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131.
The polarization of nucleons, which arises in deuteron electrodisintegration as a function of the angle between nucleon trajectories is considered. In electron scattering by large angles the polarization is affected by the interaction in the final state as well as by the presence of a D-wave component in the deuteron ground state. It is shown that the polarization degree of producing nucleons essentially depends on the choice of radial parts of the deuteron wave-function and the D-wave contribution in the deuteron ground state. 相似文献
132.
133.
A. E. Frumkin A. M. Churakov Yu. A. Strelenko O. Yu. Smirnov S. L. Ioffe V. A. Tartakovsky 《Russian Chemical Bulletin》1999,48(7):1295-1298
Oxidation of 4,6-dichloro-1,3-phenylenediamine with Caro's acid yields the corresponding dinitrosobenzene, which reacts withN,N-dibromo-tert-butylamine to give 1,5-bis(tert-butyl-NNO-azoxy)-2,4-dichlorobenzene. Treatment of the latter with ammonia yields 4-amino-and 4,6-diamino-1,3-bis(tert-butyl-NNO-azoxy)benzenes.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya. No. 7, pp. 1307–1310, July, 1999. 相似文献
134.
135.
L. M. Makarenkova I. V. Bliznets S. L. Ioffe Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》2000,49(7):1261-1269
The reactions of primary amines withN,N-bis(trimethylsilyloxy) enamines can give products of both mono-and bis-α-oximinoalkylation of primary amines. The steric
restrictions in both reactants substantially retard bis-α-oximinoalkylation. A general method for the synthesis of α-amino-substituted
oximes from primary amines and bis-silyl derivatives of aliphatic nitro compounds was developed.
For Part 1, see Ref. 1.
Published inIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1265–1272, July, 2000. 相似文献
136.
137.
Guskov A. A. Klenov M. S. Churakov A. M. Tartakovsky V. A. 《Russian Chemical Bulletin》2016,65(11):2763-2765
5-Amino-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide reacts with nitronium tetra-fluoroborate to give 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide. This compound is of interest as a new energetic material. A plausible reaction mechanism involves electrophilic substitution of the tert-butyl-NNO-azoxy group by the nitro group.
相似文献138.
Sukhorukov AY Boyko YD Ioffe SL Khomutova YA Nelyubina YV Tartakovsky VA 《The Journal of organic chemistry》2011,76(19):7893-7900
Asymmetric synthesis of GlaxoSmithKline's highly potent phosphodiesterase inhibitor 1 has been accomplished in nine steps and 16% overall yield. The original strategy suggested involves as a key step the silylation of enantiopure six-membered cyclic nitronates 4 obtained by a highly stereoselective [4 + 2]-cycloaddition of an appropriate nitroalkene 5 to trans-1-phenyl-2-(vinyloxy)cyclohexane. Functionalization of the resulting 5,6-dihydro-4H-1,2-oxazine and subsequent stereoselective reduction of 1,2-oxazine ring in intermediate 2 furnished the pyrrolizidinone framework with the recovery of chiral auxiliary alcohol. 相似文献
139.
M. S. Klenov A. M. Churakov Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》2011,60(11):2429-2431
A reaction of N-nitro-O-(4-nitrophenyl)hydroxylamine with nitriles RCN (R = Me, Et, Ph) in the presence of P4O10 in excess amount at 0 °C leads to the formation of 2-R-5-nitro-1,3-benzoxazoles. The reaction presumably takes place through the intermediate (phenoxy)oxodiazonium ion [NO2C6H4O-N=N=O]+, which eliminates an N2O molecule to form the aryloxenium ion [NO2C6H4O]+. The latter reacts with nitriles RCN at the ortho-carbon atom of the phenyl ring giving 2-R-5-nitro-1,3-benzoxazoles. 相似文献
140.
M. S. Klenov A. M. Churakov Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》2011,60(10):2051-2056
A new method for the synthesis of benzotetrazine-1,3-dioxides was developed from the 2-(tert-butyl-NNO-azoxy)-N-nitroaniline O-alkyl derivatives upon the action of strong acids (H2SO4, MeSO3H, CF3CO2H) or BF3·Et2O. A mechanism suggested for these reactions includes transformation of the N=N(O)OR group (R = Me, Pri) to the oxodiazonium ion (N=N=O)+, which intramolecularly reacts with the neighboring tert-butyl-NNO-azoxy group, furnishing the tetrazine-1,3-dioxide ring. 相似文献