首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2149篇
  免费   53篇
  国内免费   3篇
化学   1430篇
晶体学   24篇
力学   29篇
数学   70篇
物理学   652篇
  2021年   17篇
  2020年   19篇
  2019年   23篇
  2018年   18篇
  2017年   20篇
  2016年   31篇
  2015年   37篇
  2014年   37篇
  2013年   96篇
  2012年   90篇
  2011年   94篇
  2010年   59篇
  2009年   53篇
  2008年   113篇
  2007年   140篇
  2006年   114篇
  2005年   140篇
  2004年   115篇
  2003年   102篇
  2002年   106篇
  2001年   54篇
  2000年   41篇
  1999年   20篇
  1998年   22篇
  1997年   23篇
  1996年   30篇
  1995年   19篇
  1994年   25篇
  1993年   24篇
  1992年   24篇
  1991年   20篇
  1990年   18篇
  1989年   19篇
  1988年   20篇
  1987年   9篇
  1986年   17篇
  1985年   36篇
  1984年   37篇
  1983年   24篇
  1982年   22篇
  1981年   39篇
  1980年   31篇
  1979年   33篇
  1978年   31篇
  1977年   29篇
  1976年   21篇
  1975年   10篇
  1973年   15篇
  1972年   9篇
  1969年   10篇
排序方式: 共有2205条查询结果,搜索用时 15 毫秒
161.
Using a newly developed laser-microwave-laser resonance method, we observed a pair of microwave transitions between hyperfine levels of the (n,L)=(37,35) state of antiprotonic helium. This experiment confirms the quadruplet hyperfine structure arising from the interaction of the antiproton orbital angular momentum, the electron spin and the antiproton spin as predicted by Bakalov and Korobov. The measured frequencies of nu(+)(HF)=12.895 96+/-0.000 34 GHz and nu(-)(HF)=12.924 67+/-0.000 29 GHz agree with recent theoretical calculations on a level of 6x10(-5).  相似文献   
162.
Excitation with nanosecond-laser pulses at fluences well below the melt threshold removes Si dimers on the Si(001)-(2x1) surface and induces atomic-Si desorption through an electronic mechanism. The rate of this photoinduced reaction depends superlinearly on the excitation intensity, and is enhanced resonantly at the photon energy where the optical transition injects holes into the dimer backbond surface-band state. The results reveal the crucial role of surface holes and their nonlinear localization in the bond rupture of Si dimers on this surface.  相似文献   
163.
Initial distributions of metastable antiprotonic (4)He and (3)He atoms over principal (n) and angular momentum (l) quantum numbers have been deduced using laser spectroscopy experiments. The regions n = 37-40 and n = 35-38 in the two atoms account for almost all of the observed fractions [(3.0 +/- 0.1)% and (2.4 +/- 0.1)%] of antiprotons captured into metastable states.  相似文献   
164.
Lan S  Ishikawa H 《Optics letters》2002,27(17):1567-1569
We propose a new mechanism for constructing waveguide intersections with broad bandwidth and low cross talk in photonic crystal (PC) circuits. The intersections are created by combination of coupled-cavity wave-guides (CCWs) with conventional line-defect waveguides. This mechanism utilizes the strong dependence of the defect coupling on the field pattern in the defects and the alignment of the defects (i.e., the coupling angle) in CCWs. By properly designing the defect mode, we demonstrate through numerical simulation the establishment of such a waveguide intersection in one of the most useful PCs, which is based on a two-dimensional triangular lattice of air holes made in a dielectric material. The transmission of a 500-fs pulse at ~1.3 microm is simulated by use of the finite-difference time-domain method, showing negligible distortion and low cross talk.  相似文献   
165.
166.
167.
The regioselective ring-opening reaction of α-methyl-β-propiolactone with 3,3-ethylene-dioxybutylmagnesium bromide in the presence of copper(I) catalyst afforded 2-methyl-6-oxoheptanoic acid, which was easily converted into (E)-3,7-dimethyl-2-2-octene-1,8-diol in good yield.  相似文献   
168.
