On $$A_1^2$$ A 1 2 restrictions of Weyl arrangements

Journal of Algebraic Combinatorics - Let $$\mathcal {A}$$ be a Weyl arrangement in an $$\ell $$ -dimensional Euclidean space. The freeness of restrictions of $$\mathcal {A}$$ was first settled by a...     

Titanocene-catalyzed double silylation of dienes and aryl alkenes with chlorosilanes

Double silylation of 1,3-butadienes with chlorosilanes was found to proceed by using titanocene dichloride as the catalyst in the presence of ⁿBuMgCl, giving rise to 1,4-disilylated 2-butenes in good yields. Aryl substituted alkenes also afforded 1,2-disilylated products under similar conditions.     

N-carbonylation of lithium azaenolates of amides, formamides, ureas, and carbamates with carbon monoxide mediated by selenium

N-Carbonylation of less nucleophilic nitrogen compounds was achieved by the reaction of the lithium azaenolates with carbon monoxide and selenium. This reaction proceeds in the cases of amides, formamides, ureas, and carbamates, leading to the formation of the corresponding carbamoselenoates in good to high yields after trapping with BuI.     

Effects of 2-hydroxypropyl α-cyclodextrin on the radioactive iodine sorption on activated carbon

Journal of Radioanalytical and Nuclear Chemistry - Effect of 2-hydroxypropyl α-cyclodextrin (α-HPCD) on the iodine adsorption onto activated carbon (AC) was investigated. The iodine...     

Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents

New catalytic C--Si bond-forming reactions using chlorosilanes are described. These reactions proceed efficiently under mild conditions by the combined use of Grignard reagents and transition metal catalysts, such as Ti, Zr, Ni, and Pd. It is proposed that ate complex intermediates formed by the reaction of transition metals with Grignard reagents play important roles as the active catalytic species. The present study demonstrates the practical use of chlorosilanes in transition metal catalyzed silylation reactions providing convenient methods for allyl- or vinylsilane synthesis. The reaction pathways of these transformations as well as the scope and limitations are discussed.     

Nature of interacting electron states of Coulomb glass in local energy minima

Non-equilibrium relaxation of Coulomb glass in disordered thin films is investigated by kinetic Monte Carlo simulation. We numerically confirm aging phenomena in the autocorrelation function C(t, t_W ) in a quasi-two-dimensional system with finite thickness and clarify the effect of an external electric field on the elongated relaxation time due to aging. We also study the statistical properties of electron states belonging to local energy minima in random site models. Our results highlight the difference in the properties of energy landscape between two different models to describe Coulomb glass, called the random site model and the lattice model.