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61.
Alena A. Volgusheva Daria A. Todorenko Ivan V. Konyukhov Elena N. Voronova Sergey I. Pogosyan Tatyana Yu Plyusnina Sergey S. Khruschev Taras K. Antal 《Photochemistry and photobiology》2023,99(4):1106-1114
The effect of the toxicant 2,3′,4,4′,6-pentachlorobiphenyl (PCB-119) on the growth, chlorophyll content, and PSII activity of C. sorokiniana cells was investigated. A strong negative effect of the toxicant was observed at PCB concentration of 0.05 μg mL−1, when culture growth ceased, chlorophyll strongly bleached, and cell death occurred. The use of original highly sensitive fluorimeter to measure three types of high-resolution chlorophyll fluorescence kinetics allowed us to detect an initial dramatic decrease in the activity of primary photosynthetic reactions, followed by their almost complete recovery at the end of the incubation period when most cells were dead. The study of the distribution of individual cells in culture in terms of Fv/Fm parameter, which reflects the quantum yield of PSII photochemistry, revealed the existence of 2–3% of cells retaining high Fv/Fm (>0.7) in the presence of the toxicant. The treated cultures were able to resume growth after prolonged incubation in fresh medium. The high sensitivity fluorescence methods used made it possible to identify stress-resistant cells which maintain high photosynthetic activity in the presence of lethal doses of toxic substances; these cells provide recovery of the population after stress. 相似文献
62.
Shupeniuk V. I. Amaladoss N. Taras T. N. Sabadakh O. P. Matkivskyi N. P. 《Russian Journal of Organic Chemistry》2021,57(4):582-588
Russian Journal of Organic Chemistry - Eight new 4-substituted 1-amino-9,10-anthraquinones containing a primary amino group were synthesized by nucleophilic substitution of bromine in... 相似文献
63.
Pogorelov TV Autenrieth F Roberts E Luthey-Schulten ZA 《The journal of physical chemistry. B》2007,111(3):618-634
Small, water-soluble, type c cytochromes form a transient network connecting major bioenergetic membrane protein complexes in both photosynthesis and respiration. In the photosynthesis cycle of Rhodobacter sphaeroides, cytochrome c2 (cyt c2) docks to the reaction center (RC), undergoes electron transfer, and exits for the cytochrome bc1 complex. Translations of cyt c2 about the RC-cyt c2 docking interface and surrounding membrane reveal possible exit pathways. A pathway at a minimal elevation allowed by the architecture of the RC is analyzed using both an all-atom steered molecular dynamics simulation of the RC-cyt c2 complex and a bioinformatic analysis of the structures and sequences of cyt c. The structure-based phylogenetic analysis allows for the identification of structural elements that have evolved to satisfy the requirements of having multiple functional partners. The patterns of evolutionary variation obtained from the phylogenetic analysis of both docking partners of cyt c2 reveal conservation of key residues involved in the interaction interfaces that would be candidates for further experimental studies. Additionally, using the molecular mechanics Poisson-Boltzmann surface area method we calculate that the binding free energy of reduced cyt c2 to the RC is nearly 6 kcal/mol more favorable than with oxidized cyt c2. The redox-dependent variations lead to changes in structural flexibility, behavior of the interfacial water molecules, and eventually changes in the binding free energy of the complex. 相似文献
64.
A subset C?G of a group G is called k-centerpole if for each k-coloring of G there is an infinite monochromatic subset G, which is symmetric with respect to a point c??C in the sense that S=cS ?1 c. By c k (G) we denote the smallest cardinality c k (G) of a k-centerpole subset in G. We prove that c k (G)=c k (? m ) if G is an abelian group of free rank m??k. Also we prove that c 1(? n+1)=1, c 2(? n+2)=3, c 3(? n+3)=6, 8??c 4(? n+4)??c 4(?4)=12 for all n????, and ${\frac{1}{2}(k^{2}+3k-4)\le c_{k}(\mathbb{Z}^{n})\le2^{k}-1-\max_{s\le k-2}\binom {k-1}{s-1}}$ for all n??k??4. 相似文献
65.
