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11.
Tian Fook Kong Pei Yen Tan Benjamin Zikai Tay Xinhui Shen Marcos 《Electrophoresis》2021,42(9-10):1070-1078
In this work, we aim to observe and study the physics of bacteria and cancer cells pearl chain formation under dielectrophoresis (DEP). Experimentally, we visualized the formation of Bacillus subtilis bacterial pearl chain and human breast cancer cell (MCF-7) chain under positive and negative dielectrophoretic force, respectively. Through a simple simulation with creeping flow, AC/DC electric fields, and particle tracing modules in COMSOL, we examined the mechanism by which bacteria self-organize into a pearl chain across the gap between two electrodes via DEP. Our simulation results reveal that the region of greatest positive DEP force shifts from the electrode edge to the leading edge of the pearl chain, thus guiding the trajectories of free-flowing particles toward the leading edge via positive DEP. Our findings additionally highlight the mechanism why the free-flowing particles are more likely to join the existing pearl chain rather than starting a new pearl chain. This phenomenon is primarily due to the increase in magnitude of electric field gradient, and hence DEP force exerted, with the shortening gap between the pearl chain leading edge and the adjacent electrode. The findings shed light on the observed behavior of preferential pearl chain formation across electrode gaps. 相似文献
12.
Regiospecific Formation and Unusual Optical Properties of 2,5‐Bis(arylethynyl)rhodacyclopentadienes: A New Class of Luminescent Organometallics
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Dr. Andreas Steffen Dr. Richard M. Ward Dr. Meng Guan Tay Dr. Robert M. Edkins Dr. Fabian Seeler Magda van Leeuwen Dr. Lars‐Olof Pålsson Prof. Dr. Andrew Beeby Dr. Andrei S. Batsanov Prof. Dr. Judith A. K. Howard Prof. Dr. Todd B. Marder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(13):3652-3666
A series of 2,5‐bis(arylethynyl)rhodacyclopentadienes has been prepared by a rare example of regiospecific reductive coupling of 1,4‐(p‐R‐phenyl)‐1,3‐butadiynes (R?H, Me, OMe, SMe, NMe2, CF3, CO2Me, CN, NO2, ?C?C‐(p‐C6H4?NHex2), ?C?C?(p‐C6H4?CO2Oct)) at [RhX(PMe3)4] ( 1 ) (X=?C?C?SiMe3 ( a ), ?C?C‐(p‐C6H4?NMe2) ( b ), ?C?C?C?C?(p‐C6H4?NPh2) ( c ) or ?C?C?{p‐C6H4‐C?C?(p‐C6H4‐N(C6H13)2)} ( d ) or Me ( e )), giving the 2,5‐bis(arylethynyl) isomer exclusively. The rhodacyclopentadienes bearing a methyl ligand in the equatorial plane (compound 1 e ) have been converted into their chloro analogues by reaction with HCl etherate. The rhodacycles thus obtained are stable to air and moisture in the solid state and the acceptor‐substituted compounds are even stable to air and moisture in solution. The photophysical properties of the rhodacyclopentadienes are highly unusual in that they exhibit, exclusively, fluorescence between 500–800 nm from the S1 state, with quantum yields of Φ=0.01–0.18 and short lifetimes (τ=0.45–8.20 ns). The triplet state formation (ΦISC=0.57 for 2 a ) is exceptionally slow, occurring on the nanosecond timescale. This is unexpected, because the Rh atom should normally facilitate intersystem crossing within femto‐ to picoseconds, leading to phosphorescence from the T1 state. This work therefore highlights that in some transition‐metal complexes, the heavy atom can play a more subtle role in controlling the photophysical behavior than is commonly appreciated. 相似文献
13.
This paper presents a novel non-contact method for evaluating the resonant frequency of a microstructure, Firstly, the microstructure under test is excited by ultrasonic waves. This excitation method does not impose any undefined load on the specimen like the electrostatic excitation and also this is the first actual use of ultrasonic wave for exciting a microstructure in the literature. Secondly, the amplitudes of the microstructure are determined by image edge detection using a Mexican hat wavelet transform on the vibrating images of the microstructure. The vibrating images are captured by a CCD camera when the microstructure is vibrated by ultrasonic waves at a series of discrete high frequencies (〉30 kHz). Upon processing the vibrating images, the amplitudes at various excitation frequencies are obtained and an amplitude-frequency spectrum is obtained from which the resonant frequency is subsequently evaluated. A micro silicon structure consisting of a perforated plate (192 × 192 μm) and two cantilever beams (76 × 43 μm) which is about 4 μm thickness is tested. Since laser interferometry is not required, thermal effects on a test object can be avoided. Hence, the setup is relatively simple. Results show that the proposed method is a simple and effective approach for evaluating the dynamic characteristics of microstructures. 相似文献
14.
