全文获取类型
收费全文 | 202篇 |
免费 | 3篇 |
专业分类
化学 | 148篇 |
数学 | 19篇 |
物理学 | 38篇 |
出版年
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2017年 | 4篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 6篇 |
2013年 | 10篇 |
2012年 | 12篇 |
2011年 | 15篇 |
2010年 | 17篇 |
2009年 | 9篇 |
2008年 | 18篇 |
2007年 | 13篇 |
2006年 | 15篇 |
2005年 | 12篇 |
2004年 | 5篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 4篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有205条查询结果,搜索用时 0 毫秒
201.
Niina M. Suni Henni Aalto Tiina J. Kauppila Tapio Kotiaho Risto Kostiainen 《Journal of mass spectrometry : JMS》2012,47(5):611-619
In this article, the effect of spray solvent on the analysis of selected lipids including fatty acids, fat‐soluble vitamins, triacylglycerols, steroids, phospholipids, and sphingolipids has been studied by two different ambient mass spectrometry (MS) methods, desorption electrospray ionization‐MS (DESI‐MS) and desorption atmospheric pressure photoionization‐MS (DAPPI‐MS). The ionization of the lipids with DESI and DAPPI was strongly dependent on the spray solvent. In most cases, the lipids were detected as protonated or deprotonated molecules; however, other ions were also formed, such as adduct ions (in DESI), [M‐H]+ ions (in DESI and DAPPI), radical ions (in DAPPI), and abundant oxidation products (in DESI and DAPPI). DAPPI provided efficient desorption and ionization for neutral and less polar as well as for ionic lipids but caused extensive fragmentation for larger and more labile compounds because of a thermal desorption process. DESI was more suitable for the analysis of the large and labile lipids, but the ionization efficiency for less polar lipids was poor. Both methods were successfully applied to the direct analysis of lipids from pharmaceutical and food products. Although DESI and DAPPI provide efficient analysis of lipids, the multiple and largely unpredictable ionization reactions may set challenges for routine lipid analysis with these methods. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
202.
Toivonen TL Hukka TI Cramariuc O Rantala TT Lemmetyinen H 《The journal of physical chemistry. A》2006,110(44):12213-12221
Spectroscopic properties of a ground state nonbonded porphine-buckminsterfullerene (H2P...C60) complex are studied in several different relative orientations of C60 with respect to the porphine plane by using the density functional (DFT) and time-dependent density functional (TDDFT) theories. The geometries and electronic structures of the ground states are optimized with the B3LYP and PBE functionals and a SVP basis set. Excitation energies and oscillator strengths are obtained from the TDDFT calculations. The relative orientation of C60 is found to affect the equilibrium distance between H2P and C60 especially in the case of the PBE functional. The excitation energies of different H2P...C60 complexes are found to be practically the same for the same excitations when the B3LYP functional is used but to differ notably when PBE is used in calculations. Existence of the states related to a photoinduced electron transfer within a porphyrin-fullerene dyad is also studied. All calculations predict a formation of an excited charge-transfer complex state, a locally excited donor (porphine) state, as well as a locally excited acceptor (fullerene) state in the investigated H2P...C60 complexes. 相似文献
203.
Hannu-Pekka Komsa Tapio Rantala Alfredo Pasquarello 《Physica B: Condensed Matter》2012,407(15):3063-3067
We present a comparison of the most common finite-size supercell correction schemes for charged defects in density functional theory calculations. Considered schemes include those proposed by Makov and Payne (MP), Lany and Zunger (LZ), and Freysoldt, Neugebauer, and Van de Walle (FNV). The role of the potential alignment is also assessed. Supercells of various sizes are considered and the corrected formation energies are compared to the values obtained by extrapolation to large supercells. For defects with localized charge distributions, we generally find that the FNV scheme slightly improves upon the LZ one, while the MP scheme generally overcorrects except for point-charge-like defects. We also encountered more complex situations in which the extrapolated values do not coincide. Inspection of the defect electronic structure indicates that this occurs when the defect Kohn–Sham states are degenerate with band-edge states of the host. 相似文献
204.
Development of fuzzy state controller and its application to a hydraulic position servo 总被引:5,自引:0,他引:5
By combining control theory and fuzzy set theory, a new kind of state controller is proposed. Full order feedback and membership functions, which utilize the experience of experts, are used in the design of the state controller which we call a fuzzy state controller. Hydraulic position servos with a nonsymmetrical cylinder are commonly used in industry. This kind of system is nonlinear in nature and generally difficult to control. For different ending position, moving direction, strokes, and load the system dynamics is totally different. Once the above-mentioned parameters of the system are known, it is relatively straightforward to tune the gains of state controller to obtain good dynamic response. But when these parameters change, especially in case of the load, using the same gains will cause overshoot or even loss of system stability. Adaptive control is not applicable in this case due to the complexity of the algorithm, its rate of convergence, and the fast response characteristic of the system. The fuzzy state controller has been successfully applied to a hydraulic position servo. The system shows excellent robustness against variations of system parameters. 相似文献
205.