Acidity and alkali metal adsorption on the SiO2-aqueous solution interface

The intrinsic deprotonation constant (pK(a(2))(int)) and the intrinsic ion exchange constants (pK(Me(+))(int)) of Li(+), Na(+), and K(+) on SiO(2) were uniquely determined at 30 degrees C by using the potentiometric titration data, the Gouy-Chapman-Stern-Grahame (GSCG) model for the structure of the electrical double-layer (edl) and the double-extrapolation method. The values of these constants were pK(a(2))(int) = 6.57, pK(Li(+))(int) = pK(Na(+))(int) = pK(K(+))(int) = 5.61. The chemical meaning of intrinsic equilibrium constants and the equality in the values of pK(Li(+))(int), pK(Na(+))(int) and pK(K(+))(int) were discussed.     

Binding of brucine to human serum albumin

The feature of brucine binding to human serum albumin (HSA) was investigated via fluorescence and UV/vis absorption spectroscopy. The results revealed that brucine caused the fluorescence quenching of HSA by the formation of brucine–HSA complex. The hydrophobic interaction plays a major role in stabilizing the complex; the binding site number n and apparent binding constant K_A, corresponding thermodynamic parameters the free energy change (ΔG), enthalpy change (ΔH) and entropy change (ΔS) at different temperatures were calculated. The distance r between donor (HSA) and acceptor (brucine) was obtained according to fluorescence resonance energy transfer. The effect of brucine on the conformation of HSA was analyzed using synchronous fluorescence spectroscopy and UV/vis absorption spectroscopy.     

Sorption and desorption of radiostrontium on calcareous soil and its solid components

The effect of different solid components of calcareous soil on the retention of Sr was investigated by using batch technique and selective extraction method. The sorption and desorption isotherms of Sr on the untreated calcareous soil and the three treated soils were determined at 20°C, pH 7.8±0.2 and in the presence of 0.001 M CaCl₂. It was found that all isotherms are linear and that the sorption of Sr on the calcareous soil can be described by a reversible sorption process and the sorption mechanism is mainly ion exchange.     

肉桂酸类分子非线性光学效应的理论研究

计算了一系列肉桂酸（苯基丙烯酸）类化合物的二阶非线性光学系数，系统地研究了取代基的电子性质和取代位置对其非线性光学性质的影响，并且探讨了该类化合物的饱和取代效应．研究表明，该类化合物的非线性光学性质与其分子结构有着密切的关系．     

Synthesis and Crystal Structure of a Novel Compound of （C2N2H8O2） H6V10O28

A novel vanadate decamer, involving all vanadium atoms present in +5 oxidation and one formhydroxamic acid dimer cation readical, has been synthesized. The single-crystal X-ray diffraction shows that the orange crystal is formed in the triclinic system, space group Pi, a = 8. 4960 (17), b = 10.447 (2), c = 11.299 (2) A, α= 68. 82 (3)°,β= 87.35 (3)°, γ = 66.97(3)°. V = 855. 3(3) A3, Z = 8, R1 = 0. 0857, wR2=0. 2551. X-ray crystallographic and packing in superlattice studies showed that the crystal structure was constructed by electrostatic attraction of O-H…O hydrogen bonds between formhydroxamic acid dimer cation and decavanadate polyanion. Formhydroxamic acid dimer is got through controlling the condition of the reaction using formhydroxamic acid.     

Photoinduced electron transfer between adamantanamine-(OCH2CH2)n-phenothiazine and mono-6-p-nitrobenzoyl-β-cyclodextrin

A series of adamantanamine-(OCH₂CH₂)_n-phenothiazine (n = 0, 1, 2, 3) electron donors was synthesized. Photoinduced electron transfer was observed in the supramolecular complex of the phenothiazine derivatives with p-nitrobenzoyl-β-cyclodextrin (NBCD) through binding of the adamantyl group by the NBCD cavity, which is stabilized clearly via hydrophobic interactions in aqueous solution. Detailed Stern–Volmer constants were measured and they were partitioned into dynamic Stern–Volmer quenching constants and static binding constants. The results revealed an efficient electron transfer process inside the supramolecular systems compared to that controlled by diffusion. This observation also indicates that the chain length will influence the electron transfer efficiency of a supramolecular donor–acceptor system.     

A convenient synthesis of 2-aryl substituted benzo[f] [1,2,4]triazolo[1,5-a]azepine derivatives

A convenient synthetic pathway to 2-aryl-5,6-dihydro-4H-benzo[f][1,2,4]triazolo[1,5-α]azepine derivatives 7 was developed. The synthesis was based on the cycloaddition of the 1,2,3,4-tetrahydronaphthalene a-acetoxy azo compounds 3 with Ar-CN in the presence of AlCl3 and the consecutive ring enlargement.     

Study of Manganese Promoter on a Precipitated Iron-Based Catalyst for Fischer-Tropsch Synthesis

The effects of Manganese(Mn)incorporation on a precipitated iron-based Fischer-Tropsch synthesis(FTS)catalyst were investigated using N_2 physical adsorption,air differential thermal analysis (DTA),H_2 temperature-programmed reduction(TPR),and M(?)ssbauer spectroscopy.The FTS perfor- mances of the catalysts were tested in a slurry phase reactor.The characterization results indicated that Mn increased the surface area of the catalyst,and improved the dispersion ofα-Fe_2O_3 and reduced its crystallite size as a result of the high dispersion effect of Mn and the Fe-Mn interaction.The Fe-Mn inter- action also suppressed the reduction ofα-Fe_2O_3 to Fe_3O_4,stabilized the FeO phase,and(or)decreased the carburization degree of the catalysts in the H_2 and syngas reduction processes.In addition,incorporated Mn decreased the initial catalyst activity,but improved the catalyst stability because Mn restrained the reoxidation of iron carbides to Fe_3O_4,and improved further carburization of the catalysts.Manganese suppressed the formation of CH_4 and increased the selectivity to light olefins(C_(2-4)~=),but it had little effect on the selectivities to heavy(C_(5 )) hydrocarbons.All these results indicated that the strong Fe-Mn interaction suppressed the chemisorptive effect of the Mn as an electronic promoter,to some extent,in the precipitated iron-manganese catalyst system.     

簇合物[Fe（DMF）6][W2S6]的合成,结构和性能研究

以(NH_4)_2WS_4、FeCl_3和NaS_2CNC_5H_(10)为原料,合成出[Fe(DMF)_6][W_2S_6]簇合物,用X射线衍射法测定了晶胞结构.其晶胞参数为a=0.8778(1)nm,b=0.9467(3)nm,c=1.1362(6)nm,α=71.506(1)°,β=74.775(2)°,γ=74.775(2)°,ν=0.84806nm~3,Z=1.晶体结构经块矩阵最小二乘法精修后,最终偏离因子R=0.0811.此外还进行了红外光谱、紫外可见光谱的测定.