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41.
Flávio A. Pavan Sheila Leal Tania M.H. Costa Edilson V. Benvenutti Yoshitaka Gushikem 《Journal of Sol-Gel Science and Technology》2002,23(2):129-133
Aniline/silica sol-gel material was obtained. The aniline was immobilized on the silica surface using chloropropyltrimethoxysilane as bridge reagent. The base activator NaH was used to produce a fast SN2 reaction between the base and the alkylorganosilane. The resulting modified silica was characterized by elemental analysis and infrared spectroscopy using an oven cell. The organic coverage on the surface was proportional to the organic precursor concentration. The aniline/silica materials are thermally stable up to 300°C, in high vacuum. 相似文献
42.
Mariza Pires de Melo† Tania Cristina Pithon Curi Rui Curl Paolo Di Mascio Giuseppe Cilento 《Photochemistry and photobiology》1997,65(2):338-341
Peroxidase activity in neutrophils is higher than in thioglycollate macrophages, while in lymphocytes this enzyme activity is very low. Indole-3-acetic acid is oxidized by peroxidase and the role of this enzyme in the cytotoxic effect of the compound was evaluated by measuring oxygen consumption, light emission and cell death in neutrophils, macrophages and lymphocytes. The increase in light emission, oxygen consumption and rate of cell death in cells cultured in the presence of indole-3-acetic acid presented a direct correlation with the peroxidase activity of the cells as follows: neutrophils > thioglycollate macrophages > resident macrophages > lymphocytes. Indeed, in lymphocytes that possess very low peroxidase activity, indole-3-acetic acid did not result in an increase in light emission or oxygen consumption and it was not cytotoxic. 相似文献
43.
Renato P. Freitas Cristiane Calza Tania A. Lima Angela Rabello Ricardo Tadeu Lopes 《X射线光谱测定》2010,39(5):307-310
In this work, 102 fragments of Marajoara ceramics, belonging to the National Museum collection (Rio de Janeiro, Brazil), were analyzed using energy dispersive X‐ray fluorescence (EDXRF) and principal component analysis (PCA) in order to identify possible groups of samples that present similar behaviors or different characteristics. This information will give an important aid to a more accurate classification of these artifacts. The EDXRF measurements were carried out with a portable system developed in the Nuclear Instrumentation Laboratory consisting of an Oxford TF3005 X‐ray tube, with W anode, and an Si‐PIN XR‐100CR detector from Amptek, working at 25 kV and 100 µA, acquisition time of 600 s and a beam collimation of 2 mm. PCA applied to the X‐ray fluorescence results revealed a clear cluster separation to the samples. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
44.
Luciana S. Buriol Michael J. Hirsch Panos M. Pardalos Tania Querido Mauricio G. C. Resende Marcus Ritt 《Optimization Letters》2010,4(4):619-633
One of the main goals in transportation planning is to achieve solutions for two classical problems, the traffic assignment
and toll pricing problems. The traffic assignment problem aims to minimize total travel delay among all travelers. Based on
data derived from the first problem, the toll pricing problem determines the set of tolls and corresponding tariffs that would
collectively benefit all travelers and would lead to a user equilibrium solution. Obtaining high-quality solutions for this
framework is a challenge for large networks. In this paper, we propose an approach to solve the two problems jointly, making
use of a biased random-key genetic algorithm for the optimization of transportation network performance by strategically allocating
tolls on some of the links of the road network. Since a transportation network may have thousands of intersections and hundreds
of road segments, our algorithm takes advantage of mechanisms for speeding up shortest-path algorithms. 相似文献
45.
Tania Chowdhury Kaushik Bera Debabrata Samanta Sandip Dolui Suvendu Maity Nakul C. Maiti Prasanta Kumar Ghosh Debasis Das 《应用有机金属化学》2020,34(4):e5556
Four new zinc (II) complexes [Zn (HL1H)Br2] (1), [Zn (HL1H)Cl2] (2), [Zn2(HL2)Br3] (3), and [Zn (HL2)Cl] (4) have been synthesized by adopting template synthetic strategy and utilizing two homologous Schiff base ligands (H2L1 = 4-bromo-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-6-methoxyphenol, H2L2 = 4-bromo-2-{[3-(2-hydroxyethylamino)propylimino]methyl}-6-methoxyphenol), differing in one -CH2- unit in the ligating backbone, by adopting template synthetic strategy. All the complexes have been characterized by single crystal X-ray diffraction analysis as well as by other routine physicochemical techniques. Ligand mediated structural variations have been observed and rationalized by density functional theoretical (DFT) calculations. Interaction of the complexes 1–4 with Bovine Serum Albumin protein (BSA) has been studied by different spectroscopic techniques. A complete thermodynamic profile (ΔHo, ΔSo and ΔGo) was evaluated initially from the change in absorption and fluorescence spectra upon addition of BSA to the complexes. Appreciable binding constant values in the range ~ 0.94–4.51 × 104 M−1 indicate efficient binding tendency of the complexes to BSA with the sequence 1 ≅ 2 > 3 ≅ 4. Circular dichroism (CD), isothermal calorimetric titration experiments, molecular docking and molecular dynamics have been performed to gain deep insight into the binding regions of complex 1 to BSA. Experimental evidences suggest an interaction of zinc complexes at the surface of BSA protein and this particular binding has been exploited to determine unknown concentration of BSA protein. For this purpose complex 1 was explored as a BSA protein quantification tool. 相似文献
46.
