The characteristic red chemiluminescence from reactions with acidic potassium permanganate: further spectroscopic evidence for a manganese(II) emitter

A direct comparison of the laser-induced photoluminescence of manganese(ii) with the chemiluminescence from the reaction between acidic potassium permanganate and sodium borohydride was used to confirm that the characteristic red emission from this widely used chemiluminescence reagent emanates from an electronically excited manganese(ii) species.     

Softening and hardening of yield stress by hydrogen–solute interactions

Abstract

Hydrogen atoms have a wide variety of effects on the mechanical performance of metals, and the underlying mechanisms associated with effects on plastic flow and embrittlement remain to be discovered or validated. Here, the reduction in the plastic flow stress (softening) due to hydrogen atoms in solute-strengthened metals, previously proposed by Sofronis et al. is demonstrated at the atomistic level. Glide of an edge dislocation through a field of solutes in a nickel matrix, both in the absence of hydrogen and in the presence of H bound to the solutes, is modelled. The ‘solutes’ here are represented by vacancies, enabling use of accurate binary Ni–H interatomic potentials. Since vacancies have a misfit strain tensor in the Ni matrix and also bind hydrogen atoms, they are excellent surrogates for study of the general phenomenon. The binding of H to the solute (vacancy) reduces the misfit volume to nearly zero but also creates a non-zero tetragonal distortion. Solute strengthening theory is used to establish the connection between strength and solute/hydrogen concentration and misfit strain tensor. Simulations show that when a dislocation moves through a field of random vacancy ‘solutes’, the glide stress is reduced (softening) when H is bound to the solutes. Trends in the simulations are consistent with theory predictions. Trends of softening or hardening by H in metal alloys can thus be made by computing the misfit strain tensor for a desired solute in the chosen matrix with and without bound hydrogen atoms. Pursuing this, density functional theory calculations of the interaction of H with carbon and sulphur solutes in a Ni matrix are presented. These solutes/impurities do not bind with H and the complexes have larger misfit strains, indicative of H-induced strengthening rather than softening for these cases. Nonetheless, H/solute interactions are the only mechanism, to date, that shows nanoscale evidence of plastic softening due to hydrogen associated with the hydrogen-enhanced localised plasticity concept in fcc metals.     

Cucurbit[8]uril induced heterodimerization of methylviologen and naphthalene functionalized proteins

Cucurbit[8]uril is a supramolecular inducer of protein heterodimerization for proteins appended with methylviologen and naphthalene host elements. Two sets of fluorescent protein pairs, which visualize the specific protein assembly process, enabled the interplay of the supramolecular elements with the proteins to be established.     

The magnetoelectric effects in weak ferromagnetic YMn<Subscript>2</Subscript>O<Subscript>5</Subscript> modulated structure: a Landau theory approach

According to the group theory approach, linear magnetoelectric effect (ME) can not be obtained for the spatial group of YMn₂O₅, which was known to be mmm. Regard to the magnetic structure of these type of materials, we propose a magnetic group structure for the YMn₂O₅ by considering spin orientation of the Mn³⁺ and Mn⁴⁺ ions. According to the landau theory of phase transition it can be shown, how symmetrical rules result in relationship between quantities such as magnetic order, polarization, and etc. This relation shows a weak ferromagnetic state, associated with spontaneous polarization, arisen by Dzyaloshinskii-Moriya type interaction and a field induced change in magnetoelectrical susceptibility.     

The influence of laser annealing in the presence of longitudinal weak magnetic field on asymmetrical magnetoimpedance response of CoFeSiB amorphous ribbons

Asymmetrical magnetoimpedance (AMI) is very important to further improve micromagnetic sensor performance in terms of linearity and sensitivity. This behavior was investigated for Co_68.15Fe_4.35Si_12.5B₁₅ amorphous ribbons irradiated by a 1064 nm Nd:YAG pulsed laser in air and in the presence of 3 Oe longitudinal magnetic field with changing pulse repetition rate. Results indicate that for different pulse repetition rates, various types of AMI profiles appear. For the samples annealed in the presence of longitudinal field, because of induced anisotropy, rising in asymmetry factor takes place and another peak in the magnetoimpedance (MI) profile transpires.     

Magneto-optical Kerr effect in glass/Cu/CoFeSiB/SnO2 thin films

We report on the Kerr signal enhancement as a result of the capping effect of SnO₂ on the CoFeSiB amorphous layer. The magnetic layer was deposited by pulsed laser deposition method on Cu buffer layer and was capped by SnO₂ with different thicknesses. The magnetic behavior of the samples was investigated by the Kerr effect. As the SnO₂ thickness increased up to about 70 nm, the Kerr signal increased and then reduced. The results were analyzed using the formalism based on the matrix method.     

Adjustable dispersion compensating in one dimensional coupled resonator planar optical waveguides

In this paper, the optical properties in finite size one dimensional coupled resonator optical waveguide are investigated. The large dependence of the group velocity, dispersion parameter and its higher order slope such as transmission group delay, third order dispersion and intrinsic waveguide induced loss have been studied. By engineering the optical contrast ratio of the medium by using some accessible and compatible materials, according to the equivalent layers theory, the above mentioned parameters can either be adjusted or enhanced dramatically, according to the configuration of the optical networks and users’ requirements. Also, by setting proper choice of the optical contrast ratio, super flattening of the transmittance group delay, third order dispersion spectrum and reduced intrinsic waveguide induced loss can be realized. Our results show the potential applications of the device for preventing the satellite pulse creating and transmitting pulse information distortion in multichannel lightwave systems.     

Determination of glyphosate mono-isopropylamine salt in process samples using flow injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection

The mono-isopropylamine salt of glyphosate was selectively determined directly in industrial and commercial formulations using flow injection analysis with tris(2,2′-bipyridyl)ruthenium(II) chemiluminescence detection without the need for separation. Glyphosate and its mono-isopropylamine salt furnished detection limits of 7×10⁻⁹ and 3.5×10⁻¹⁰ M and relative standard deviations of 0.4% at 1×10⁻⁷ M and 0.8% at 5×10⁻⁸ M, respectively. The methodology is robust and reliable with samples subjected only to aqueous dilution prior to analysis.     

Enhanced permanganate chemiluminescence

The significant enhancement of acidic potassium permanganate chemiluminescence by Mn(II) results from the concomitant presence of permanganate and Mn(III) in the reagent solution, which enables rapid production of the excited Mn(II) emitter with a wide range of analytes. Furthermore, the key Mn(III) co-reactant can be quickly generated by reducing permanganate with sodium thiosulfate, instead of the slow (~24 h) equilibration required when Mn(ii) is used. The emission from reactions with analytes such as tyrosine and fenoterol was over two orders of magnitude more intense than with the traditional permanganate reagent.