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151.
Tadatsugu Hatori Tetsuo Kamimura Yoshi H. Ichikawa 《Physica D: Nonlinear Phenomena》1985,14(2):193-202
An analytical tool is given to study the statistical properties of the radial twist map, Xn+1 = Xn + α(Yn+1) and Yn+1 = Yn + Af (Xn), with arbitrary rotation number α(Y) and arbitrary periodic force f(X). The case for which f(X) = sin 2 πX and with arbitrary α is treated in the region of large A. The turbulent diffusion coefficient D for the chaotic orbit relaxes as to , except for the case of the standard map, where the eventual value of D is different from . 相似文献
152.
4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) is a well-known fluorophore, with a high molar extinction coefficient and high fluorescence quantum efficiency (Phi(fl)). Furthermore, its structure can be modified to change its excitation and emission wavelengths. However, little work has been done on the structural modification of fluorines at the B-4 position with other functional groups. We synthesized 4-methoxy-substituted BODIPY derivatives in satisfactory yields, and found that they exhibited improved solubility in aqueous solution. Moreover, their oxidation and reduction potentials were greatly decreased without any change in their absorbance and fluorescence properties. These features of 4-substituted BODIPYs may be useful for developing novel fluorescence probes based on the intramolecular photoinduced electron transfer (PeT) mechanism, because it is possible to optimize the PeT process precisely by modulating the electrochemical properties of the fluorophore. The value of this approach is exemplified by its application to the development of a highly sensitive and pH-independent fluorescence probe for nitric oxide. 相似文献
153.
Tetsuo Tsuchiya Akio Watanabe Tomohiko Nakajima Toshiya Kumagai 《Applied Physics A: Materials Science & Processing》2010,101(4):681-684
Europium-doped yttrium oxide (Y2O3:Eu) thin films were successfully deposited on quartz and ITO/glass substrates by excimer-laser-assisted metal organic deposition
(ELAMOD) at low temperatures. The effects of laser wavelength and thermal temperature on the films’ crystallinity and photoluminescence
properties were investigated. Films irradiated by an ArF laser at 80 mJ/cm2 and 400–500°C were highly crystallized compared with those prepared by thermal MOD. In contrast, when the film was irradiated
by a KrF laser at 500°C, no crystalline Y2O3:Eu was formed. The Y2O3:Eu film irradiated by the ArF laser at 80 mJ/cm2 and 500°C showed typical PL spectra of Eu3+ ions with cubic symmetry and a 5D0→7F2 transition at ∼612 nm. The PL intensity at 612 nm was much higher for the film prepared with ELAMOD than for that prepared
by the thermal-assisted process, and the photoemission intensity of the film prepared with ELAMOD strongly depended on the
substrate material. 相似文献
154.
Pattern dynamics plays a fundamental role in biological functions from cell to organ in living systems, and the appearance of rotating waves can lead to pathological situations. Basic dynamics of rotating waves of contraction-relaxation activity under local perturbation is studied in a newly developed protoplasmic droplet of the Physarum plasmodium. A light pulse is applied by irradiating circularly a quarter of the droplet showing a single rotating wave. The oscillation pattern changes abruptly only when the irradiation is applied at a part of the droplet near the maximal contraction. The abrupt changes are as follows: the rotating wave disappears or is displaced when the irradiation area is very close to the center of the rotating wave, while new rotating waves are created when the irradiation area is far from the center of the rotating wave. These results support the hypothesis that the phase response curve has a discontinuous change (type 0 resetting) from delay to advance around the maximal contraction. The significance of the results is discussed in relation to “vulnerability” in excitable media and biological systems in general. 相似文献
155.
Electrophoretic measurements of micellar mobility have revealed that polyoxyethylated nonionic surfactant micelles have negative zeta potential in various electrolytes, indicating that the partition of anions into the micelle dominates the entire electrolyte partition and the induced surface potential of the micelle. Although an excess of a negative charge is thus revealed in the micelle, it is uncertain whether anions are preferably solvated in the micelles or cations are expelled from the micelles. To determine the solvation energies of single ions in the hydrophilic layer of the micelle, we have performed ion transfer voltammetric measurements at microinterfaces between nitrobenzene and aqueous tetraethyleneglycol solution, which acts as a model for the palisade layer of the micelles. The cooperative utilization of these different methods has allowed us to determine the Gibbs free energy of transfer of a single ion without an extrathermodynamic assumption. On the basis of the resulting values, the partition of ions and the zeta potential induced by the imbalance of anionic and cationic partition have been quantitatively explained. 相似文献
156.
