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21.
Nonlinear Dynamics - The effects of the global harmonic force on an ensemble of nonlocally coupled chaotic Rössler oscillators is studied. The autonomous ensemble without external force... 相似文献
22.
Nonlinear Dynamics - A pendulum with an attached permanent magnet swinging in the vicinity of a conductor is a typical experiment for the demonstration of electromagnetic braking and Lenz’... 相似文献
23.
Dr. Oleg A. Levitskiy Olga I. Aglamazova Prof. Dr. Vadim A. Soloshonok Dr. Hiroki Moriwaki Prof. Dr. Tatiana V. Magdesieva 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(31):7074-7082
The results of extended comparative investigation of nickel(II) Schiff base complexes (containing various auxiliary chiral moieties) commonly used as a methodological platform for the asymmetric synthesis of tailor-made α-amino acids are provided. The following issues are addressed: 1) redox activity (determining the possibility for electrochemically induced reactions); 2) quantitative estimation of the reactivity of deprotonated complexes towards electrophiles; and 3) quantum-chemical estimation of noncovalent interactions in the metal coordination environment (which shed light on the origin of the stereochemical outcome observed for different stereoinductors). Possible mechanisms that determine the relationship between the stereochemical configuration of a molecule and its electronic structure are discussed. The DFT-calculated HOMO–LUMO energies and localization, as well as relative energies for the (S)- and (R)-alanine derivatives, that determine the stereoinduction efficiency in thermodynamically controlled reactions in nickel(II) coordination are provided. The computational data are supported by experimental results on the monobenzylation of glycine derivatives. 相似文献
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25.
Yuriy Stoyan Alexander Pankratov Tatiana Romanova 《The Journal of the Operational Research Society》2016,67(5):786-800
We further improve our methodology for solving irregular packing and cutting problems. We deal with an accurate representation of objects bounded by circular arcs and line segments and allow their continuous rotations and translations within rectangular and circular containers. We formulate a basic irregular placement problem which covers a wide spectrum of packing and cutting problems. We provide an exact non-linear programming (NLP) model of the problem, employing ready-to-use phi-functions. We develop an efficient solution algorithm to search for local optimal solutions for the problem in a reasonable time. The algorithm reduces our problem to a sequence of NLP subproblems and employs optimization procedures to generate starting feasible points and feasible subregions. Our algorithm allows us to considerably reduce the number of inequalities in NLP subproblems. To show the benefits of our methodology we give computational results for a number of new challenger and the best known benchmark instances. 相似文献
26.
The numerical analysis of variational integrators relies on variational error analysis, which relates the order of accuracy
of a variational integrator with the order of approximation of the exact discrete Lagrangian by a computable discrete Lagrangian.
The exact discrete Lagrangian can either be characterized variationally, or in terms of Jacobi’s solution of the Hamilton-Jacobi
equation. These two characterizations lead to the Galerkin and shooting constructions for discrete Lagrangians, which depend
on a choice of a numerical quadrature formula, together with either a finite-dimensional function space or a one-step method.
We prove that the properties of the quadrature formula, finite-dimensional function space, and underlying one-step method
determine the order of accuracy and momentum-conservation properties of the associated variational integrators. We also illustrate
these systematic methods for constructing variational integrators with numerical examples. 相似文献
27.
R.L. Viana A.M. BatistaC.A.S. Batista J.C.A. de PontesF.A. dos S. Silva S.R. Lopes 《Communications in Nonlinear Science & Numerical Simulation》2012,17(7):2924-2942
Many networks of physical and biological interest are characterized by a long-range coupling mediated by a chemical which diffuses through a medium in which oscillators are embedded. We considered a one-dimensional model for this effect for which the diffusion is fast enough so as to be implemented through a coupling whose intensity decays exponentially with the lattice distance. In particular, we analyzed the bursting synchronization of neurons described by two timescales (spiking and bursting activity), and coupled through such a long-range interaction network. One of the advantages of the model is that one can pass from a local (Laplacian) type of coupling to a global (all-to-all) one by varying a single parameter in the interaction term. We characterized bursting synchronization using an order parameter which undergoes a transition as the coupling parameters are changed through a critical value. We also investigated the role of an external time-periodic signal on the bursting synchronization properties of the network. We show potential applications in the control of pathological rhythms in biological neural networks. 相似文献
28.
João Batista Oliveira 《Computational Optimization and Applications》2000,16(3):215-229
This paper describes an efficient method (O(n)) to evaluate the Lipschitz constant for functions described in some algorithmic language. Considering arithmetical operations as the basis of the algorithmic language and supported by control structures, the rules to evaluate such Lipschitz constants are presented and their correctness is proved. An extension of the method to evaluate Lipschitz constants over interval domains is also presented. Examples are presented, but the effectiveness of the method is doubtful when compared to other approaches, and effective enhancements based on slope evaluations are also explored. 相似文献
29.
Maria das Graças Andrade Korn Elane Santos da Boa Morte Daniele Cristina Muniz Batista dos Santos Jacira Teixeira Castro José Tiago Pereira Barbosa Alete Paixão Teixeira 《应用光谱学评论》2013,48(2):67-92
Abstract The present article gives an overview of recent publications and modern techniques of sample preparation for food analysis employing atomic and inorganic mass spectrometric techniques, such as flame atomic absorption spectrometry, chemical vapor generation atomic absorption and atomic fluorescence spectrometry, graphite furnace atomic absorption spectrometry, inductively coupled plasma optical emission spectrometry, and inductively coupled plasma mass spectrometry. Among the most frequently applied sample preparation techniques for food analysis are dry ashing, usually with the addition of an ashing aid, and acid digestion, preferably with the assistance of microwave energy. Slurry preparation, particularly with the assistance of ultrasound, is increasingly used to reduce acid consumption and sample preparation time. Direct analysis of solid samples is gaining importance in the field of food analysis as it offers the highest sensitivity, avoids the use of acids and other aggressive reagents, makes possible the analysis of micro‐samples, and can be applied for fast screening analysis, e.g., of fresh meat. 相似文献
30.
Tatiana S. Martynova 《计算数学(英文版)》2014,32(3):297-305
An effective algorithm for solving large saddle-point linear systems, presented by Krukier et al., is applied to the constrained optimization problems. This method is a modification of skew-Hermitian triangular splitting iteration methods. We consider the saddle-point linear systems with singular or semidefinite (1, 1) blocks. Moreover, this method is applied to precondition the GMRES. Numerical results have confirmed the effectiveness of the method and showed that the new method can produce high-quality preconditioners for the Krylov subspace methods for solving large sparse saddle-point linear systems. 相似文献