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41.
Masaru Kojima 《Tetrahedron letters》2007,48(25):4431-4436
A new fluorous benzylidene acetal protecting group was regioselectively introduced into carbohydrates, deprotected under acidic conditions, and reused. Oligosaccharides were synthesized via regioselective conversion of the fluorous acetal group to the benzyl group by traditional reaction conditions. The fluorous compounds were easily separated from non-fluorous by-products by fluorous solid phase extraction. 相似文献
42.
Phototactic responses of newly hatched silkworm larvae to monochromatic lights and their mixtures were measured to determine wavelength-dependent properties. Each fluence rate-response curve for a monochromatic light was composed of a log-linearly increasing part, a plateau and a decreasing part. Curves were classified into two groups according to the slopes of the linear parts: responses to UV-blue light (364-482 nm) and responses to green-red light (513-681 nm). Different plateau values were found for both groups. The action spectrum had its maximum at 557 nm and showed another large value at about 364 nm, and its minimum was at 447 nm. When green-orange lights (540-577 nm) were added to 557 nm, the silkworms were attracted more by the mixed lights than by the 557 nm component light only. Mixed lights of UV (364 nm) and blue (447 nm) attracted the silkworms more than either component. The magnitude of the response decreased remarkably when green light was mixed with U V or blue light. We conclude that the silkworm possesses colour vision and responds differently to green-red lights (≥ 513 nm) from UV-blue lights (≲ 482 nm). 相似文献
43.
Smiles-type free radical rearrangements of arenesulfonates and arenesulfonamides are exploited for synthetic purposes. 4-Substituted benzenesulfonates cause Smiles-type rearrangement only when substituted by an electron withdrawing group. Therefore, ipso-attack by an alkyl radical on arenesulfonates takes place in an electrophilic manner. Arenesulfonamides rearrange only when the amide nitrogen is substituted by an alkoxycarbonyl group, due to the electron withdrawing nature of this group. Sulfonates and the N-ethoxycarbonylsulfonamide derivatives of naphthalene, quinoline, and thiophene cause more rearrangement and show synthetic utility. Aromatic amino acid analogues were synthesized by Smiles-type rearrangement with moderate yields. The radical Smiles-type rearrangement of sulfonate and sulfonamide derivatives can be a useful synthetic route when we understand the electronic character of these reactions. 相似文献
44.
3,4-Dhydro-6,7-dimethoxy-4-methyl-3-oxo-quinoxaline-2-carbonyl azide is a highly senstive fluorescence derivatization reagent for primary, secondary and tertiary alcohols for high-performance liquid chromatography. Reaction conditions are optimized with benzyl alcohol, n-hexanol, cyclohexanol and 2-methyl-2-butanol. The reagent reacts with the alcohols in benzene to produce the corresponding fluorescent carbamic acid esters, which can be separated on a reversed-phase column YMC Pack C8 with aqueous methanol as eluent. the detection limits for the alchols are 2–5 fmol per 10-μl njection. The reagent also reacts with hydroxysteroids with primary, secondary and/or tertiary alcoholic group(s) to form fluorescent derivatives. Hydroxycarboxylic acids and phenols do not give any chromatographic peaks. 相似文献
45.
Torizawa T Ono AM Terauchi T Kainosho M 《Journal of the American Chemical Society》2005,127(36):12620-12626
The unambiguous assignment of the aromatic ring resonances in proteins has been severely hampered by the inherently poor sensitivities of the currently available methodologies developed for uniformly 13C/15N-labeled proteins. Especially, the small chemical shift differences between aromatic ring carbons and protons for phenylalanine residues in proteins have prevented the selective observation and unambiguous assignment of each signal. We have solved all of the difficulties due to the tightly coupled spin systems by preparing regio-/stereoselectively 13C/2H/15N-labeled phenylalanine (Phe) and tyrosine (Tyr) to avoid the presence of directly connected 13C-1H pairs in the aromatic rings. The superiority of the new labeling schemes for the assignment of aromatic ring signals is clearly demonstrated for a 17 kDa calcium binding protein, calmodulin. 相似文献
46.
