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911.
Avocados are a superfood gaining popularity in people's diet. Profiling and quantifying the volatiles associated with flavor can further help in understanding the fruit. However, this is challenging due to relatively low abundance of volatile compounds. The complex mixtures inherent to avocado flavor can result in coelutions using classical chromatographic techniques. To overcome these challenges, solid-phase microextraction was used to extract and preconcentrate volatiles, then separated and quantified using two-dimensional gas chromatography with a flame ionization detector. This technique enhances separation power and produces well-ordered chromatograms, allowing for templated groupings of compounds of similar chemical composition into regions. Using the flame ionization detector, an average response factor was determined and used for quantification of these templated group-type regions, as well as individual compounds. This group-type quantification improved the overall precision of compound classes in 50 avocados by at least a factor of 2, when compared to that of the individual components. Overall, the abundance of associated flavor groups, such as terpenes and alcohols decreased, whereas aldehyde groups remained constant throughout ripening. The combination of solid-phase microextraction with two-dimensional gas chromatography and group-type quantification allows for an overall better understanding of the volatiles associated with flavor of avocados. 相似文献
912.
Topological phases in (2+1)-dimensions are frequently equipped with global symmetries, like conjugation, bilayer or electric–magnetic duality, that relabel anyons without affecting the topological structures. Twist defects are static point-like objects that permute the labels of orbiting anyons. Gauging these symmetries by quantizing defects into dynamical excitations leads to a wide class of more exotic topological phases referred as twist liquids , which are generically non-Abelian. We formulate a general gauging framework, characterize the anyon structure of twist liquids and provide solvable lattice models that capture the gauging phase transitions. We explicitly demonstrate the gauging of the Z2-symmetric toric code, SO(2N)1 and SU(3)1 state as well as the S3-symmetric SO(8)1 state and a non-Abelian chiral state we call the “4-Potts” state. 相似文献
913.
We develop properties of Cauchy integrals associated to a general class of first-order elliptic systems of differential operators D on a bounded, uniformly rectifiable (UR) domain Ω in a Riemannian manifold M. We show that associated to such Cauchy integrals are analogues of Hardy spaces of functions on Ω annihilated by D , and we produce projections, of Calderón type, onto subspaces of Lp(∂Ω) consisting of boundary values of elements of such Hardy spaces. We consider Toeplitz operators associated to such projections and study their index properties. Of particular interest is a “cobordism argument,” which often enables one to identify the index of a Toeplitz operator on a rough UR domain with that of one on a smoothly bounded domain. 相似文献
914.
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916.
S C Brailsford T B Bolt G Bucci T M Chaussalet N A Connell P R Harper J H Klein M Pitt M Taylor 《The Journal of the Operational Research Society》2013,64(2):157-168
This paper addresses a key issue in the health OR literature, namely the apparent failure of OR modelling to become embedded and widely implemented within healthcare organisations. The research presented here is a case study to evaluate the adoption of one particular simulation modelling tool, Scenario Generator (S:G), which was developed by the SIMUL8 Corporation in a PPI partnership with the UK's National Health Service (NHS) Institute for Innovation and Improvement. The study involved semi-structured interviews with employees of 28 Primary Care Trusts who had all been engaged in some way with the initiative, with participants classified as ‘Not Started’, ‘Given Up’ and ‘Actively Using’. This paper presents a brief summary of barriers and facilitators to the successful use of the S:G software, but its main purpose is to focus more broadly on factors influencing the successful adoption of simulation tools in general within healthcare organisations. The insights gained in this study are relevant to improving the uptake of OR modelling in general within the NHS. 相似文献
917.
