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931.
Photoproducts of pyridoxal-5-P, i.e., 4-pyridoxic-5-P and bis-pyridoxal-5-P, have been studied by spectroscopic methods. The spectroscopic properties of bis-pyridoxal-5-P (bis-PLP) resemble those of pyridoxal-5-P (PLP) under similar experimental conditions. The coupling of methylen hydrogens to the phosphorus atom has been shown by NMR spectroscopy. The singlet in the31P-NMR spectra and the triplet in1H-undecoupled experiments confirm the presence of the phosphate group in the 5 position of the structure of the vitamin. The effect of pH and solvent composition on the relative distribution of species of bis-pyridoxine-5-P (bis-PNP) has been investigated by absorption and fluorescence spectroscopy. The acid-base dissociation of the phosphate group is easily detected by emission spectroscopy. Bis-PNP and bis-PLP bind to the enzyme RNase A and they behave as competitive inhibitors with respect to the substrate cytidine-2-3-cyclic phosphate. The natural forms of vitamin B6, pyridoxine, and pyridoxine-5-P have no effect on the catalytic activity of the protein. Experimental evidence derived from fluorescence and inhibition experiments is consistent with the hypothesis that bis-PNP recognizes the catalytic site of RNase A. 相似文献
932.
T. Harkó 《Acta Physica Hungarica A》1996,3(1-2):115-129
The dynamics of a homogeneous, anisotropic, spatially flat Bianchi type I universe filled with a scalar field is studied. Using the usual synchronous form of the line element, general exact solutions for the Einstein field equations are obtained in the case of the exponential-potential scalar field (V=Λexp(k?)) and in the case of the Barrow-Saich potential ( $V \sim \dot \varphi ^2 $ ). Conditions under which inflation can occur are discussed and the late-time behaviour of the models is also considered. 相似文献
933.
The dilepton spectra from open charm decay inp+A reactions at $\sqrt s = 200$ AGeV are proposed to constrain gluon shadowing in nuclei. We show that the required measurements are feasible at RHIC. 相似文献
934.
Mn2(CO)10 was photolysed in the gas phase by the XeCl-excimer laser with fluence in the range 25–300 mJ/cm2 and a dye laser. The UV/VIS emission of the products was probed on a nanosecond time scale. The emission from excited states of metal atoms was detected only. The Mn atoms are predominantly formed in their ground statea
6
S
2 1/2. The absorption of one photon and the subsequent relaxation process leads to the formation ofz
6
P
J
0
(J = 11/2, 21/2, 31/2) states and emission of photons at a wavelength of 403 nm. The formation of the excited statese
8
D
5 1/2,z
6
F
4 1/2
0
ande
6
D
4 1/2 and the subsequent emission observed at wavelengths of 357, 383 and 446 nm requires the absorption of two photons by the ground-state Mn atoms. In addition, transition from thea
6
D
j (J = 11/2, 21/2) lower states were observed in the wavelength-resolved Laser-Induced Fluorescence (LIF) spectra. 相似文献
935.
M. Veselský Š. Šáro F. P. Heßberger V. Ninov S. Hofmann D. Ackermann 《Zeitschrift für Physik A Hadrons and Nuclei》1996,356(1):403-410
Velocity distributions and production cross sections of evaporation residues have been measured in the reaction20Ne+208Pb at projectile energies of 8.6, 11.4, 14.9 A.MeV. Essential deviations from statistical model of deexcitation have been
observed. Monte Carlo simulations involving emission of non-equilibrium particles have been used in order to reproduce experimental
velocity, charge and mass distributions of evaporation residues and to estimate indirectly multiplicities of pre-equilibrium
particles.
Communicated by V. Metag 相似文献
936.
A. González Arias A. del Cueto J. M. Muñoz C. de Francisco L. Torres A. G. Flores M. Zazo J. Iñiguez 《Applied Physics A: Materials Science & Processing》1996,63(5):453-459
Silica may dissolve up to about 0.05 wt% in an iron excess NiZnCo spinel matrix, affecting noticeably the magnetic properties at low and high values of the applied field. The initial permeability is reduced by about 50% with the addition of only 0.1 % SiO2, while the coercivity almost triples, without noticeable changes in porosity or grain distribution. The vacancy and Fe2+ content of the sintered material also show a considerable change. The energy associated to the transformation Fe3+ Fe2+ for the samples without SiO2 was found to be 0.41–0.42 eV, while for the samples with SiO2 additions it decreased to 0.26 eV. The changes in magnetic properties are thought to be caused, more than because of the mentioned changes in ion distribution, by the stresses and defects created in the lattice due to the very small size of the Si4+ ion, which substitutes Fe3+ ions in tetrahedral sites. The transition Fe3+ Fe2+ seems to take place exclusively in the octahedral sites. 相似文献
937.
The anisotropic homogeneous 3 is isometrically globally embedded into a nine-dimensional Euclidean or pseudo-Euclidean space. In a special case the Euclidean space is six-dimensional. The space-sections of the anti-Mach metric appear as a submanifold of theE
9. We obtain also the isometric embedding ofSO(3) with its natural Killing metric. 相似文献
938.
Studying the algebraic structure of the YangiansY(sl(2)), andY(sl(3)) we present their boson realizations. In the case ofY(sl(2)) we give the realization by using 1-canonical boson pair and two parameters and in theY(sl(3)) with 2-canonical boson pairs, two parameters and subalgebrasl(2). Substituting the realization ofU(sl(2)), we can obtain the pure boson realization by 3-canonical pairs and three parameters.Presented at the 4th Colloquium Quantum Groups and Integrable Systems, Prague, 22–24 June 1995. 相似文献
939.
R. S. Dunne A. J. Macfarlane J. A. de Azcárraga J. C. Pérez Bueno 《Czechoslovak Journal of Physics》1996,46(12):1235-1242
Theq-calculus for genericq is developed and related to the deformed oscillator of parameterq
1/2. By passing with care to the limit in whichq is a root of unity, one uncovers the full algebraic structure ofZ
n
-graded fractional supersymmetry and its natural representation.Presented at the 5th International Colloquium on Quantum Groups: Quantum Groups and Integrable Systems, Prague, 20–22 June 1996.This paper describes research supported in part by E.P.S.R.C and P.P.A.R.C. (UK) and by the C.I.C.Y.T (Spain). J.C.P.B. wishes to acknowledge an FPI grant from the CSIC and the Spanish Ministry of Education and Science. 相似文献
940.
We apply the pseudoextension mechanism, which in the undeformed case gives the centrally extended Galilei group {ie137-02} as a contraction of a trivial extensionP×U(1) of the Poincaré group, to the case of the-Poincaré algebra. As a result, the four-dimensional {ie137-03}-deformed extended Galilei algebra is obtained.Presented at the 4th Colloquium Quantum Groups and Integrable Systems, Prague, 22–24 June 1995. 相似文献