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García Rodenas LA Weisz AD Magaz GE Blesa MA 《Journal of colloid and interface science》2000,230(1):181-185
The electrokinetic behavior of titanium dioxide particles (Degussa P25, mainly composed of anatase) put in contact with chromium(VI) aqueous solutions is highly sensitive to light exposure under normal laboratory conditions. In the dark, adsorption of Cr(VI) gives rise to substantial decrements in the mobilities, especially in the acidic branch, and, at higher concentrations, to shifts in the isoelectric point (pH(piep)) to lower values, as expected for anionic chemisorption. A two-mode adsorption model accounts qualitatively for the results. Under light, pH(piep) shifts in the opposite direction as the Cr(VI) concentration increases. A maximum value is attained at [Cr(VI)] approximately 10(-3) mol dm(-3), pH(piep) 8.2, which coincides with values reported for hydrous chromium(III) oxides. At higher concentrations, Cr(VI) adsorption defines a shift of pH(piep) to lower values. It is concluded that light absorption by titanium dioxide promotes the reduction of Cr(VI) and the surface precipitation of the hydrous Cr(III) oxide. The values of pH(piep) for partially covered surfaces are well described by a simple model of surface ionization derived earlier. FTIR/ATR analysis of the surfaces supports this interpretation, and further suggests that one of the modes of Cr(VI) adsorption implies surface dimerization to yield adsorbed dichromate. Copyright 2000 Academic Press. 相似文献
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Sandee AJ van Der Veen LA Reek JN Kamer PC Lutz M Spek AL van Leeuwen PW 《Angewandte Chemie (International ed. in English)》1999,38(21):3231-3235
By a sol-gel process a rhodium complex containing a diphosphane with a large natural P-Rh-P bite angle is covalently anchored in a silica matrix (see picture). The immobilized catalyst is a very selective hydroformylation catalyst that is completely and conveniently separated from the product and can be reused in numerous cycles. 相似文献
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A method of determining asymptotic expansions for weakly couplednonlinearly perturbed systems of harmonic oscillators with slowlyvarying frequencies is presented. In an example with two oscillators,each one experiences a separate resonance passage that producesa first-order amplitude change. Simultaneously, second-orderadjustments occur to both oscillators. The determination isachieved by carrying the calculations to third order. 相似文献
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Fatima N Tapondjou LA Lontsi D Sondengam BL Atta-Ur-Rahman Choudhary MI 《Natural product letters》2002,16(6):389-393
Phytochemical investigations on the non-alkaloidal extracts of Mitragyna stipulosa bark has led to the isolation of a series of triterpenoids mainly consisting of quinovic acid ([structure: see text]) and its glycoside derivatives [structure: see text] and [structure: see text]. The other constituents isolated include alpha-amyrin, 3beta-acetyl ursolic acid and a mixture of oleanolic and ursolic acid and beta-sitosterol glucopyranoside. Their structures were identified by spectral and chemical studies and compounds [structure: see text] and [structure: see text] were, respectively, identified as quinovic acid 3-O-[beta-D-glucopyranoside] (quinovin glycoside C) and quinovic acid 3-O-[beta-D-quinovopyranoside]-27-O-[beta-D-glucopyranosyl] ester. Compounds [structure: see text] and [structure: see text] showed significant inhibitory activity against snake venom phosphodiesterase I. 相似文献
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Rémy Bertrand Teponno Azefack Léon Tapondjou Hyun Ju‐Jung Jung‐Hwan Nam Pierre Tane Hee‐Juhn Park 《Helvetica chimica acta》2007,90(8):1599-1605
From the bulbils of Dioscorea bulbifera L. var. sativa, three new clerodane diterpenoids, bafoudiosbulbin C (=methyl (2β,8α,12S)‐17‐oxo‐2,19 : 8,19 : 12,17 : 15,16‐tetraepoxycleroda‐3,13(16), 14‐triene‐18‐carboxylate; 1 ), bafoudiosbulbin D (=methyl (2β,6β,12R)‐17,19‐dioxo‐2,19 : 6,17 : 8,12 : 15,16‐tetraepoxycleroda‐13(16),14‐diene‐18‐carboxylate; 2 ), and bafoudiosbulbin E (=methyl (2β,3α,4α,6β,12R)‐17,19‐dioxo‐2,19 : 3,4 : 6,17 : 8,12 : 15,16‐pentaepoxycleroda‐13(16),14‐diene‐18‐carboxylate; 3 ) were isolated, together with the known compounds bafoudiosbulbins A and B, 3‐O‐β‐D ‐glucopyranosyl‐β‐sitosterol, and 6′‐stearoyl‐3‐O‐β‐D ‐glucopyranosyl‐β‐sitosterol. Their structures were established by high‐field NMR techniques (1H,1H‐COSY, 13C‐DEPT, HSQC, HMBC, and NOESY), MS analyses, as well as by comparison of their spectral data with those of related compounds. 相似文献
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WANG Yue BI Xiao-Jun CUI Shu-Wang DING Lin-Kai DAN Zeng-Luo-Bu DING Xiao-Hong FAN Chao FENG Cun-Feng FENG Zhao-Yang FENG Zhen-Yong GAO Xiao-Yu GENG Qing-Xi GUO Hong-Wei HE Hui-Hai HE Mao HU Hai-Bing HU Hong-Bo HUANG Qing JIA Huan-Yu LA Ba-Ci-Ren LE Gui-Ming LI Ai-Feng LI Jin-Yu LOU Yu-Qing LU Hong LU Sui-Ling MENG Xian-Ru MU Jun REN Jing-Ru TAN You-Heng WANG Bo WANG Hui WANG Yong-Gang WU Han-Rong XUE Liang YANG Xian-Chu YE Zong-Hai YU Guang-Ce YUAN Ai-Fang ZHANG Hui-Min ZHANG Ji-Long ZHANG Nai-Jian ZHANG Xue-Yao ZHANG Yong ZHANG Yi ZHA Xi-Sang-Zhu ZHOU Xun-Xiu YUAN Qiang 《中国物理C(英文版)》2008,32(11)
Using the data taken from Tibet Ⅱ High Density (HD) Array (1997 February--1999 September) and Tibet-Ⅲ array (1999 November--2005 November), our previous northern sky survey for TeV γ-ray point sources has now been updated by a factor of 2.8 improved statistics. From 0.0° to 60.0° in declination (Dec) range, no new TeV γ-ray point sources with sufficiently high significance were identified while the well-known Crab Nebula and Mrk421 remain to be the brightest TeV T-ray sources within the field of view of the Tibet air shower array. Based on the currently available data and at the 90% confidence level (C.L.), the flux upper limits for different power law index assumption are re-derived, which are approximately improved by 1.7 times as compared with our previous reported limits. 相似文献