Three‐Dimensional Branched and Faceted Gold–Ruthenium Nanoparticles: Using Nanostructure to Improve Stability in Oxygen Evolution Electrocatalysis
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Dr. Lucy Gloag Dr. Tania M. Benedetti Dr. Soshan Cheong Dr. Yibing Li Dr. Xuan‐Hao Chan Prof. Lise‐Marie Lacroix Prof. Shery L. Y. Chang Dr. Raul Arenal Dr. Ileana Florea Dr. Hector Barron Dr. Amanda S. Barnard Dr. Anna M. Henning Prof. Chuan Zhao Prof. Wolfgang Schuhmann Prof. J. Justin Gooding Prof. Richard D. Tilley 《Angewandte Chemie (International ed. in English)》2018,57(32):10241-10245
Achieving stability with highly active Ru nanoparticles for electrocatalysis is a major challenge for the oxygen evolution reaction. As improved stability of Ru catalysts has been shown for bulk surfaces with low‐index facets, there is an opportunity to incorporate these stable facets into Ru nanoparticles. Now, a new solution synthesis is presented in which hexagonal close‐packed structured Ru is grown on Au to form nanoparticles with 3D branches. Exposing low‐index facets on these 3D branches creates stable reaction kinetics to achieve high activity and the highest stability observed for Ru nanoparticle oxygen evolution reaction catalysts. These design principles provide a synthetic strategy to achieve stable and active electrocatalysts. 相似文献
47.
Flávio A PavanWelington F de Magalhães Maria A de LucaCelso C Moro Tania M.H Costa 《Journal of Non》2002,311(1):54-60
Silicapropylaniline nanometric materials with varying organic content were obtained using a sol-gel synthesis. By increasing the organic load, the scanning electron microscopy technique shows a slight increase in the average size of aggregated particles. N2 isotherms and positron annihilation lifetime spectroscopy measurements show that the average pore size decreases accompanied by a surface area reduction. FTIR thermal analysis was used to estimate the thermal stability of the organic phase and also to detect the presence of trapped organic groups in closed pores. From the organic coverage and surface area measurements the surface density of the immobilized organic molecules as well as the average intermolecular distance between them could be estimated. 相似文献
48.
A Liouville-Green (WKB) asymptotic approximation theory is developed for some classes of linear second-order difference equations in Banach algebras. The special case of linear matrix difference equations (or, equivalently, of second-order systems) is emphasized. Rigorous and explicitly computable bounds for the error terms are obtained, and this when both, the sequence index and some parameter that may enter the coefficients, go to infinity. A simple application is made to orthogonal matrix polynomials in the Nevai class. 相似文献
49.
Oliver Kaufhold F. Ekkehardt Hahn Tania Pape Alexander Hepp 《Journal of organometallic chemistry》2008,693(21-22):3435-3440
N-mesityl-N′-pyridyl-imidazolium chloride 1a and the corresponding bromide salt 1b have been deprotonated with NaH in THF giving the free N-heterocyclic carbene N-mesityl-N′-pyridyl-imidazolin-2-ylidene 2 in 80% yield (starting from 1a). Imidazolium salt 1a reacts with RuCl3 · xH2O to give a racemic mixture of dinuclear di-μ-chloro bridged ruthenium complexes [(κ2-2)2Ru(μ-Cl)2Ru(κ2-2)2]2+ [3a]2+. The carbene carbon atoms as well as the halides are arranged in cis-positions to each other whereas the nitrogen atoms adopt a trans-configuration. The di-μ-bromo bridged derivative [(κ2-2)2Ru(μ-Br)2Ru(κ2-2)2]2+ [3b]2+ was obtained from RuCl3 · xH2O and 1b. The bridging halide ligands can be removed by the reaction with silver or sodium salts of bidentate Lewis acids. Complex [3a]2+ reacts with silver pyridylcarboxylate to give a racemic mixture of the mononuclear complex [4]+. Reaction of [3a]2+ with the sodium salt of l-proline resulted in a diastereomeric mixture of complexes [5]+. The free N-heterocyclic carbene 2 reacts with [FeCl2(PPh3)2] to give after anion exchange with NaBPh4 cis/cis/trans coordinated [Fe(κ2-2)2(MeCN)2](BPh4)2 [6](BPh4)2. The molecular structures of [3b](PF6)2, [4]PF6 and [6](BPh4)2 · H2O are reported. 相似文献
50.
Alexander D. Fusi Yudong Li Dr. A. Llopis-Lorente Dr. Tania Patiño Prof. Dr. Jan C. M. van Hest Dr. Loai K. E. A. Abdelmohsen 《Angewandte Chemie (International ed. in English)》2023,62(5):e202214754
Unprecedented opportunities exist for the generation of advanced nanotechnologies based on synthetic micro/nanomotors (MNMs), such as active transport of medical agents or the removal of pollutants. In this regard, great efforts have been dedicated toward controlling MNM motion (e.g., speed, directionality). This was generally performed by precise engineering and optimizing of the motors′ chassis, engine, powering mode (i.e., chemical or physical), and mechanism of motion. Recently, new insights have emerged to control motors mobility, mainly by the inclusion of different modes that drive propulsion. With high degree of synchronization, these modes work providing the required level of control. In this Minireview, we discuss the diverse factors that impact motion; these include MNM morphology, modes of mobility, and how control over motion was achieved. Moreover, we highlight the main limitations that need to be overcome so that such motion control can be translated into real applications. 相似文献