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161.
Dimethyl furan-2, 5-dicarboxylate (DMFDCA) is a valuable biomass-derived chemical that is an ideal alternative to fossil-derived terephthalic acid as a monomer for polymers. The one-step oxidation of 5-hydroxymethylfurfural (HMF) to DMFDCA is of practical significance. It not only shortens the reaction pathway but also avoids the separation process of intermediates; thus, reducing cost. In this work, non-noble bimetallic catalysts supported on N-doped porous carbon (CoMn@NC) were synthesized via a one-step co-pyrolysis procedure using different pyrolysis temperatures and proportions of metal precursors and additives. We employed the prepared CoMn@NC catalysts in the aerobic oxidation of HMF under mild reaction conditions to obtain DMFDCA. High-yield DMFDCA was obtained by screening the prepared catalysts and optimizing the reaction conditions, including the strength and amount of the base, as well as the reaction temperature. The optimized yield of DMFDCA was 85% over the Co3Mn2@NC-800 catalyst after 12 h at 50 ℃ using ambient-pressure oxygen. The physicochemical properties of the catalysts were determined using a variety of characterization techniques, the factors affecting the performance of each catalyst were investigated, and the relationship between the physicochemical properties and performance of the prepared catalysts was elucidated. A porous structure with a high surface area had a positive effect on mass transfer efficiency. Cobalt nanoparticles (NPs) and atomically dispersed Mn were coordinated to N-doped carbon to form M―Nx (where M = Co or Mn). Based on the Mott-Schottky effect, there was significant electron transfer between each metal and the N-doped carbon, additionally, the metal NPs supplied electrons to the carbon atoms. The electron-deficient metal site in the pyridinic N-rich carbon was beneficial for the activation of HMF and oxygen. The activation of oxygen produced reactive oxygen species (such as superoxide radical anions) to ensure high selectivity to DMFDCA through dehydrogenative oxidation of the hemiacetal intermediate and hydroxymethyl group of 5-hydroxymethyl-2-methyl-furoate. The existence of disordered and defective carbons increased the number of active sites. Subsequently, we performed a series of control experiments. Based on our current experimental results and previous studies, we propose a simple mechanism for the aerobic oxidation of HMF to DMFDCA. The catalyst was stable, its performance decreased slightly after two cycles, and it was tolerant to SCN− ions and resistant against N or S poisoning. Furthermore, the use of this catalytic system can be expanded to various substituted aromatic alcohols, such as benzyl alcohols with different substituents, furfuryl alcohol, and heterocyclic alcohols. Simultaneously, the product type was further extended from methyl esters to ethyl esters with a high yield when the substrate reacted with ethanol. In conclusion, this catalytic system can be applied in the production of carboxylic esters for polymers.![]()
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162.
Teng Xia Ju 《数学学报(英文版)》2009,25(5):831-844
In this paper, we show that if H is a finite-dimensional Hopf algebra such that H and H^* are semisimple, then gl.dim(A#σH)=gl.dim(A), where a is a convolution invertible cocycle. We also discuss the relationship of global dimensions between the crossed product A^#σH and the algebra A, where A is coacted by H. Dually, we give a sufficient condition for a finite dimensional coalgebra C and a finite dimensional semisimple Hopf algebra H such that gl.dim(C α H)=gl.dim(C). 相似文献
163.
Hongxiao Hu Zhidong Teng Haijun Jiang 《Nonlinear Analysis: Real World Applications》2009,10(4):2420-2433
We study the permanence of a class of nonautonomous two-species Lotka–Volterra competitive systems with infinite delay and feedback controls. New results on the permanence of solutions are obtained. The corresponding results given in [F. Chen, Z. Li, Y. Huang, Note on the permanence of a competitive system with infinite delay and feedback controls, Nonlinear Anal. RWA 8 (2007) 680–687] are improved and extended. 相似文献
164.
师同顺 《光谱学与光谱分析》1998,18(3):293-297
研究了香兰素对甲苯胺希夫碱及其金属配合物在3800-200 cm^-1范围的傅里叶变换红外光谱光谱,对主要谱带进行了经验归属。 相似文献
165.
166.
A separated pair calculation of the electronic structure of the Li2O molecule is described. Rather extensive calculations were made of the potential surface for symmetric configurations of Li2O using a double zeta Slater orbital basis. A linear configuration with LiO bond length of 1.71 Å is found to be most stable. The electron distribution and correlation effects are discussed. 相似文献
167.
Back BB Baker MD Ballintijn M Barton DS Becker B Betts RR Bickley AA Bindel R Budzanowski A Busza W Carroll A Decowski MP García E Gburek T George N Gulbrandsen K Gushue S Halliwell C Hamblen J Harrington AS Henderson C Hofman DJ Hollis RS Hołyński R Holzman B Iordanova A Johnson E Kane JL Khan N Kulinich P Kuo CM Lee JW Lin WT Manly S Mignerey AC Noell A Nouicer R Olszewski A Pak R Park IC Pernegger H Reed C Remsberg LP Roland C Roland G Sagerer J Sarin P Sawicki P Sedykh I Skulski W Smith CE 《Physical review letters》2003,91(7):072302
We have measured transverse momentum distributions of charged hadrons produced in d+Au collisions at sqrt[s(NN)]=200 GeV. The spectra were obtained for transverse momenta 0.25
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168.
169.
L. Qian Z. Xu F. Teng X.-X. Duan Z.-S. Jin Z.-L. Du F.-S. Li M.-J. Zheng Y.-S. Wang 《Journal of nanoparticle research》2007,9(3):523-527
Efficiency of polymer light-emitting diodes (PLEDs) with poly(2-methoxy-5-(2-ethyl hexyloxy)-p-phenylene vinylene) (MEH-PPV) as an emitting layer was improved if a dehydrated nanotubed titanic acid (DNTA) doped hole-buffer
layer polyethylene dioxythiophene (PEDOT) was used. Photoluminescence (PL) and Raman spectra indicated a stronger interaction
between DNTA and sulfur atom in thiophene of PEDOT, which suppresses the chemical interaction between vinylene of MEH-PPV
and thiophene of PEDOT. The interaction decreases the defect states in an interface region to result in enhancement in device
efficiency, even though the hole transporting ability of PEDOT was decreased. 相似文献
170.
We study the Fresnel diffraction of Gaussian beam truncated by one circular aperture, and give the general analytic expression of the Fresnel diffraction of truncated Gaussian beam denoted by Bessel functions. Then the characteristic of the axial diffraction fluctuation and the influence of the caliber of the circular aperture and the wave waist of Gaussian beam on the diffraction distributions are discussed, respectively. Through the numerical calculations, the characteristics of the transverse diffraction are presented and the relationship of the fluctuation of the transverse diffraction profile and the position of the axial point is shown. The physical origin of the fluctuation of Fresnel diffraction intensities of truncated Gaussian beam is expressed in terms of Fresnel half-zone theory. These phenomena and the conclusions are important for the measurement of the parameters of the beam and its applications. 相似文献