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排序方式: 共有570条查询结果,搜索用时 281 毫秒
561.
Nora Ali Hassan Osama M. Darwesh Sayed Saad Smuda Ammar B. Altemimi Aijun Hu Francesco Cacciola Imane Haoujar Tarek Gamal Abedelmaksoud 《Molecules (Basel, Switzerland)》2022,27(17)
Starch is affected by several limitations, e.g., retro-gradation, high viscosity even at low concentrations, handling issues, poor freeze–thaw stability, low process tolerance, and gel opacity. In this context, physical, chemical, and enzymatic methods have been investigated for addressing such limitations or adding new attributes. Thus, the creation of biomaterial-based nanoparticles has sparked curiosity. Because of that, single nucleotide polymorphisms are gaining a lot of interest in food packaging technology. This is due to their ability to increase the mechanical and water vapor resistance of the matrix, as well as hide its re-crystallization during storage in high-humidity atmospheres and enhance the mechanical properties of films when binding in paper machines and paper coating. In medicine, single nucleotide polymorphisms (SNPs) are suitable as carriers in the field of drug delivery for immobilized bioactive or therapeutic agents, as well as wastewater treatments as an alternative to expensive activated carbons. Starch nanoparticle preparations can be performed by hydrolysis via acid hydrolysis of the amorphous part of a starch molecule, the use of enzymes such as pullulanase or isoamylase, or a combination of two regeneration and mechanical treatments with the employment of extrusion, irradiation, ultrasound, or precipitation. The possibility of obtaining cheap and easy-to-use methods for starch and starch derivative nanoparticles is of fundamental importance. Nano-precipitation and ultra-sonication are rather simple and reliable methods for nanoparticle production. The process involves the addition of a diluted starch solution into a non-solvent, and ultra-sonication aims to reduce the size by breaking the covalent bonds in polymeric material due to intense shear forces or mechanical effects associated with the collapsing of micro-bubbles by sound waves. The current study focuses on starch nanoparticle manufacturing, characterization, and emerging applications. 相似文献
562.
Nur Shakinah Razali Ahmed Saud Abdulhameed Ali H. Jawad Zeid A. ALOthman Tarek A. Yousef Omar K. Al-Duaij Norah Salem Alsaiari 《Molecules (Basel, Switzerland)》2022,27(20)
In this study, Mango (Mangifera indica) seeds (MS) and peels (MP) seeds mixed fruit wastes were employed as a renewable precursor to synthesize high-surface-area-activated carbon (MSMPAC) by using microwave-induced ZnCl2 activation. Thus, the applicability of MSMPAC was evaluated towards the removal of cationic dye (methylene blue, MB) from an aqueous environment. The key adsorption factors, namely A: MSMPAC dose (0.02–0.1 g), B: pH (4–10), and C: time (5–15 min), were inspected using the desirability function of the Box-Behnken design (BBD). Thus, the adsorption isotherm data were found to correspond well with the Langmuir model with a maximum adsorption capacity of (232.8 mg/g). Moreover, the adsorption kinetics were consistent with both pseudo-first-order and pseudo-second-order models. The spontaneous and endothermic nature of MB adsorption on the MSMPAC surface could be inferred from the negative ∆G° values and positive value of ∆H°, respectively. Various mechanisms namely electrostatic forces, pore filling, π-π stacking, and H-bonding govern MB adsorption by the MSMPAC. This study demonstrates the utility of MS and MP as renewable precursors to produce high-surface area MSMPAC with a potential application towards the removal of cationic organic dyes such as MB. 相似文献
563.
