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61.
Using Fickett’s model for reactive compressible flows, i.e., the reactive form of Burgers’ equation, we address the problem of shock induced ignition by a piston in a reactive medium characterized by a 2 step induction-reaction kinetics. Owing to the model’s simplicity, the ignition and acceleration mechanism is explained using the two families of characteristics admitted by the model. The energy release along the particle paths provides the amplification of forward-traveling pressure waves. These waves pre-compress the medium in the induction layer ahead of the reaction zone, therefore changing the induction delays of successive particles. The variation of the induction delay provides the modulation of the amplification of the forward traveling pressure waves by controlling the residence time of the pressure waves in the reaction zone. A closed form analytical solution is obtained by the method of characteristics and high activation energy asymptotics. The acceleration of the reaction zone was found to be proportional to the product of the activation energy, the ratio of the induction to reaction time and the heat release. This finding provides a theoretical justification for the previous use of this non-dimensional number to characterize the ignition regimes observed experimentally in detonations and shock induced ignition phenomena. Numerical simulations are presented and analyzed. Both subsonic and supersonic internal flame propagation are observed, consistent with experiment and previous reactive Euler models. 相似文献
62.
Pei Tang Qi-Feng Chen Ling Wang Qiao-Hong Chen Xi-Xian Jian Feng-Peng Wang 《Tetrahedron》2012,68(27-28):5668-5676
O-Demethylation at C-1 in the C19-diterpenoid alkaloids is very challenging. In this paper, it was firstly observed that 10-OH group in deltaline (1) is a determining factor for the O-demethylation reaction. After removal of this hydroxyl group, 1-O-methyl group in the corresponding deltaline analogs can be readily removed by treatment with HBr–HOAc. Meanwhile, the C-14 atom in bromides 18 or 20 can be extruded under basic condition probably via a sequence, including Grob fragmentation, aerobic oxidation, deformylation, and SN2 nucleophilic substitution, to give enone 21 (70%) and oxetane 22 (14%). The structure of compound 22 was confirmed by X-ray crystallographic analysis of its derivative 21. 相似文献
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Xian Tao Ke‐Cheng Shen Qing‐Yun Tang Meng Feng Jiang‐Tao Fang Yu‐Long Wang Ying‐Zhong Shen 《应用有机金属化学》2012,26(7):323-329
New N‐silver(I) acetylbenzamide complexes of type Ln?AgNC9H8O2 (L = PPh3; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt)3; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were obtained in high yields and characterized by elemental analysis, 1H NMR, 13C{H} NMR, 31P{H} NMR and IR spectroscopy, respectively. The molecular structure of 2b has been determined by X‐ray single‐crystal analysis in which the silver atom is in a distorted tetrahedral geometry and crystallizes as cis–trans. New N‐silver(I) acetylbenzamide complexes have a four‐membered ring, which could influence their chemical and physical properties and modulate volatility. Metal organic chemical vapor deposition experiments were carried out successfully at 400°C and 450°C using 2e as precursor for the deposition of silver films, respectively. The high‐purity silver film obtained at 400°C is dense and homogeneous. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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为了测量黑腔靶X光引光效率、转换效率,我们设计了相应的分解靶(泄漏靶)实验,1989~1992年在″神光″装置上共进行了四次漏靶分解实验,利用灵敏度作了绝对标定的平响应X光二极管对漏靶注入孔、引光孔流出的X光角分布进行了测量,测出了x光角分布,得到了黑腔靶X光转换效率为50%~60%,引光效率约6%,为以后辐射驱动内爆研究的理论计算和靶的优化设计提供了重要的数据。 相似文献
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Morelos A Albuquerque IF Bondar NF Carrigan RA Chen D Cooper PS Lisheng D Denisov AS Dobrovolsky AV Dubbs T Endler AM Escobar CO Foucher M Golovtsov VL Gottschalk H Gouffon P Grachev VT Khanzadeev AV Kubantsev MA Kuropatkin NP Lach J Lang Pengfei Li Chengze Li Yunshan Luksys M Mahon JR McCliment E Newsom C Pommot Maia MC Samsonov VM Schegelsky VA Shi Huanzhang Smith VJ Tang Fukun Terentyev NK Timm S Tkatch II Uvarov LN Vorobyov AA Yan Jie Zhao Wenheng Shuchen Z Zhong Yuanyuan 《Physical review letters》1993,71(21):3417-3420