Summary Sodium ion-selective electrodes (Na+-ISE) were prepared by implanting Si+ and Li+ into alumina wafers and their characteristics were investigated. The alumina wafer had a thickness of 100 m and a diameter of 1.40 cm. The ionselective membrane was produced by ion-implanting of Li+ and Si+ on both sides of a single-crystal alumina wafer. The total doses of Li+ and Si+ were controlled to be the same, viz. 1013–1015 ions/cm2. The ion-implanted alumina wafer with 1014 or 4×1014 ions/cm2 of Li+ and Si+ showed better characteristics than the others.The response curves of the 1014 ions/cm2 implanted alumina wafer had a slope of 42 mV/pNa in a concentration range from 1–10–4mol/l. The full response achieved after about 1 min was reproducible. The proposed idea of producing Na+-ISE by ion-implantation technique was applied to functuate the gate surface of the field effect transitor to sodium ion. The sodium ion-sensitive FET (Na+-ISFET) prepared by implanting Li+ and Al+ at a dose of 5×1014 ions/cm2 showed a slope of 30 mV/pNa in a concentration range from 1–10–4mol/l.
Herstellung Na+-ionenselektiver Elektroden durch Einbau von Lithium und Silicium in Einkristall-Alumniumoxidblättchen und Anwendung zur Erzeugung von ISFET
Zusammenfassung Na+-selektive Elektroden wurden durch Einbau von Si+ und Li+ in Aluminiumoxidblättchen hergestellt und ihre Charakteristiken untersucht. Die Blättchen hatten eine Dicke von 100 m und einen Durchmesser von 1,40 cm. Ebenso wurde die Membran für einen ISFET hergestellt. Die Gesamtmenge von Li+ und Si+ wurde auf 1013–1015 Ionen/cm2 eingestellt, wobei sich bei 1014 oder 4×1014 Ionen/cm2 die beste Charakteristik ergab.Die Responsekurven der mit 1014 Ionen/cm2 versehenen Aluminiumoxidplättchen hatten eine Neigung von 42 mV/pNa in einem Konzentrationsbereich von 1–10–4mol/l. Der nach 1 min erhaltene volle Response war reproduzierbar. Die vorgeschlagene Technik wurde zur Einstellung der Gate-Oberfläche des Feldeffekt-Transistors auf Natriumion benutzt. Der Na+-sensitive FET (Na+-ISFET), der durch Einbau von Li+ und Al+ mit 5×1014 Ionen/cm2 hergestellt wurde, zeigte eine Neigung der Signalkurve von 30 mV/pNa in einem Bereich von 1–10–4mol/l.
  相似文献   
169.
Abstract— Quantum efficiencies for photoconversion of bacteriorhodopsin (trans-bR) to a bathochromic product (batho-bRt) and its photoreversion in purple membrane at 77 and 9 K were investigated with low temperature spectrophotometry. The kinetics of the photoconversion and its photoreversion cannot be expressed by a single exponential curve. The photoconversions at 77 and 9 K showed the same slope in the early stage. The kinetics of the photoreversions were identical at the two temperatures. These results indicate that the quantum efficiencies for the conversion of trans-bR to batho-bRt or for its photoreversion are identical at the two temperatures.
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bRt due to the trimer structure of the purple membrane.  相似文献   
170.
The contribution of backscattered electrons (BE) to Auger electrons (AE) and secondary electrons (SE) was studied by depositing Be onto a polycrystalline or deposited Cu substrate. The effects of backscattering on SE and maximum escape depth of SE were obtained by using the so called δ-η method. This method was also applied to the AE and the effects of BE on AE were experimentally evaluated. The AE yield versus primary energy curve which was corrected for BE was compared with other experiments and theories and considerably good agreement was obtained. From this analysis, the excitation efficiencies of AE by primary electrons and by BE could also be obtained. The absolute AE yield of Be (KVV) was estimated by “area” measurements. The changes of plasma losses, the elastic peaks, the energy distribution of BE, and the true SE were also observed as a function of deposited film thickness, and the results are discussed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号