It is attempted to model a displacive phase transformation by Continuous Displacement Cluster Variation Method. The main focus of the present study is placed on distorted to non-distorted phase transformation in the two-dimensional square lattice. The entropy is formulated within the single-site approximation (point approximation), while the pair-wise atomic interaction energies are combined to stabilize a distorted phase at low temperatures. The distorted to non-distorted phase transformation in the present study is of the second order, and the calculated distribution of atoms suggests that the transformation is of the displacive type in the classification. 相似文献
157.
Tone Takahashi Hideki Tomita Motoi Nakayama Yoshitaka Adachi Volker Sonnenschein Tetsuo Iguchi Klaus Wendt 《Hyperfine Interactions》2013,218(1-3):133-138
2D coordination polymer iron(II) spin crossover complexes containing 3,5-lutidine with host framework Fe(3,5-lutidine)2Ni(CN)4were synthesized. Their spin crossover properties were studied by temperature dependent 57Fe Mössbauer spectroscopy. Materials show gradual incomplete spin crossover with distinct thermochromism, while only 25 % of iron(II) ions are switched to the low spin state at 80 K, as determined by a detailed 57Fe Mössbauer study. 相似文献
158.
Takaaki Takatsuka Hideki Tomita Tetsu Sonoda Volker Sonnenschein Chika Sakamoto Hiroki Mita Takuma Noto Chikara Ito Shigetaka Maeda Tetsuo Iguchi Michiharu Wada Klaus Wendt Iain Moore 《Hyperfine Interactions》2013,216(1-3):41-46
93Nb(n, n′)93mNb reaction allows retrospective estimation of integrated fast neutron dose in nuclear reactor. We proposed isomer-selective trace analysis of 93mNb by Resonance Ionization Mass Spectrometry (RIMS) combined with a gas-jet atomic source and an injection locked Ti:Sapphire laser system operated at several kHz. Resonant ionization spectroscopy of Nb in gas-jet using Ti:Sapphire laser was demonstrated. 相似文献
159.
In the atomic absorption spectrometry with the long absorption tube using a hydrogen-air flame, only the total consumption type of the burners, e.g., Beckman1 or ring burners2, have been used for the input of a sample solution to the flame. The use of the indirect input method with nebulization chamber has never been attempted, though, by use of a commercially available apparatus with nebulization chamber, the large increase of the sensitivity has been easily obtained by heating the chamber and nebulizing air3–5. 相似文献
160.
Tetsuo Ogawa 《Phase Transitions》2013,86(1-2):93-128
Photoinduced structural phase transitions via excited electronic states are discussed theoretically using a one-dimensional model composed of localized electrons and lattices under the adiabatic or diabatic approximation. We show that the global structural change by photoexcitation only at a site is possible, and we clarify conditions for the occurrence of such phenomena. Spatiotemporal dynamics of nonequilibrium first-order phase transitions is also investigated in detail in terms of photoinduced nucleations and domino processes of the domain boundaries (domain walls), which are in striking contrast to the mean-field dynamics. In the adiabatic regime, after the spontaneous emission of a photon, an initial local structural change (i) remains locally, (ii) induces cooperatively a global structural change, or (iii) disappears and returns to the initial phase. Dynamical features of the case (ii) are characterized by the deterministic (semichaotic) domino process; domain walls between the two phases move determinis-tically at a constant velocity (with changing speed) without further spontaneous emissions in the case of strong (weak) dissipation. In the diabatic regime, similar three types of structural change exist. The domain-wall dynamics is described as the stochastic domino process, which is accompanied by the successive radiative transitions. A new theoretical treatment is also proposed to study crossover between the adiabatic and diabatic regimes. 相似文献