Ganisl B Valovka T Hartl M Taucher M Bister K Breuker K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(16):4460-4469
Electron detachment dissociation (EDD) is an emerging mass spectrometry (MS) technique for the primary structure analysis of peptides, carbohydrates, and oligonucleotides. Herein, we explore the potential of EDD for sequencing of proteins of up to 147 amino acid residues by using top-down MS. Sequence coverage ranged from 72% for Melittin, which lacks carboxylic acid functionalities, to 19% for an acidic 147-residue protein, to 12% for Ferredoxin, which showed unusual backbone fragmentation next to cysteine residues. A limiting factor for protein sequencing by EDD is the facile loss of small molecules from amino acid side chains, in particular CO(2). Based on the types of fragments observed and fragmentation patterns found, we propose detailed mechanisms for protein backbone cleavage and side chain dissociation in EDD. The insights from this study should further the development of EDD for top-down MS of acidic proteins. 相似文献
66.
Thermodynamic and transport properties of mesoscopic conductors are strongly influenced by the proximity of a superconductor: an interplay between the large scale quantum coherent wave functions in the normal mesoscopic and the superconducting region, respectively, leads to unusual mechanisms of quantum interference. These manifest themselves in both the mean and the mesoscopic fluctuation behaviour of superconductor-normal-metal (SN) hybrid systems being strikingly different from those of conventional mesoscopic systems. After reviewing some established theories of SN quantum interference phenomena, we introduce a new approach to the analysis of SN mesoscopic physics. Essentially, our formalism represents a unification of the quasi-classical formalism for describing mean properties of SN systems on the one hand, with more recent field theories of mesoscopic fluctuations on the other hand. Thus, by its very construction, the new approach is capable of exploring both averaged and fluctuation properties of SN systems on the same microscopic footing. As an example, the method is applied to the study of various characteristics of the single particle spectrum of SNS structures. 相似文献
67.
In the paper, we consider three quadratic optimization problems which are frequently applied in portfolio theory, i.e., the Markowitz mean–variance problem as well as the problems based on the mean–variance utility function and the quadratic utility. Conditions are derived under which the solutions of these three optimization procedures coincide and are lying on the efficient frontier, the set of mean–variance optimal portfolios. It is shown that the solutions of the Markowitz optimization problem and the quadratic utility problem are not always mean–variance efficient. 相似文献
68.
For a mixed stochastic differential equation driven by independent fractional Brownian motions and Wiener processes, the existence and integrability of the Malliavin derivative of the solution are established. It is also proved that the solution possesses exponential moments. 相似文献
69.
For a G-space X, we put and explore a question whether X admits a non-discrete Hausdorff G-invariant topology. 相似文献
70.
Wang PL Kolodiazhnyi T Yao J Mozharivskyj Y 《Journal of the American Chemical Society》2012,134(3):1426-1429
Compromise between the electrical conductivity and Seebeck coefficient limits the efficiency of chemical doping in the thermoelectric research. An alternative strategy, involving the control of a local crystal structure, is demonstrated to improve the thermoelectric performance in the RE(2)SbO(2) system. The RE(2)SbO(2) phases, adopting a disordered anti-ThCr(2)Si(2)-type structure (I4/mmm), were prepared for RE = La, Nd, Sm, Gd, Ho, and Er. By traversing the rare earth series, the lattice parameters of the RE(2)SbO(2) phases are gradually reduced, thus increasing chemical pressure on the Sb environment. As the Sb displacements are perturbed, different charge carrier activation mechanisms dominate the transport properties of these compounds. As a result, the electrical conductivity and Seebeck coefficient are improved simultaneously, while the number of charge carriers in the series remains constant. 相似文献