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排序方式: 共有254条查询结果,搜索用时 171 毫秒
51.
Iran Sheikhshoaie Tayebeh Shamspur S. Yousef Ebrahimipur 《Arabian Journal of Chemistry》2012,5(2):201-205
Manganese(II) complex of (E)-2-(hydroxyl-5-methoxybenzylideneamino) phenol was synthesized and used as a suitable Mn(II) – selective membrane in PVC matrix. The plasticized membrane sensor exhibits a nersian response for Mn(II) ions over a wide concentration range of 6 × 10?6–2 × 10?2 M with slope of 29 ± 1 mV per decade. It has a response time of <11 s and can be used for 2 months without any measurable divergence in potential. The response of the proposed sensor is independent of pH between 4 and 9.5. The proposed sensor shows a fairly good discriminating ability towards Mn(II) in comparison with some hard and soft metals. The electrode was used in the determination of Mn(II) in aqueous solutions and as an indicator electrode in potentiometer titration of manganese ions against EDTA. 相似文献
52.
Maryam Sadat Hosseini-ZareMohammad Mahdavi Mina SaeediMehdi Asadi Shahrzad JavanshirAbbas Shafiee Alireza Foroumadi 《Tetrahedron letters》2012,53(27):3448-3451
We describe a new one-pot synthesis of 2,3-diaryl-5H-imidazo[2,1-a]isoindol-5-ones via the reaction of 1,2-diketones, 2-formylbenzoic acids, and ammonium acetate in acetic acid under reflux conditions and in the absence of a catalyst. 相似文献
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Cssio Luiz Coutinho Almeida-da-Silva Nallusamy Sivakumar Homer Asadi Anna Chang-Chien M. Walid Qoronfleh David M. Ojcius Musthafa Mohamed Essa 《Molecules (Basel, Switzerland)》2022,27(13)
Boswellia trees, found throughout the Middle East and parts of Africa and Asia, are the source of frankincense oil. Since antiquity, frankincense has been traded as a precious commodity, but it has also been used for the treatment of chronic disease, inflammation, oral health, and microbial infection. More recently, the bioactive components of Boswellia trees have been identified and characterized for their effects on cancer, microbial infection (especially infection by oral pathogens), and inflammation. Most studies have focused on cell lines, but more recent research has also investigated effects in animal models of disease. As natural products are considered to be safer than synthetic drugs, there is growing interest in further developing the use of substances such as frankincense oil for therapeutic treatment. 相似文献
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Pourpasha Hadi Zeinali Heris Saeed Asadi Alireza 《Journal of Thermal Analysis and Calorimetry》2019,138(1):57-67
Journal of Thermal Analysis and Calorimetry - Today, nanoparticles are used as additives because of their unique properties. The aim of the present research is to investigate the effect of the... 相似文献
57.
Spectroscopic studies,structural characterization and electrochemical studies of two cobalt (III) complexes with tridentate hydrazone Schiff base ligands: Evaluation of antibacterial activities,DNA‐binding,BSA interaction and molecular docking
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Co(III) complexes of tridentate Schiff base ligands derived from N‐(2‐hydroxybenzylideneamino)benzamide (H 2 L 1 ) and 2‐(2‐hydroxybenzylidene)hydrazine‐1‐carboxamide ( H 2 L 2 ) were synthesized and characterized using IR, Raman, 1H–NMR and UV–Vis spectroscopies. X‐ray single crystal structures of complexes 1 and 2 have also been determined, and it was indicated that these Co(III) complexes are in a distorted octahedral geometry. The cyclic voltammetry (CV) of the complexes indicates an irreversible redox behavior for both complexes 1 and 2 . The antibacterial effects of the synthesized compounds have been tested by minimum inhibitory concentration and minimum bactericidal concentration methods, which suggested that the metal complexes exhibit better antibacterial effects than the ligands against Gram‐positive bacteria. The effects of the drug (drug = ligands and complexes) on bovine serum albumin (BSA) were examined using circular dichroism (CD) spectropolarimetry, and it was revealed that the BSA (BSA, as a carrier protein) secondary structure changed in the presence of the drug. Interaction of the drug with calf‐thymus DNA (CT‐DNA) was investigated by UV–Vis absorption, fluorescence emission, CV and CD spectroscopy. Binding constants were determined using UV–Vis absorption. The results indicated that the studied Schiff bases bind to DNA, with the hyperchromic effect and non‐intercalative mode in which the metal complexes are more effective than ligands. Furthermore, molecular docking simulation was used to obtain the energetic and binding sites for the interaction of the complexes with Mycobacterium tuberculosis enoyl‐acyl carrier protein reductase (InhA), and results showed that complex 1 has more binding energy. 相似文献
58.
Sabri H. Asadi A. Ghale Majarshin A. Jalili Malekzadeh R. 《Physics of Particles and Nuclei Letters》2020,17(2):136-141
Physics of Particles and Nuclei Letters - In this paper, we have considered the evolution of the local part of two neutron separation energies in the Zr, Gd, Sm, Ba, Xe, Os and Pt isotopic chain.... 相似文献
59.
Hedayati Nafiseh Montazer Majid Mahmoudirad Mahnaz Toliyat Tayebeh 《Cellulose (London, England)》2021,28(12):8095-8113
Cellulose - The influence of ketoconazole and β-CD/ketoconazole on cotton fabric as fungal skincare was previously reported however the impact of nanosilver on the antifungal and antibacterial... 相似文献
60.
The synthesis and characterisation of the title ligands (MXBDP and PXBDP) are described. The successive protonation constants
(log Kn) are: for MXBDP, 10.77, 10.44, 9.82, 8.88, 3.19 and 1.48; for PXBDP, 10.94, 10.58, 9.90, 9.38, 3.37 and 2.27 (n=16).
With copper(II), nickel(II) and cobalt(II) both ligands preferentially form binuclear complexes, M2L4+ (L=MXBDP, PXBDP), for
which the formation constants [logβ(M2L), M=Cu, Ni, Co] are: for MXBDP, 22.16, 16.20, 11.07; for PXBDP, 25.48, 17.18 and 12.74,
respectively. The copper complexes Cu2(MXBDP)Cl4· 4H2O and Cu2(PXBDP)Cl4·2H2O have been isolated.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献