全文获取类型
收费全文 | 234篇 |
免费 | 4篇 |
国内免费 | 3篇 |
专业分类
化学 | 161篇 |
力学 | 3篇 |
数学 | 23篇 |
物理学 | 54篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2016年 | 5篇 |
2014年 | 4篇 |
2013年 | 10篇 |
2012年 | 16篇 |
2011年 | 11篇 |
2010年 | 9篇 |
2009年 | 2篇 |
2008年 | 7篇 |
2007年 | 13篇 |
2006年 | 11篇 |
2005年 | 8篇 |
2004年 | 18篇 |
2003年 | 5篇 |
2002年 | 8篇 |
2001年 | 8篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有241条查询结果,搜索用时 15 毫秒
61.
R Shen T Iwasaki J Terao N Kambe 《Chemical communications (Cambridge, England)》2012,48(74):9313-9315
Cu-catalyzed cross-coupling of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as a ligand precursor was developed. The use of 1,3-butadiene resulted in improved yields of alkyl-alkyl products with improved selectivities. 相似文献
62.
Enantioselective direct aldol reaction of α-substituted nitroacetates with aqueous formaldehyde for the synthesis of α-alkyl serines has been achieved under base-free neutral phase-transfer conditions with a bifunctional chiral phase-transfer catalyst. 相似文献
63.
Prof. Dr. Kazuhiko Semba Naoto Bessho Prof. Dr. Tetsuaki Fujihara Prof. Dr. Jun Terao Prof. Dr. Yasushi Tsuji 《Angewandte Chemie (International ed. in English)》2014,53(34):9007-9011
Borylative allyl–allyl coupling using allenes, bis(pinacolato)diboron, and allyl phosphates has been developed in the presence of a copper catalyst bearing an N‐heterocyclic carbene ligand. The reaction affords boryl‐substituted 1,5‐diene derivatives in good to high yields with high regioselectivity and Z selectivity. 相似文献
64.
H Terao T Sugawara Y Kita N Sato E Kaho S Takeda 《Journal of the American Chemical Society》2001,123(43):10468-10474
The crystal structure of a hydrated crystal of bis(squaryl)biphenyl (BSQB*4H2O), in which two squaric acid moieties are connected with a 4,4'-biphenyl unit, was characterized by the presence of a one-dimensional hydrogen-bonded chain composed of BSQB and water molecules. X-ray crystallographic analysis showed that BSQB exists in a dianion form and that, on average, two of the four water molecules are protonated. The enhanced temperature dependence of the thermal parameters of the oxygen atoms of the water molecules suggested dynamic disorder of the water molecules. The solid-state magic angle spinning deuterium NMR spectrum of BSQB*4D2O revealed that deuterons are exchanged between heavy water molecules and oxonium ions with an exchange rate of ca. 700 Hz around 250 K and that deuterons start to migrate in a hydrogen-bonded cluster of water molecules. Ac dielectric measurements were also used to examine the dynamic process in the hydrated crystal. The dielectric permittivity of the crystal dramatically increased above 250 K with a distinct frequency dependence (epsilon' = 4.7 x 10(4) at 340 K and 1 kHz). The frequency dependence of tan delta at 290 K exhibited a maximum at 3.0 kHz, and this maximum shifted to lower frequencies when the temperature of the crystal decreased. These experimental results suggested that in the one-dimensional hydrogen-bonded chain of BSQB*4H2O a proton relay between oxonium ions and water molecules occurred within a cluster of four water molecules and that the relay was transmitted to the adjacent cluster mediated by the modulation of the negative charge distribution of the BSQB dianion. These phenomena were interpreted as the solitonic migration of the charged domain boundaries along the one-dimensional hydrogen-bonded chain. 相似文献
65.
Tomoyuki Mochida Shinya Suzuki Hiroshi Moriyama Hiroshi Terao Tadashi Sugawara 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1183-1184
The crystal structure of the title compound, (C16H36N)[Ni(C4N2S2)2], shows stacking of the dimerized anions, surrounded by columns of cations. 相似文献
66.
In response to the Comment of Furi?, attention is drawn to four points: the dinstinction between the reaction and normal coordinates, zero-point energy, an alternative of the NMR results, and ab initio calculations. 相似文献
67.
68.
69.
70.