Satoru Hommura Yasuhiro Kunisa Ichiro Terada Masaru Yoshitake 《Journal of fluorine chemistry》2003,120(2):151-155
Characteristics of fibril reinforced membranes developed by Asahi Glass Company are reviewed. PTFE-fibrils <1 μm in diameter are dispersed in ion-exchange membranes uniformly. Mechanical properties, such as tensile strength, tear strength, creep property and compressive property were examined and compared with non-reinforced membranes. Fibril reinforced membranes, even by the addition of a small amount of PTFE-fibrils (2.7 wt.%), show excellent mechanical strength, especially in creep and tear strength. Cell performance is nearly equal to the one using a non-reinforced membrane and cell voltage stays about the same during the cell operation at 80 °C for 3000 h. 相似文献
47.
Chen A Kamata K Nakagawa M Iyoda T Haiqiao Wang H Li X 《The journal of physical chemistry. B》2005,109(39):18283-18288
We have recently demonstrated a one-step process to fabricate silver-polypyrrole (PPy) coaxial nanocables (Chen, A.; Wang, H.; Li, X. Chem. Commun. 2005, 14, 1863). The formation process of silver-PPy coaxial nanocables is discussed in this article. It was found from the results of TEM and SEM images that large numbers of silver atoms were formed when AgNO3 was added to a pyrrole solution. Then silver atoms transform to silver-PPy nanosheets with regular morphology, which will connect together to be more stable. Silver-PPy nanocables will be able to grow at the expense of the silver-PPy nanosheets. Poly(vinylpyrrolidone) (PVP) plays crucial roles in this process: as a capping agent to form silver nanowires, and as a dispersant of pyrrole monomers, which can influence the site at which pyrrole monomer exists. On the basis of experimental analysis, the possible mechanism was proposed. Because of the effect of PVP, silver ions and pyrrole monomers are apt to be adsorbed at the [111] and [100] facets of silver nanosheets, respectively. Obvious polymerization will take place on the boundary of the [111] and [100] facets. The PPy layer stays stable on the [100] facets. Meanwhile, newly formed silver atoms and silver nanosheets will further ripen and grow on the [111] facets. In a word, the morphology of final products and the formation process are determined by the reaction site between AgNO3 and the pyrrole monomer, which is influenced by PVP. 相似文献
48.
Hidetsura Cho Yoshiko Ohnaka Mariko Hayashimatsu Masaru Ueda Keiyuu Shima 《Tetrahedron letters》1986,27(52):6377-6380
Chlorination of 5,6-dihydropyrimidine-4-(3H)-one derivatives (1) with POCl3 gave 1,4(3,4)-dihydropyrimidines (3), whose alkoxycarbonylation (ClCOOREt3N or NaH) afforded regioselectively novel compounds (4). A new Pummerer
rearrangement of compound (1, X=
---S(O)CH3) with
3, gave compound (5h). 相似文献
49.
The INDO calculations were performed on bicyclo[2.1.1]hex-5-yl radical. From these calculations, it was confirmed that the hyperfine coupling constants depend largely on the geometry of the α hydrogen. The localized MO's were obtained from the canonical MO's calculated by using the INDO method. With the use of the localized MO's thus obtained, the variation in the hyperfine coupling constants at the 6exo- and 6endo-protons in this radical was explained in terms of the through-bond and/or the through-space interactions according to the procedure which we proposed previously. That is by the procedure we can selectively pick up a particular interaction between the specified localized MO's. The hyperfine coupling constant in this radical can be expressed by the summation of several interaction terms. The difference in the hyperfine spin coupling constants of the H6exo and H6endo in the radical now concerned has been attempted to explain using MO coefficients of the occupied orbitals. 相似文献
50.
Masaru Kihara Kouichi Yoshioka Tamboue Deffo Dwight S. Fullerton Douglas C. Rohrer 《Tetrahedron》1984,40(7):1121-1133
Earlier studies have shown that the β-D-digitoxose (2,6-dideoxy-β-D-mannopyranose) directly attached to the cardiac glycoside steroid C3 has the greatest effect on biological activity. This report describes the synthesis of eight digitoxosides (2a-9a), with widely varying cyclic and acyclic C17β-side groups, and the corresponding C3',C4'-acetonides (2b-9b). NMR analysis of conformational strain introduced by the acetonide groups is supported by crystallographic analysis of the sugars' torsion angles. 相似文献