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991.
Interest in the synthesis of composite colloidal particles consisting of a core and shell with different compositions stems
from the fact that such particles can be useful in processes where the properties of both core (e.g., size and shape homogeneity,
ease of preparation in large amounts, magnetic characteristics, etc.) and shell (interfacial properties, porosity, chemical
stability, etc.) might be of interest. However, the applicability must be based on a proper characterization of those properties.
In this work, colloidal spheres of hematite (α-Fe2O3) were used as nuclei of mixed particles where the shell is yttrium oxide. The electrical properties of the aqueous interface
are compared to those of the pure oxides by means of potentiometric titration of their surface charge and potential against
pH, as a function of indifferent electrolyte concentration. It is found that the mixed particles efficiently mimic yttrium
oxide, since the behavior of their surface electrical characteristics closely resembles that of the latter compound. Differences
are found, however, that can be ascribed to an incomplete or porous coverage, but such divergences are of little significance
when an overall comparison is carried out.
Received: 30 January 2001 Accepted: 11 July 2001 相似文献
992.
Ponticelli Gustavo Cocco M. Teresa Congiu Cenzo Onnis Valentina Ianelli Sandra Cossu Francesco 《Transition Metal Chemistry》2001,26(1-2):24-27
CoII, NiII and CuII chloride complexes with acetamidrazone derivatives (L
1
)–(L
8
) have been prepared, by reacting the corresponding metal chloride with the ligand in a 1:2 ratio, and characterised by chemical analysis and physical measurements. The ligand behaviour and the geometry have been assigned on the basis of i.r. spectroscopy, electronic reflectance spectra and molar conductivity values and only, where possible, the geometry has been confirmed as octahedral by X-ray structure determination. Complexes cytotoxicity on a human cellular line of adenocarcinoma was also tested. Three of the complexes present a weak cytotoxicity in vitro. 相似文献
993.
Giraudo Maria Teresa Sacerdote Laura Zucca Cristina 《Methodology and Computing in Applied Probability》2001,3(2):215-231
A reliable Monte Carlo method for the evaluation of first passage times of diffusion processes through boundaries is proposed. A nested algorithm that simulates the first passage time of a suitable tied-down process is introduced to account for undetected crossings that may occur inside each discretization interval of the stochastic differential equation associated to the diffusion. A detailed analysis of the performances of the algorithm is then carried on both via analytical proofs and by means of some numerical examples. The advantages of the new method with respect to a previously proposed numerical-simulative method for the evaluation of first passage times are discussed. Analytical results on the distribution of tied-down diffusion processes are proved in order to provide a theoretical justification of the Monte Carlo method. 相似文献
994.
Kui Huang Teresa A. Croce Sharon K. Hamilton Chinessa T. Adkins Billie L. Evans III Eva Harth 《Macromolecular Symposia》2007,255(1):20-23
Summary: The development of suitable delivery systems for intracellular delivery of proteins, peptides and other bioactive materials opens the possibility to establish refined strategies for small drug delivery, gene delivery and vaccination. We present the assembly of advanced drug delivery systems from tailored building blocks to scaffolds and bioactive cargos to afford targeting and transport across biological barriers. In particular, the utilization of novel molecular transporter will advance the bioavailability of small and macromolecular drugs that show targeted intracellular delivery. 相似文献
995.
The purpose of this work is to establish the existence of capacity solutions to the thermistor problem under certain weak assumptions on data. Also, some numerical results are shown. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
996.
Patrícia Pinto Maria J. Calhorda Vitor Félix Teresa Avilés Michael G. B. Drew 《Monatshefte für Chemie / Chemical Monthly》2000,3(4):1253-1265
The reaction between [Cu(NCMe)4][PF6] and 1,1′-bis-(diphenylphosphino)-ferrocene (dppf) in several ratios, solvents, and conditions led to the synthesis and structural characterization of the Cu(I) complexes [Cu(dppf)(Odppf)][PF6] (1), [(dppf)Cu(μ-dppf)Cu(dppf)][PF6]2 (2), and [(dppf)Cu(μ-Cl)2Cu(dppf)] (3). Although 1 and the cation in 2 were known, the first was structurally characterized for the first time, exhibiting a significant asymmetry in the coordination sphere of Cu(I) owing to the presence of oxygen. In 2, the PF6 − anion led to an interesting crystal packing with large open channels containing water. Finally, DFT calculations on a model of 3 showed that its HOMO exhibits, besides Fe, a significant Cu and Cl character, which is reflected in its electrochemical properties. 相似文献
997.
998.
