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21.
A. T. Soldatenkov A. V. Temesgen I. A. Bekro 《Chemistry of Heterocyclic Compounds》2001,37(10):1216-1222
A general scheme was developed for the cascade and stage oxidation of 1,4-disubstituted 1,2,3,6-tetrahydropyridines by potassium permanganate, based on the successive oxidation of the allylic triad of carbon atoms in the piperideine ring. In the case of 4-aryltetrahydropyridines 2-oxotetrahydropyridines are formed initially. 3,4-Dihydroxypiperidin-2-ones and finally 1-aminoalkan-3-ones are then formed. The oxidation of 4-methyl-substituted tetrahydropyridines to the analogous 1-aminoalkanones begins differently - with 3,4-dihydroxylation followed by lactamization of the piperidinediols. 相似文献
22.
Measurement of elastic and quasielastic reaction cross sections were done in 16O + 118Sn system at two different energies above the barrier. Attempts are being made to understand the results in the framework
of coupled reaction channel model. 相似文献
23.
A. T. Soldatenkov I. A. Bekro S. A. Soldatova E. Glover A. Temesgen L. N. Kuleshova V. N. Khrustalev N. D. Sergeeva 《Russian Chemical Bulletin》1997,46(11):1916-1919
Oxidative coupling of 1-alkyl(benzyl)-4-(γ-pyridyl)-1,2,5,6-tetrahydropyridines with acetone in the presence of KMnO4 follows two pathways and yields both 1-R-2-(acetylmethylene)tetrahydropyridines and 1-R-3,4-dihydroxypiperidin-2-ones. When
acetonitrile is used instead of acetone, the reaction under similar conditions occurs as selective ketodihydroxylation of
the starting piperideines yielding 1-R-3,4-dihydroxy-4-(γ-pyridyl)piperidin-2-ones. The molecular and crystal structures of
one of these products (R=Et) was studied by X-ray diffraction analysis.
For part 4, see Ref. 1
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2020–2023, November, 1997. 相似文献