Synthesis and Investigation of Piezophotocatalytic Properties of Polyvinylidene Fluoride Nanofibers Modified with Titanium Dioxide

Moscow University Chemistry Bulletin - A piezoactive nanofiber composite PVDF film with TiO2 nanoparticles included in it was synthesized by electrospinning. The composition, morphology and...     

AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX

Journal of Structural Chemistry - A new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II)2Ca(II)] complex has been successfully prepared. It is...     

SYNTHESES,CRYSTAL STRUCTURES,AND ANTIMICROBIAL ACTIVITIES OF ZINC COMPLEXES DERIVED FROM 2-AMINO-N′- (PYRIDIN-2-YLMETHYLENE)BENZOHYDRAZIDE

Journal of Structural Chemistry - New zinc complexes, [ZnBr2(HL)] (1), [ZnBr(HL)(NCS)]·0.5H2O (2), [Zn(HL)I2] (3), and [ZnL2] (4), where L is the monoanionic form of...     

OPERANDO X-RAY DIFFRACTION ANALYSIS OF THE MnOx–ZrO2 CATALYST DURING OXIDATION OF PROPANE

Journal of Structural Chemistry - A series of MnOx–ZrO2 catalysts is prepared by coprecipitation with variation of the calcinationtemperature from 400 °C to...     

Secondary Metabolites of Mahonia bealei

Chemistry of Natural Compounds -     

A Robust Algorithm for Roots Selection and Saturation Pressure Calculation for Cubic Equations of State

Journal of Solution Chemistry - In this work, a robust and rigorous procedure for roots calculation and selection for a Cubic Equation of State is presented. Roundoff errors are detected and...     

Interaction of a turbulent wake with the outer flow

The integral methods of boundary-layer theory are used to examine the interaction of a turbulent wake with the outer flow for the example of planar flow.In contrast with the known Crocco-Lees theory [1], the turbulent layer in the gas is described with the aid of an appropriate family of velocity profiles rather than by means of a Dorodnitsyn-type transformation of the incompressible turbulent layer. The selection of the simplest among the possible systems of first order interaction equations is justified; this system reduces to a single differential equation and an estimate is given of the influence of the arbitrariness in the equation selection on the final results.The hydrodynamic meaning of the singular and nonsingular integral curves and the singular point of the interaction equation is clarified on the basis of an examination of the interaction of compression and rarefaction waves in the outer supersonic stream with the wake. The effect of blowing (suction) and the initial boundary layer on the base pressure and the supersonic interaction flow as a whole is examined on the basis of the integral conditions for the splicing of the interaction flow with the isobaric mixing flow behind the corner. It is shown that, with proper selection of the single constant in the turbulent viscosity formula, the computational results are in satisfactory agreement with experiment.In conclusion, the authors wish to thank G. G. Chernyi for helpful discussions of the study, and L. V. Kapranova and Z. A. Donskova for assistance in the calculations.     

A machine for static and dynamic triaxial testing

A machine has been developed for studying the static and dynamic triaxial constitutive behavior of large specimens of geologic and construction materials. Test specimens can also contain a cylindrical tunnel cavity to permit study of tunnel-reinforcement structures and rock-structure interaction. The specimens are 0.3 m in diameter and 0.3 to 0.45 m high; the model tunnels can be up to 50 mm in diameter. Static and dynamic triaxial loads can be applied with maximum pressures of 200 MPa in static tests and 100 MPa in dynamic tests. Dynamic loading can also be superimposed on a static preload as large as 20 MPa. To facilitate study of tunnel reinforcement, the tunnel is maintained at ambient pressure, with access at both ends for instrumentation and photography. Example results show the influence on tunnel deformation of loading rate as well as the presence of joints and their orientation. For a given allowable tunnel closure, substantially greater pressures can be sustained under dynamic loading than under static loading, and substantially greater pressures can be sustained by an intact specimen than by a jointed specimen.     

Integrated-plane photoelastic method—Application of photoelastic isodynes

It has been shown by Pindera and Mazurkiewicz that a new type of scattered-light modulation in the plane of a two-dimensional photoelastic object can be obtained when the stationary integrated photoelastic method developed by Pindera and Straka is applied in a scanning mode and when the transfer function of the photoelastic system satisfies certain conditions. The new type of light modulation, called field of isodynes by the authors, carries information on stress components normal to the direction of propagation of primary beam, and on corresponding total-force component. The points where this stress component is equal to zero can be easily determined. The classical scattered-light modulation along a chosen line represents a cross section of a corresponding isodynes field. It is shown that these features of the method of isodynes make it possible to easily determine the distribution and values of normal stress components at any arbitrary rectilinear cross section, and to check immediately the accuracy of measurements. The experimental determination of contact stresses and contact regions using the method of isodynes is especially simple and elegant.     

A study of the freezing of binary solutions saturating a porous matrix

The freezing of a binary solution saturating a porous matrix is investigated experimentally and numerically. An aqueous solution of sodium chloride constituted the binary solution. Spherical glass beads constituted the porous matrix. The freezing was initiated at one of the vertical walls of a rectangular cavity. The temperature distribution in the solid, liquid and mush regions were recorded. A mathematical model that considered conduction as the only mode of heat transfer was developed. The predictions of the model were compared with experimental data. In general, as the model were compared with experimental data. In general, as the model ignored natural convection, the predicted temperatures agreed well with the data during early times in the freezing when conduction was the dominant mode of heat transfer. But as freezing progressed the predictions departed from the data and this departure was larger when the initial superheat was high i.e., when the natural convective flow was vigorous and its influence strong on the freezing process.

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Untersuchung des Gefriervorgangs in einem mit binärer Flüssigkeit getränkten porösen Körper

Zusammenfassung Der Gefriervorgang in einem mit einer binären Flüssigkeit getränkten porösen Körper wurde experimentell und numerisch untersucht. Eine wässerige Lösung von Natriumchlorid bildete die Binärlösung, während eine Glaskugelschüttung den porösen Körper repräsentierte. Der Gefriervorgang wurde an einer der senkrechten Wände einer rechteckigen Vertiefung eingeleitet und die Temperaturverteilung in der Fest-, Flüssig- und Mischphase gemessen. Das zur Überprüfung der experimentell gefundenen Ergebnisse dienende mathematische Modell unterstellte Wärmeleitung als einzigen Wärmetransportmechanisms. Da zu Beginn des Gefriervorgangs die im Modell vernachlässigte natürliche Konvektion gegenüber der Wärmeleitung von geringem Einfluß ist, zeigte sich in diesem Bereich gute Übereinstimmung zwischen Theorie und Experiment. Mit fortschreitendem Gefriervorgang traten immer größere Abweichungen auf, besonders wenn die Anfangsüberhitzung hoch war und folglich die natürliche Konvektionsströmung starken Einfluß auf den Gefriervorgang nahm.