Controlled ring‐opening polymerization of trimethylene carbonate and access to PTMC‐PLA block copolymers mediated by well‐defined N‐heterocyclic carbene zinc alkoxides
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Four novel Zinc–NHC alkyl/alkoxide/chloride complexes ( 4 , 5 , 9 and 9′ ) were readily prepared and fully characterized, including X‐ray diffraction crystallography for 5 and 9′ . The reaction of N‐methyl‐N′‐butyl imidazolium chloride ( 3.HCl ) with ZnEt2 (2 equiv.) afforded the corresponding [(CNHC)ZnCl(Et)] complex ( 4 ) via a protonolysis reaction, as deduced from NMR data. The alcoholysis of 4 with BnOH led to quantitative formation of the dinuclear Zn(II) alkoxide species [(CNHC)ZnCl(OBn)]2 ( 5 ), as confirmed by X‐ray diffraction analysis. The NMR data are in agreement with species 5 retaining its dimeric structure in solution at room temperature. The protonolysis reaction of N‐(2,6‐diisopropylphenyl)‐N′‐ethyl methyl ether imidazolium chloride ( 8.HCl ) with ZnEt2 (2 equiv.) yielded the [(CNHC)ZnCl(Et)] species 9 . The latter was found to be reactive with CH2Cl2 in solution and to cleanly convert to the corresponding Zn(II) dichloride [(CNHC)ZnCl2]2 ( 9′ ), whose molecular structure was also elucidated using X‐ray diffractometry. Unlike Zn(II)–NHC alkoxide species 1 and 2 , which contain a NHC flanked with an additional N‐functional group (i.e. thioether and ether, respectively), the Zn(II) alkoxide species 5 incorporates a monodentate NHC ligand. The Zn(II) complexes 1 , 2 and 5 were tested in the ring‐opening polymerization (ROP) of trimethylene carbonate (TMC). All three species are effective initiators for the controlled ROP of trimethylene carbonate, resulting in the production of narrow disperse PTMC material. Initiator 1 (incorporating a thioether moiety) was found to perform best in the ROP of TMC. Notably, the latter also readily undergoes the sequential ROP of TMC and rac‐LA in the presence of a chain‐transfer agent, leading to well‐defined and high‐molecular‐weight PTMC/PLA block copolymers. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
999.
Isabel Álvarez-Martos M. Teresa Fernández-Abedul Adela Anillo José Luis G. Fierro Francisco Javier García Alonso Agustín Costa-García 《Analytica chimica acta》2012
A new modification of glass electrophoresis microchips based on poly (acrylic) acid immobilization has been performed. It is based on the reaction of PAA with an amine functionalized surface, obtained through the bifunctional reagent 3-aminopropyl triethoxysilane. Parameters affecting all the three steps involved: surface activation, silanization and polymer immobilization were optimized employing soda-lime glass plates. Characterization by SEM and XPS was carried out. Application of the modified microchips to the separation of a model system: dopamine (D), epinephrine (E) and norepinephrine (NE), that on the other hand are of high clinical relevance was performed employing amperometric detection. Modification is necessary for obtaining partial resolution of all the three analytes in a microchip with an effective separation length of 30 mm. Situation changes from no resolution (Rs) at all (only one peak was achieved for the mixture) to a partial resolution (Rs D–NE and Rs NE–E are 0.25 and 0.24 respectively). Microchips with 60 mm of separation channel were also modified, implying this procedure a resolution enhancement (Rs of 0.49 and 0.28 for D–NE and NE–E respectively), even when methanol is employed as organic modifier (Rs values of 0.70 (D–NE) and 0.66 (NE–E) for a 3% MeOH). 相似文献
1000.
Miguel Á. González‐Curbelo Samara Dionis‐Delgado María Asensio‐Ramos Javier Hernández‐Borges 《Journal of separation science》2012,35(2):299-307
Analytical potentiality of a modified version of the QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) method has been studied and validated for the extraction of a group of 11 pesticides (ethoprophos, cadusafos, dimethoate, terbufos, disulfoton, chlorpyrifos‐methyl, fenitrothion, pirimiphos‐methyl, malathion, chlorpyrifos and fensulfothion) and some of their metabolites (malaoxon, disulfoton sulfoxide, terbufos sulfone and disulfoton sulfone) in toasted barley and chickpea flours. The method involves separation and quantification by gas chromatography (GC) with nitrogen phosphorus detection (NPD) using triphenylphosphate as the internal standard. Matrix‐matched calibration was carried out for both flours due to the existence of a matrix effect. Linearity, recovery, precision and accuracy studies of the proposed QuEChERS‐GC‐NPD method were evaluated in each sample matrix. Mean recovery values were in the range of 73–118% with relative standard deviation values below 10%. Limits of detection of the whole method were between 0.07 and 57.39 μg/kg. The method was finally applied for the analysis of 14 samples collected in different zones of the Tenerife island. The residues of pirimiphos‐methyl were found in 13 of them, confirming its unequivocal presence by mass spectrometry. 相似文献