全文获取类型
收费全文 | 1151篇 |
免费 | 43篇 |
国内免费 | 6篇 |
专业分类
化学 | 882篇 |
晶体学 | 11篇 |
力学 | 16篇 |
数学 | 77篇 |
物理学 | 214篇 |
出版年
2023年 | 10篇 |
2022年 | 9篇 |
2021年 | 15篇 |
2020年 | 12篇 |
2019年 | 22篇 |
2018年 | 23篇 |
2017年 | 18篇 |
2016年 | 23篇 |
2015年 | 34篇 |
2014年 | 36篇 |
2013年 | 60篇 |
2012年 | 91篇 |
2011年 | 102篇 |
2010年 | 41篇 |
2009年 | 42篇 |
2008年 | 82篇 |
2007年 | 65篇 |
2006年 | 66篇 |
2005年 | 73篇 |
2004年 | 59篇 |
2003年 | 47篇 |
2002年 | 59篇 |
2001年 | 12篇 |
2000年 | 15篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 9篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 12篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1981年 | 9篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 3篇 |
1971年 | 2篇 |
1968年 | 2篇 |
1961年 | 2篇 |
1960年 | 2篇 |
排序方式: 共有1200条查询结果,搜索用时 15 毫秒
31.
Yoshitomo Kashiwagi Yumiko Takamori Kentaro Yoshida Tetsuya Ono 《Electroanalysis》2013,25(12):2575-2577
This paper describes the electrocatalytic oxidation of amines on TEMPO (2,2,6,6‐tetramethylpiperidine‐1‐oxyl)‐modified electrodes prepared by electrochemical copolymerization of TEMPO precursor containing pyrrole side chain and 2,2′‐bithiophene. The modified electrode exhibits electrocatalytic activity for the oxidation of primary and secondary amines. Cyclic voltammetric studies showed that the peak current of the cyclic voltammogram increased linearly with increasing concentration of amine in the sample solution. 相似文献
32.
Sadayuki Mori Tetsuya Karita Koichi Komatsu Nobuyuki Sugita Terence S. M. Wan 《合成通讯》2013,43(9):1475-1482
Under high pressure conditions, fullerene C60 smoothly reacts with 2H-pyran-2-one to give a [4+2] cycloadduct, which can be reduced to an alcohol derivative. 相似文献
33.
Misa Sugino Keisuke Hatanaka Tetsuya Miyano Ichiro Hisaki Mikiji Miyata Aya Sakon Hidehiro Uekusa Norimitsu Tohnai 《Tetrahedron letters》2014
An organic salt composed 9,10-bis(4-aminophenyl)anthracene and hypophosphorous acid emits yellow-green fluorescence in the crystalline state. The salt also gives water inclusion crystal which provides blue-green fluorescence. Single X-ray crystal studies revealed that water molecules induced the fluorescence change resulting from reaggregation of molecular packing. 相似文献
34.
Dr. Chunlin Chen Prof. Zhongchang Wang Dr. Mitsuhiro Saito Dr. Tetsuya Tohei Prof. Yoshiro Takano Prof. Yuichi Ikuhara 《Angewandte Chemie (International ed. in English)》2014,53(6):1543-1547
Atomic‐resolution imaging of beam‐sensitive biominerals is extremely challenging, owing to their fairly complex structures and the damage caused by electron irradiation. Herein, we overcome these difficulties by performing aberration‐corrected electron microscopy with low‐dose imaging techniques, and report the successful direct atomic‐resolution imaging of every individual atomic column in the complex fluorapatite structure of shark tooth enameloid, which can be of paramount importance for teeth in general. We demonstrate that every individual atomic column in shark tooth enameloid can be spatially resolved, and has a complex fluorapatite structure. Furthermore, ab initio calculations show that fluorine atoms can be covalently bound to the surrounding calcium atoms, which improves understanding of their caries‐reducing effects in shark teeth. 相似文献
35.
Tomoko Nagao Masayoshi Isozaki Tetsuya Fujimoto Iwao Yamamoto 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8-9):1975-1976
The reaction of a cyclic phosphonium ylide [ 1 ] with enoate 2 gives a hydroazulene derivative with stereoselectivity. 相似文献
36.
Yoshio Aso Shoji Nishiguchi Tetsuya Jigami Tetsuo Otsubo Fumio Ogura 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):417-418
Several well-defined 3,4-thienylene-ethynylene oligomers with different chain lengths have been synthesized and characterized. X-Ray crystallographic analyses proved their unique, totally helical conformations. 相似文献
37.
Daisuke Saeki Takeshi Yamada Yasuko In Tetsuya Kajimoto Reiko Tanaka Yota Iizuka Takahisa Nakane Akihito Takano Kazuo Masuda 《Tetrahedron》2013,69(5):1583-1589
Novel 5 lupane-type of triterpenois, i.e., 3β-acetoxy-18α,19α-epoxylupan-21β-ol (1), 18α,19α-epoxy-21β-hydroxylupan-3-one (2), lup-18-ene-3,21-dione (3), lupa-18,21-dien-3β-yl acetate (4), and (17S)-17,18-seco-lup-19(21)-ene-3,18,22-trione (5), named officinatrione, as well as 16 known compounds from the roots of Taraxacum officinale collected in Takatsuki city, Osaka, Japan. Of the above compounds, 5 was the first lupane-type triterpene, of which the D-ring was open to form a nine-membered ring. Compounds 2 and 5 exhibited moderate cytotoxic activities against L1210 cell line (IC50 10.5 and 10.1 μM). 相似文献
38.
Tetsuya Kajimoto Yuichi Ishioka Takahiro Katoh 《Journal of carbohydrate chemistry》2013,32(8-9):469-495
p‐Dodecylbenzenethiol (1) and p‐octyloxybenzenethiol (2) were synthesized as new odorless benzenethiols. Moreover, preparation of novel 1‐thioglycosides using 1 and 2 as well as their application for glycosylation reactions was performed. As a result, it was found that these 1‐thio‐glycosides were excellent glycosyl donors, and especially 2‐thio‐sialoside prepared from 1 and 2 afforded the best result to date in terms of α‐ and β‐selectivity in the sialylation where only the single C‐3 hydroxyl group of acceptor D‐galactopyranoside was free. All procedures from the preparation of thioglycosides to glycosylation reaction were attainable under completely odorless conditions. 相似文献
39.
40.
Scaling symmetry of -type Drinfel’d–Sokolov hierarchy is investigated. Applying similarity reduction to the hierarchy, one can obtain the Schlesinger
equation with (n + 1) regular singularities. Especially in the case of n = 3, the hierarchy contains the three-wave resonant system and the similarity reduction gives the generic case of the Painlevé
VI equation. We also discuss Weyl group symmetry of the hierarchy.
相似文献