.8 and 93.4% and the repeatability to 5.1 and 12.8% for OTA and ZON, respectively. The reproducibility obtained was 8.5 and 15.0% for soil samples, representing concentration levels from 0.2-30 microg kg(-1) dw (OTA) and from 1.0-100 microg kg(-1) dw (ZON). 相似文献
33.
34.
Based upon a thermodynamical approach, the generalized Onsager type of relaxation of van der Waals networks is presented. By linearly and identically coupling the set hidden variables to the network, the memory function of the system can be related to the equilibrium strain-energy function. The relaxation behavior of real networks on stretching can quantitatively be described by means of a distribution of relaxation times known from small strain experiments. Some new and interesting conclusions are discussed as to how the macroscopically non-linear visco-elastic response might be interpreted. 相似文献
35.
36.
Th. F. Tadros 《Colloid and polymer science》1980,258(4):439-446
Summary The adsorption isotherms of lignosulphonates with various degrees of sulphonation (0.5, 1,0, 2.0 and 4.0 moles per 840 unit weight of lignin) were measured on polystyrene latex particles from aqueous solution at 25 °C. The results showed that the lignin with the lowest degree of sulphonation gave the highest adsorption. The lignin with 1.0 and 2.0 degrees of sulphonation gave similar adsorption which was lower than that obtained with the half sulphonated lignin. However, further increase in degree of sulphonation resulted in an increase in the adsorption.Adsorption layer thickness measurements showed that the lignosulphonate with half degree of sulphonation gave thicker layers than that with 2.0 moles sulphonation. Increasing electrolyte (NaCl and CaCl,) concentration resulted in a decrease in the adsorbed layer thickness. Microelectrophoresis at 25 °C, showed only small differences in the zeta potential as a function of degree of sulphonation. Addition of electrolytes (KCl, Na2SO4 and CaCl2) showed a reduction in the zeta potential. Flocculation by salts of various valence types, namely KCl, Na2SO4 and CaCl2 showed that the critical flocculation concentration (C.F.C.) decreases in the order KCl > Na2SO4 > CaCl2. The change in degree of sulphonation had only a marginal effect on the C.F.C.
Zusammenfassung Die Isothermen der Adsorption von Lignosulfonaten mit verschiedenen Sulfonierungsgraden (S = 0,5, 1,0, 2,0 und 4,0 Mole pro 840 Gewichtseinheit des Lignins) an PolystyrolLatex-Teilchen in wäßriger Lösung wurden bei 25 °C gemessen. Hiernach wird Lignin mit den niedrigsten S-Werten am stärksten adsorbiert. Lignine mitS = 1,0 und 2,0 zeigen ähnliche Adsorption; sie ist aber kleiner als die fürS = 0,5. Mit weiter steigendemS nimmt die Adsorption zu.Aus der Messung der Dicke der Adsorptionsschicht folgt, daß fürS = 0,5 größer als fürS = 2,0 ist. Bei wachsendem Zusatz von NaCl oder CaCl2 fällt ab. Nach Mikroelektrophorese-Messungen bei 25 °C hängt das -Potential nur wenig vonS ab. fällt durch die Gegenwart von KCl, Na2SO4 oder CaCl2 ab. Mit den gleichen Salzen erfolgt eine Ausflockung, wobei die kritische Flockungskonzentration CFC in der Reihenfolge KCl, Na2SO4, CaCl2 abnimmt; CFC ändert sich nur wenig mitS.相似文献
37.
Selenomethionine contents of NIST wheat reference materials 总被引:1,自引:0,他引:1
Values of the total selenium and selenomethionine (Semet) content of four wheat-based reference materials have been obtained by gas chromatography-stable isotope dilution mass spectrometry methods. The total Se method is an established one, and the results obtained with it are consistent with previously-assigned values. The Semet method (previously reported by our laboratory) is based on reaction with CNBr. Our data indicate that the four wheat samples (wheat gluten, durum wheat, hard red spring wheat, and soft winter wheat), though having a 30-fold range in total Se content, all have about 45% of their total Se values in the form of selenomethionine. Investigation of the CNBr-based method suggests that additional experiments are needed to verify that all selenomethionine in the wheat samples is accounted for, but also indicates that the values obtained are within 15% of the true values. As the form in which Se occurs in foods and dietary supplements is important from a nutritional perspective, adding information about Se speciation to total Se values in appropriate reference materials makes these materials more valuable in relevant analytical work. 相似文献
38.