Tarek M. Trad Kyle B. Donley David C. Look Kurt G. Eyink David H. Tomich Curtis R. Taylor 《Journal of Crystal Growth》2010,312(24):3675-3679
ZnO nanoparticles as small as 80 nm were successfully synthesized using a modified vapor phase transport (VPT) process at substrate temperatures as low as 222 °C. Particle size distribution and morphology were characterized by scanning electron microscopy and atomic force microscopy. Energy dispersive X-ray spectroscopy and X-ray diffraction indicate the synthesis of high quality crystalline ZnO structures. Low temperature (4.2 K) photoluminescence (PL) spectroscopy was used to characterize the optical quality of the nanoparticles. Ultraviolet emission and a nanostructure specific feature at 3.366 eV are strong in the PL spectra. The 3.366 eV feature is observed to predominate the spectrum with decrease in particle size. This size effect corroborates the luminescence as a nanostructure-specific surface related exciton feature as previously speculated in the literature. In addition, self-assembled ZnO mesoparticles (>100 nm) were realized by increasing the growth time. Low growth temperatures of the particles allow for their potential utilization in flexible organic hybrid optoelectronics. However, this work focuses mainly on the modified synthesis and optical characterization of nanoparticles. 相似文献
918.
Shigeru Arimoto Mark Spivakovsky Keith F. Taylor Paul G. Mezey 《Journal of mathematical chemistry》2010,48(3):776-790
The present article is a direct continuation of the previous part III of this series of articles, which have been devoted
to cultivating a new interdisciplinary region between chemistry and mathematics. In the present part IV, we develop two sets
of fundamental theoretical tools, using methods from the field of resolution of singularities and analytic curves. These two
sets of tools are essential in structurally elucidating the assertion of the Fukui conjecture (concerning the additivity problems)
and the crux of the functional asymptotic linearity theorem (functional ALT) that proves the conjecture in a broad context.
This conjecture is a vital guideline for a future development of the repeat theory (RST)—the central unifying theory in the
First and the Second Generation Fukui Project. 相似文献
919.
Freya J. Hine Adam J. Taylor C. David Garner 《Coordination chemistry reviews》2010,254(13-14):1570-1579
The development of the coordination chemistry of dithiolene ligands is summarised, together with a consideration of the electronic structure of complexes of these ‘non-innocent’ ligands. This information provides a context for a consideration of the role of dithiolenes in natural systems, i.e. as the ligand that binds molybdenum (or tungsten) at the catalytic centre of an extensive series of enzymes. These enzymes catalyse the transfer of an oxygen atom to or from the substrate: e.g. the sulfite oxidases catalyse the conversion of sulfite to sulfate and the nitrate reductases catalyse the conversion of nitrate to nitrite. The nature of the catalytic centres of several of these enzymes has been determined and each involves one or two ‘molybdopterin’ (MPT) cofactors bound to a mononuclear metal centre via their dithiolene group. The biosynthesis of MPT is described and, given its nature, possible roles for this moiety in the function of the oxotransferase enzymes are discussed. The review concludes with a consideration of the coordination chemistry that has been stimulated by the present knowledge of the nature and function of the catalytic centres of these enzymes. 相似文献
920.
Douglas J. Morrison Karen Taylor Tom Preston 《Rapid communications in mass spectrometry : RCM》2010,24(12):1755-1762
The introduction of liquid chromatography coupled with isotope ratio mass spectrometry (LC/IRMS) as an analytical tool for the measurement of isotope ratios in non‐volatile analytes has somewhat simplified the analytical cycle from sample collection to analysis mainly due to the avoidance of the extensive sample processing and derivatisation that were necessary for gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS). Here we test the performance of coupling strong anion exchange to IRMS using only the second commercially available interface; the Liquiface. The system was modified from installation specification to improve peak resolution in the interface and maintain peak separation from the column to the mass spectrometer. The system performance was assessed by the determination of sensitivity, accuracy and precision attained from carbohydrate separations. The system performed satisfactorily after modifications, resulting in maintenance of peak resolution from column to mass spectrometer. The sensitivity achieved suggested that ~150 ng carbon could be analysed with acceptable precision (<0.3‰). Accuracy was maintained in the interface as determined by correlation with offline techniques, resulting in regression coefficient of r2 = 0.98 and a slope of 0.99. The average precision achieved for the separation of seven monosaccharides was 0.36‰. The integration of a carbonate removal device limited the effect of background carbon perturbations in the mass spectrometer associated with eluent gradients, and the coupling of strong anion‐exchange chromatography with IRMS was successfully achieved using the Liquiface. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献