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61.
Dr. Sabrina Nickel Dr. Remigiusz A. Serwa Dr. Farnusch Kaschani Sabrina Ninck Dr. Susanne Zweerink Prof. Dr. Edward W. Tate Prof. Dr. Markus Kaiser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(30):10721-10728
Polyacetylenes are a class of alkyne‐containing natural products. Although potent bioactivities and thus possible applications as chemical probes have already been reported for some polyacetylenes, insights into the biological activities or molecular mode of action are still rather limited in most cases. To overcome this limitation, we describe the application of the polyacetylene callyspongynic acid in the development of an experimental roadmap for characterizing potential protein targets of alkyne‐containing natural products. To this end, we undertook the first chemical synthesis of callyspongynic acid. We then used in situ chemical proteomics methods to demonstrate extensive callyspongynic acid‐mediated chemical tagging of endoplasmic reticulum‐associated lipid‐metabolizing and modifying enzymes. We anticipate that an elucidation of protein targets of natural products may serve as an effective guide to the development of subsequent biological assays that aim to identify chemical phenotypes and bioactivities. 相似文献
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Zinnat A. Begum Ismail M. M. Rahman Yousuke Tate Yuji Egawa Teruya Maki Hiroshi Hasegawa 《Journal of solution chemistry》2012,41(10):1713-1728
The protonation and complex formation equilibria of two biodegradable aminopolycarboxylate chelants {dl-2-(2-carboxymethyl)nitrilotriacetic acid (GLDA) and 3-hydroxy-2,2??-iminodisuccinic acid (HIDS)} with Ni2+, Cu2+, Zn2+, Cd2+ and Pb2+ ions were investigated using the potentiometric method at a constant ionic strength of I?=?0.10?mol·dm?3 (KCl) in aqueous solutions at 25?±?0.1?°C. The stability constants of the proton?Cchelant and metal?Cchelant species for each metal ion were determined, and the concentration distributions of various complex species in solution were evaluated for each ion. The stability constants (log10 K ML) of the complexes containing Ni2+, Cu2+, Zn2+, Cd2+ and Pb2+ ions followed the identical order of log10 K CuL?>?log10 K NiL?>?log10 K PbL?>?log10 K ZnL?>?log10 K CdL for either GLDA (13.03?>?12.74?>?11.60?>?11.52?>?10.31) or HIDS (12.63?>?11.30?>?10.21?>?9.76?>?7.58). In each case, the constants obtained for metal?CGLDA complexes were larger than the corresponding constants for metal?CHIDS complexes. The conditional stability constants (log10 $ K_{\text{ML}}^{'} $ ) of the metal?Cchelant complexes containing GLDA and HIDS were calculated in terms of pH, and compared with the stability constants for EDTA and other biodegradable chelants. 相似文献
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Modules over regular algebras of dimension 3 总被引:10,自引:0,他引:10
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DEBELJKOVIC D. LJ.; BRASIC V. S.; MILINKOVIC S. A.; JOVANOVIC M.B. 《IMA Journal of Mathematical Control and Information》1996,13(1):13-17
A method is presented whereby the absolute and relative stabilityof linear control systems containing transport lag can be determined.As a result feedback systems with variable time delay and loopgain, may be investigated in straightforward manner. 相似文献