J.?R.?Tolchard J.?E.?H.?Sansom P.?R.?SlaterEmail author M.?S.?Islam 《Journal of Solid State Electrochemistry》2004,8(9):668-673
Recently, high oxide ion conduction has been observed in the apatite-type systems La9.33+x(Si/Ge)6O26+x/2, with conductivities approaching and even exceeding that of yttria-stabilized zirconia. The Ge-based phases have been reported to suffer from Ge loss and undergo irreversible structural changes on sintering at the high temperatures required to obtain dense pellets. In this paper we discuss doping studies (Ba, Bi for La) aimed at stabilizing the hexagonal apatite lattice to high temperature, and/or lowering the synthesis and sintering temperatures. The results show that doping with Ba helps to stabilize the hexagonal lattice at high temperatures, although Ge loss appears to still be a problem. Conductivity data show that, as previously reported for the Si-based systems, non-stoichiometry in the form of cation vacancies and/or oxygen excess is required to achieve high oxide ion conduction in these Ge-based systems. Neutron diffraction structural data for the fully stoichiometric phase La8Ba2Ge6O26 shows that the channel oxygen atoms show little anisotropy in their thermal displacement parameters, consistent with the low oxide ion conductivity of this phase. Bi doping is shown to lower the synthesis and sintering temperatures, although the presence of Bi means that these samples are not stable at high temperatures under reducing conditions.Presented at the OSSEP Workshop Ionic and Mixed Conductors: Methods and Processes, Aveiro, Portugal, April 10–12, 2003 相似文献
39.
This study describes a new methodology by which the concentrations of non-protein (NP) thiols glutathione (GSH), cysteine (CSH), N-acetylcysteine (AcCSH), and protein (P) thiols (PSH), as well as the contribution of these components to symmetric and mixed disulfides (NPSSR, NPSSC, NPSSCAc, PSSR, PSSC, PSSCAc, PSSP) can reliably be measured. The methodology consists of a strict sequence of methods which are applied to every sample. Free thiols at any given state of the procedure are measured by Ellmans assay, the CSH fraction is measured by its unique response in the ninhydrin assay, AcCSH is selectively measured with ninhydrin after enzymatic deacylation, proteins are separated from non-protein thiols/disulfides by precipitation with trichloroacetic or perchloric acid, disulfides are reduced into free thiols with borohydride, mixed disulfides between a protein and a non-protein component are measured by extracting the non-protein thiol from the protein pellet after borohydride treatment, and protein thiols/disulfides are measured after resolubilization of the protein pellet.When this method was applied to animal and fungal tissue, new molecular indicators of the thiol redox state of living cells were identified. The findings of the present study clearly show that the new parameters are very sensitive indicators of redox state, while at the same time the traditional parameters GSH and GSSG often remain constant even upon dramatic changes in the overall redox state of biological tissue. Therefore, unbiased assessment of the redox state also requires explicit measurement of its most sensitive thiol indicators.Electronic Supplementary Material Supplementary material is available in the online version of this article at . A link in the frame on the left on that page takes you directly to the supplementary material. 相似文献
40.
The present paper reports on exfoliated graphite (EG) used for the cyclic electrochemical process of phenol oxidation in alkaline solution. It is shown that the electrochemical activity of anode-produced EG decreases considerably in the second cycle due to the deposition of an oligomer film, composed of the products of phenol oxidation, on the EG surface. Thermal treatment of the inactive graphite anode in air at 500 °C provided a regenerated material of activity three times higher for the first cycle and 2.6 times higher for three cycles as compared to the original anode. The reason for such a behavior is assigned to a carbon film formed on the EG surface during the carbonization/oxidation processes involving the products of phenol oxidation. Comparative studies showed that electroactivity of the original EG can also be enhanced if before the process of phenol oxidation the original EG is activated by heat treatment. Unfortunately, the electrochemical activity of the product of such a treatment is higher only for the first cycle of phenol oxidation and drops dramatically in the following cycles.Contribution to the 3rd Baltic Conference on Electrochemistry, Gdask-Sobieszewo, 23–26 April 2003. Dedicated to the memory of Harry B. Mark, Jr. (28 February 1934–3 March 2003) 相似文献