In this paper, we propose a novel method to encrypt a color image based on Arnold transform (ART) and interference method. A color image is decomposed into three independent channels, i.e., red, green and blue, and each channel is then encrypted into two random phase masks based on the ART and interference method. Light sources with corresponding wavelengths are used to illuminate the retrieved phase-only masks during image decryption. The influence of security parameters on decrypted images is also analyzed. Numerical simulation results are presented to illustrate the feasibility and effectiveness of the proposed method. 相似文献
15.
1.IntrodnctionWegiveaproofofthestrongconvergenceinofthesolutionoftheparabolicapproximationtowardstheentropicsolutiontothescalarconservationlawwhereuo(RN),udenotessomeapproximationofuosuchthatandthefluxfsatisfiesTheconvergenceoftheapproximatesolutions... 相似文献
16.
Xu Shi Yu Qiang Tu Hong Siang Tan Beng Kang Tay Milne W.I. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1996,24(6):1309-1318
An improved drift approximation model with an added radial electrostatic field has been successfully developed. Our model provides a computationally efficient way of quantitatively describing the plasma motion and predicting the plasma behavior in the toroidal solenoid in a filtered cathodic vacuum arc (FCVA) system. Storer's (1989) experimental results have been successfully simulated by this model. A good quantitative fit is obtained for our simulation results to the measured ion currents versus distance along the torus for various B field strengths, the attenuation length, and the wall current. The model describes the change of plasma density along the torus and provides the value of the electron-ion collision frequency at various conditions. The effect of the magnetic field and radial electric field on the plasma transportation can be assessed by the simulation and various plasma parameters can be determined. It is found that the radial electric field confines the 3-directional drift of the ions and is one of the most important parameters in determining the ion throughput. For any given B field strength and plasma parameters, there is a peak ion output corresponding to an optimal potential difference which can be obtained by the simulation. Over three times more ion output can be achieved when the torus wall is appropriately biased 相似文献
17.
Single crystals of cyclododecane, doped with a range of concentrations of an organic dye, were grown under various physical conditions. Dopant segregation resulted in similar, but not identical, cellular features to inorganic materials. The conditions for the onset of constitutional supercooling are in agreement with the theory applicable to inorganic materials. 相似文献
18.
A novel optical edge-projection method is proposed for surface contouring of an object with low reflectivity. A structured light edge is projected onto a dark surface, and the image is captured by a CCD camera. The object contour is evaluated with an active triangular projection algorithm, and one obtains a whole-field three-dimensional contour of the object by scanning the optical edge over the entire object surface. The proposed method is applied to a black nonreflective object made from woven carbon fiber and is also applied to measure the profile of a small object (a coin). The results show that an accurate profile of the specimen can be obtained. 相似文献
19.
Infrared vibrational spectroscopy in an attenuated total reflection (ATR) geometry has been employed to investigate the presence of organic thin layers on Si-wafer surfaces. The phenomena have been simulated to show there can be a field enhancement with the presented single-reflection ATR (SR-ATR) approach which is substantially larger than for conventional ATR or specular reflection. In SR-ATR, a discontinuity of the field normal to the film contributes a field enhancement in the lower index thin film causing a two order of magnitude increase in sensitivity. SR-ATR was employed to characterize a single monolayer of undecylenic acid self-assembled on Si(1 1 1) and to investigate a two monolayer system obtained by adding a monolayer of bovine serum albumin protein. 相似文献
20.
On the use of fuzzy inference techniques in assessment models: part I—theoretical properties 总被引:2,自引:0,他引:2
An assessment model is a mathematical model that produces a measuring index, either in the form of a numerical score or a
category to a situation/object, with respect to the subject of measure. From the numerical score, decision can be made and
action can be taken. To allow valid and useful comparisons among various situations/objects according to their associated
numerical scores to be made, the monotone output property and the output resolution property are essential in fuzzy inference-based
assessment problems. We investigate the conditions for a fuzzy assessment model to fulfill the monotone output property using
a derivative approach. A guideline on how the input membership functions should be tuned is also provided. Besides, the output
resolution property is defined as the derivative of the output of the assessment model with respect to its input. This derivative
should be greater than the minimum resolution required. From the derivative, we suggest improvements to the output resolution
property by refining the fuzzy production rules. 相似文献