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51.
52.
The electron spin resonance spectra of Mn2+ ions have been studied in GexTe100?x with x = 15, 17.5 and 20, and Ge20?xTe80Six with 0 ?x? 20. All samples are found to exhibit six hyperfine lines centered at g = 4.3 with hyperfine interaction constant A = 56 × 10?4cm?1. The g = 4.3 line is interpreted as being caused by Mn2+ ions incorporated in the amorphous network and surrounded by four Te atoms in an arrangement of orthorhombic symmetry. Some of the samples of GeTe show a g = 2.0 line. This line also appears after heat treatment in air at temperatures above the glass transition temperature. It is concluded that the g = 2.0 line is caused by Mn2+ ions in phase separated microcrystalline or concentrated regions of MnO in the glass. 相似文献
53.
Takaishi T Sagawa A Nagakura K Maeda T 《The Journal of the Acoustical Society of America》2002,111(6):2601-2608
As the maximum speed of high speed trains increases, the effect of aeroacoustic noise on the sound level on the ground becomes increasingly important. In this paper, the distribution of dipole sound sources at the bogie section of high speed trains is predicted numerically. The three-dimensional unsteady flow around a train is solved by the large eddy simulation technique. The time history of vortices shows that unstable shear layer separation at the leading edge of the bogie section sheds vortices periodically. These vortices travel downstream while growing to finally impinge upon the trailing edge of the section. The wavelength of sound produced by these vortices is large compared to the representative length of the bogie section, so that the source region can be regarded as acoustically compact. Thus a compact Green's function adapted to the shape can be used to determine the sound. By coupling the instantaneous flow properties with the compact Green's function, the distribution of dipole sources is obtained. The results reveal a strong dipole source at the trailing edge of the bogie section where the shape changes greatly and the variation of flow with time is also great. On the other hand, the bottom of the bogie section where the shape does not change, or the leading edge and boundary layer where the variation of flow with time is small, cannot generate a strong dipole source. 相似文献
54.
Utilization of a metalloligand, ([Cu(2,4-pydca)2(H2O)].2Et3NH) (1) (2,4-pydca = pyridine-2,4-dicarboxylate), as a building unit provides a novel porous coordination polymer, ([ZnCu(2,4-pydca)2(H2O)3(DMF)].DMF)n (2), in which the Zn(II) ion at the node of the network acts as a linker and the Cu(II) ion in the channel wall is available for guest-coordination. 相似文献
55.
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57.
The regioselective ring-opening reaction of α-methyl-β-propiolactone with 3,3-ethylene-dioxybutylmagnesium bromide in the presence of copper(I) catalyst afforded 2-methyl-6-oxoheptanoic acid, which was easily converted into (E)-3,7-dimethyl-2-2-octene-1,8-diol in good yield. 相似文献
58.
Yasuhiro Sanada Tatsuo Akiyama Yusuke Ujihira Eiji Niki 《Fresenius' Journal of Analytical Chemistry》1982,312(6):526-529
Summary Sodium ion-selective electrodes (Na+-ISE) were prepared by implanting Si+ and Li+ into alumina wafers and their characteristics were investigated. The alumina wafer had a thickness of 100 m and a diameter of 1.40 cm. The ionselective membrane was produced by ion-implanting of Li+ and Si+ on both sides of a single-crystal alumina wafer. The total doses of Li+ and Si+ were controlled to be the same, viz. 1013–1015 ions/cm2. The ion-implanted alumina wafer with 1014 or 4×1014 ions/cm2 of Li+ and Si+ showed better characteristics than the others.The response curves of the 1014 ions/cm2 implanted alumina wafer had a slope of 42 mV/pNa in a concentration range from 1–10–4mol/l. The full response achieved after about 1 min was reproducible. The proposed idea of producing Na+-ISE by ion-implantation technique was applied to functuate the gate surface of the field effect transitor to sodium ion. The sodium ion-sensitive FET (Na+-ISFET) prepared by implanting Li+ and Al+ at a dose of 5×1014 ions/cm2 showed a slope of 30 mV/pNa in a concentration range from 1–10–4mol/l.
Herstellung Na+-ionenselektiver Elektroden durch Einbau von Lithium und Silicium in Einkristall-Alumniumoxidblättchen und Anwendung zur Erzeugung von ISFET
Zusammenfassung Na+-selektive Elektroden wurden durch Einbau von Si+ und Li+ in Aluminiumoxidblättchen hergestellt und ihre Charakteristiken untersucht. Die Blättchen hatten eine Dicke von 100 m und einen Durchmesser von 1,40 cm. Ebenso wurde die Membran für einen ISFET hergestellt. Die Gesamtmenge von Li+ und Si+ wurde auf 1013–1015 Ionen/cm2 eingestellt, wobei sich bei 1014 oder 4×1014 Ionen/cm2 die beste Charakteristik ergab.Die Responsekurven der mit 1014 Ionen/cm2 versehenen Aluminiumoxidplättchen hatten eine Neigung von 42 mV/pNa in einem Konzentrationsbereich von 1–10–4mol/l. Der nach 1 min erhaltene volle Response war reproduzierbar. Die vorgeschlagene Technik wurde zur Einstellung der Gate-Oberfläche des Feldeffekt-Transistors auf Natriumion benutzt. Der Na+-sensitive FET (Na+-ISFET), der durch Einbau von Li+ und Al+ mit 5×1014 Ionen/cm2 hergestellt wurde, zeigte eine Neigung der Signalkurve von 30 mV/pNa in einem Bereich von 1–10–4mol/l.相似文献
59.
Tatsuo Iwasa Fumio Tokunaga Tôru Yoshizawa Thomas G. Ebrey 《Photochemistry and photobiology》1980,31(1):83-85
Abstract— Quantum efficiencies for photoconversion of bacteriorhodopsin (trans-bR) to a bathochromic product (batho-bRt ) and its photoreversion in purple membrane at 77 and 9 K were investigated with low temperature spectrophotometry. The kinetics of the photoconversion and its photoreversion cannot be expressed by a single exponential curve. The photoconversions at 77 and 9 K showed the same slope in the early stage. The kinetics of the photoreversions were identical at the two temperatures. These results indicate that the quantum efficiencies for the conversion of trans-bR to batho-bRt or for its photoreversion are identical at the two temperatures.
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bRt due to the trimer structure of the purple membrane. 相似文献
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bR
60.
A simple noncollinear SHG autocorrelator for monitoring the time behavior of single subpicosecond laser pulses is described. A new CCD image-line sensor with high sensitivity in the UV range is used to measure the second-harmonic (SH) spatial distribution which gives information on the duration of the fundamental light pulses. An input energy of only 10 μJ is enough to obtain the SH spatial beam patterns in this highly sensitive autocorrelation system. 相似文献