Fatma Bassyouni Mohammad Tarek Abeer Salama Bassant Ibrahim Sawsan Salah El Dine Nemat Yassin Amina Hassanein Maysa Moharam Mohamed Abdel-Rehim 《Molecules (Basel, Switzerland)》2021,26(8)
Diabetes is the most common metabolic disorder in both developing and non-developing countries, and a well-recognized global health problem. The WHO anticipates an increase in cases from 171 million in 2000 to 366 million by 2030. In the present study, we focus on the preparation of pyrimidine derivatives as potential antidiabetic and antimicrobial agents. Thein vivoeffect on total serum glucose concentration, cholesterol and antioxidant activity was assessed in adult male albino Wister rats and compared to the reference drug glimperide. Promising results were observed for compound 5. The histopathological study confirms that compound 5 results in significant activity with liver maintenance. The antimicrobial activities were evaluated against several bacterial strains such as Salmonella typhimurium ATCC 25566, Bacillus cereus, Escherichia coli NRRN 3008, Pseudomonas aeruginosa ATCC 10145, Staphylococcus aureus ATCC 6538and fungi such as Rhizopus oligosporus, Mucor miehei and Asperillus niger. Compounds 4 and 5 showed a good inhibition of the bacterial zone compared to the reference drug cephradine. Finally, we suggest protein targets for these drugs based on computational analysis, and infer their activities from their predicted modes of binding using molecular modeling. The molecular modeling for compounds 4 and 5 resulted in improved docking scores and hydrogen bonding. The docking studies are in good agreement with the in vitro and in vivo studies. 相似文献
564.
565.
Alaa S. Abd-El-Aziz Erin K. Todd Rawda M. Okasha Tarek H. Afifi 《Macromolecular Symposia》2003,196(1):89-99
The synthesis of cationic organoiron polymers with azobenzene moieties in their side chains has been accomplished via nucleophilic aromatic substitution and ring-opening metathesis polymerization (ROMP) reactions. Polyaromatic ethers and thioethers with azobenzene moieties in their side chains were functionalized with different chromophores to yield yellow-, orange- and red-colored polymers. Polynorbornenes with azobenzene-containing side chains were isolated following ROMP of their monomeric analogs. All of the organoiron polymers were soluble in polar organic solvents and underwent reversible electrochemical reduction processes. Photobleaching of the azobenzene-containing polymers was achieved in the presence of hydrogen peroxide. The metallated polymers had glass transition temperatures approximately 50 to 80°C higher than their organic analogs. 相似文献
566.
567.
Alaa S. Abd-El-Aziz Rawda M. Okasha Erin K. Todd Tarek H. Afifi Patrick O. Shipman K. Michelle D. Copping 《Macromolecular Symposia》2004,209(1):185-194
The synthesis of cationic cyclopentadienyliron-containing polymers with pendent azobenzene chromophores was accomplished via metal-mediated nucleophilic aromatic substitution reactions. All of the desired polymers were isolated as vibrantly coloured materials and displayed excellent solubility in polar aprotic solvents. Cationic and neutral cyclopentadienyliron polymers incorporating azo dyes in the backbone were also prepared. Reactions of azo dyes with dichlorobenzene complexes allowed for the isolation of cationic cyclopentdienyliron (CpFe+) complexes with azo dye chromophores. These complexes were then reacted with 1,1′-ferrocenedicarbonyl chloride to produce the trimetallic monomers with terminal chloro groups. These monomers contained two pendent CpFe+ cations and a neutral iron moiety in the backbone. Nucleophilic substitution reactions of these monomers with oxygen and sulfur containing dinucleophiles gave rise to a new class of polymeric materials. The pendent CpFe+ moieties could also be cleaved from the polymer backbones using photolysis to afford novel ferrocene based polymers. The UV-vis spectra of the organoiron monomers and polymers display similar wavelength maxima however incorporating azobenzene chromophores with electron-withdrawing substituent into the polymer chains resulted in bathochromic shifts of the λmax values. 相似文献
568.
569.
570.
Organoiron polynorbornene containing arylazo or hetarylazo dye chromophores has been prepared via ring opening metathesis polymerization using Grubbs' catalyst. The obtained polymers were isolated as brightly colored materials and displayed good solubility in polar organic solvents. The colors of these polymers were affected by the nature of the incorporated azo chromophores. Thermogravimetric analysis of these materials showed that the cleavage of the cyclopentadienyliron (CpFe+) moieties was between 225 and 231 °C, while the degradation of the polymer backbones occurred between 400 and 450 °C. UV-vis studies in DMF showed that the organoiron polymers containing arylazo dyes exhibit wavelength maxima around 425 nm. However, the replacement of these arylazo moieties with hetarylazo dyes displayed substantial bathochromic shifts in the λmax values (≈ 511 nm). 相似文献