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51.
Takahashi T Kawashima H Sugisawa H Baba T 《Solid state nuclear magnetic resonance》1999,15(2):119-123
The temperature dependence of 207Pb chemical shift in magic angle spinning (MAS) NMR spectrum of Pb(NO3)2 provides a sensitive method to calibrate sample temperatures in MAS NMR. The temperature dependence is uniform in the temperature range between 30 degrees C and 400 degrees C. The NMR sensitivity and the line width are also favorable. 相似文献
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T. Faestermann F. Feilitzsch R. S. Raghavan C. Signorini T. Yamazaki C. V. K. Baba D. B. Fossan D. Proetel 《Zeitschrift für Physik A Hadrons and Nuclei》1975,275(2):157-161
Then th,α)-reaction spectroscopical data are reported on95Mo,123Te and145Nd (target nuclei). The95Mo(n, α)92Zr and123Te(n, α)120Sn reactions showed up two lines each corresponding to the ground state and the 1st excited state with a total cross section of 32 ub and 52 μb respectively. In the case of145Nd(n, α)142Ce, a transition only to the 1st excited state of142Ce is present. It is shown that in the case of95Mo,145Nd and probably123Te, most of the cross-section comes respectively from the 2+ possibly 4?, and 0 bound levels whose widths are determined to beΓ α=0.5 × 10?6 eV,Γ α=1.6×10?8 eV andΓ α=1.6 × 10?6 eV. The present results on these three nuclei, when combined with the existing data, are consistent with the calculated statistical model values. 相似文献
56.
1,1-Dialkylethenes are readily prepared in good yields from vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones by treatment with iodine. 相似文献
57.
The electronic absorption spectra of four monosubstituted naphthalenes, α-, β-naphthols, and α-, β-naphthylamines have been investigated by means of configuration analysis with particular attention to the dependence of spectra on the position of substitution and on the electron-donating power of the substituent. The results of molecular orbital calculations based on the Pariser-Parr-Pople method are analyzed in terms of locally excited states and intramolecular charge-transfer configurations. The characteristic changes in location and polarization of the Lb, La, and Bb bands caused by substitution at the α- or β-position are adequately explained by the analysis. Two strong absorption bands of α-substituted naphthalenes, which appear in place of the Bb band of naphthalene, are shown to result from a mixing of the and states. The amino group exerts a great influence on the electronic structure of the parent molecule, so that the Bb band cannot be identified in the spectrum of β-naphthylamine. 相似文献
58.
Experimental observation of optical Ramsey interference in saturated absorption of methane in a low-pressure gas cell with
three spacially separated laser beams at 3.39 μm is reported. 相似文献
59.
This paper describes a novel, sensitive detection system for biomolecules (DNA and proteins etc.) that is integrated in a lab-on-a-chip utilizing optical compact discs (CDs) and bio-nanofibers. The new method comprises a microchannel containing CD grating that confines fragments of unique bacterial cellulose fibrils (BC), which have nanometre scale fibers and holes. A maximum of six times higher sensitivity to detect DNA was obtained with this CD and BC system compared to a conventional method. We also demonstrate an effective light-confining effect for biological application with the new method. 相似文献
60.
We demonstrate the generation of up to the 63rd harmonic (lambda = 12.6 nm) of a Ti:sapphire laser pulse (150 fs, 10 mJ), using a prepulse- (210-ps,24-mJ) produced boron plasma as the nonlinear medium. The influence of various parameters on the harmonic conversion efficiency was analyzed. The steep decrease in intensity for low-order harmonics (up to 19th order) was followed by a plateau. Typical conversion efficiencies were evaluated to be 10(-4) (for a 3rd harmonic) to 10(-7) (within the plateau region). Harmonic generation appeared to be efficient for the plasma that comprised neutral atoms and singly ionized boron. 相似文献