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51.
Chun-Yang Jina Dao-Dao Zhang Tetsuya Oguma Shi-Xiong Qian 《Journal of inclusion phenomena and macrocyclic chemistry》1996,24(4):301-310
Cycloisomalto-heptaose (CI-7) and cycloisomalto-octaose (CI-8) are two novel cyclodextrans. Treatment with C60 or C70 by kneading leads to the formation of four distinct water-soluble inclusion complexes: CI-7/C60 (2: 1), CI-8/C60 (2: 1), CI-7/C70 (2: 1) and CI-8/C70 (2: 1). Their formation and structures have been examined by UV vis spectroscopy, X-ray powder diffraction and fluorescence spectral studies. The reaction is a reversible process. 相似文献
52.
A simple, specific and sensitive micro-scale method for the assay of the antiarrhythmic agent mexiletine in human serum is described. The method uses high-performance liquid chromatography, with pre-column fluorimetric derivatization by fluorescamine. Following extraction with diethyl ether, mexiletine and 4-methylmexiletine (an internal standard) were derivatized with fluorescamine under weakly alkaline condition (pH 9.0) and chromatographed on a reversed-phase column with aqueous methanol-2-propanol as the mobile phase. The two fluorescent derivatives of mexiletine and the internal standard were separated as clear single peaks, and no interfering peaks were observed on the chromatograms. The detection limit for mexiletine was 0.005 micrograms/ml from only 100 microliters of serum, and the calibration curves in the range 0.01-5 micrograms/ml were linear, with an overall coefficient of variation of less than 5%. The analytical recovery of a known amount of mexiletine added to serum was almost 100%. This method proved to be effective in the rapid monitoring of the serum concentrations in patients who received this potent antiarrhythmic drug. 相似文献
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[reaction: see text] Diphenylphosphine oxide and related P(O)H compounds react with propargyl alcohols at room temperature in the presence of a catalytic amount of Ni(0) complex and Ph(2)P(O)OH to produce high yields of phosphinoyl 1,3-dienes though an efficient in situ dehydration process. 相似文献
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Asymmetric monobenzoylation reactions of cyclic meso-1,3- and 1,4-diols were catalyzed by a phosphinite derivative of quinidine to afford the corresponding monobenzoylated diol with good yield and enantioselectivity. [reaction: see text] 相似文献
59.
Yoshiki Chujo Tetsuya Nakamura Yuya Yamashita 《Journal of polymer science. Part A, Polymer chemistry》1990,28(1):59-65
Mercapto-16-crown-5 was prepared starting from tetraethyleneglycol and 3-chloro-2-chloromethyl-1-propene. Radical polymerization of methyl methacrylate was carried out in the presence of mercapto-16-crown-5 as a chain transfer agent to give crown ether-terminated poly(methyl methacrylate). The end crown group was characterized by IR and 1H-NMR spectra. Sodium cation was selectively extracted by this crown-containing polymer. The molecular weight of the obtained polymer had influence upon the ability of extraction of sodium cation. 相似文献
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