非线性介质中强光对弱光聚焦的控制研究

从理论和实验上分析了强光控制弱光脉冲聚焦的方法, 该方法可以灵活地控制弱光的聚焦过程和特性. 通过研究两光束共同传输, 利用强抽运光在相互作用时为弱探测光提供诱导非线性效应, 从而使弱探测光发生聚焦. 得到了在抽运光保持不变情况下探测光的解析解, 并在实验上得到验证. 进一步研究了强抽运光对弱探测光焦点位置的影响. 结果显示: 通过改变抽运光功率、束宽能够有效地控制弱探测光的聚焦过程和焦点位置. 关键词： 诱导聚焦 自聚焦 非线性折射率     

Mo的引入方式对CeO2脱硝性能的影响

固定源排放的氮氧化物(NOx)导致了严重的环境污染问题,NH3选择性催化还原(NH3-SCR)被认为是目前控制NOx排放的最有效技术,已广泛应用于电力行业的烟气排放治理.然而,我国非电行业的NOx减排仍然面临着重大挑战,因为其排放的废气温度通常低于300oC,且含有一定量的SO2,传统的钒基SCR催化剂因活性温度(30...     

受电子束辐照的硬铝靶的喷射冲量耦合系数随能通量的变化规律

采用通光式传感法和直接测量特定时间间隔的探头原理,在闪光２号装置上进行了电子束辐照硬铝靶产生的喷射冲量耦合系数与能通量关系的研究。结果表明：在能通量为１１５～２４０Ｊ／ｃｍ２范围内,喷射冲量和亏损质量面密度都随能通量近似线性变化,而喷射冲量耦合系数随能通量增大而缓慢递增,并趋于一渐近值;硬铝产生喷射冲量的能通量阈值为４０Ｊ／ｃｍ２左右;喷射冲量值为８１～２１８Ｐａｓ,亏损质量面密度为３．１ １０－２～８．６１０－２ｇ／ｃｍ２,喷射冲量耦合系数为０．７０～０．９８Ｐａｓ／（Ｊ／ｃｍ　２）。     

X(2900) in a chiral quark model

Recently,the LHCb Collaboration reported their observation of the first two fully open-flavor tetraquark states named Xo(2900) and X_1(2900) with unknown parity.Inspired by the report,we consider all the possible fourquark candidates for X(2900),which include the molecular structure,diquark structure,and their coupling in a chiral quark model via the Gaussian expansion method.To identify the genuine resonances,the real-scaling method(stabilization method) was employed.Our results show that five possible resonances,R_0(2914) with Γ=42 MeV,R1(2906) with Γ=29 MeV,R_1(2912) with Γ=10 McV,Rj(2920) with Γ=9 MeV,and R_J(2842) with Γ=24 MeV,originate in the cs■ system.Compared with experimental data,R_0(2914) with Γ=42 MeV may be an optimal X_0(2900) candidate.However,none of the resonances have a similar width for X_1(2900).Hence,further study is required.     

Surface pseudocapacitance of mesoporous Mo3N2 nanowire anode toward reversible high-rate sodium-ion storage

Sodium-ion storage devices are highly desirable for large-scale energy storage applications owing to the wide availability of sodium resources and low cost.Transition metal nitrides(TMNs)are promising anode materials for sodium-ion storage,while their detailed reaction mechanism remains unexplored.Herein,we synthesize the mesoporous Mo3N2 nanowires(Meso-Mo₃N₂-NWs).The sodium-ion storage mechanism of Mo3N2 is systematically investigated through in-situ XRD,ex-situ experimental characterizations and detailed kinetics analysis.Briefly,the Mo₃N₂ undergoes a surface pseudocapacitive redox charge storage process.Benefiting from the rapid surface redox reaction,the Meso-Mo₃N₂-NWs anode delivers high specific capacity(282 m Ah g^-1 at 0.1 A g^-1),excellent rate capability(87 m Ah g^-1 at 16 A g^-1)and long cycling stability(a capacity retention of 78.6%after 800 cycles at 1 A g^-1).The present work highlights that the surface pseudocapacitive sodium-ion storage mechanism enables to overcome the sluggish sodium-ion diffusion process,which opens a new direction to design and synthesize high-rate sodiumion storage materials.     

非理想背光照相对靶壳阿贝尔密度反演的影响

建立了背光照相的模拟手段,研究了记录屏像素尺寸、背光强度分布、背光光谱非单色、针孔弥散及针孔形状对惯性约束聚变中常用塑料球壳的阿贝尔密度反演的影响。结果表明：较大的记录屏像素尺寸会掩盖密度分布的细节;高斯型的背光空间分布会使密度分布低于真实值,可能导致非物理的负密度分布;采用Mo的L带谱线作为背光源也会导致反演密度偏离真实值;当壳层厚度小于针孔尺寸时,针孔弥散效应会显著降低峰值密度,利用维纳滤波法处理背光图像后密度反演的结果得到明显改善;相同针孔面积条件下,椭圆形针孔给出的峰值密度要低于圆形针孔的结果。     

反射率的数值反演

通过分析热流边界条件下的一维热传导过程,提出并实现了由后表面温度变化历史曲线反演前表面反射率变化历史曲线的数值方法。通过一维热传导的正向和反演计算过程,验证了反演程序的可靠性。对数值反演计算和实验测量两种方式得到的反射率曲线进行了对比,结果显示,两条反射率曲线在变化趋势上符合较好,初步验证了一维温度场中数值反演方法的可行性。     

重复频率Nd:YAG薄片激光器的时间特性

为了研究固体激光器弛豫振荡的时间特性,针对高功率大口径Nd:YAG薄片激光器,从工作物质的能级结构和离子跃迁过程出发,采用四能级速率方程模型,综合考虑泵浦速率、损耗因子、温度等因素对激光器起振延迟时间的影响,建立了速率方程组,推导出激光起振延迟时间的数学表达式,模拟分析了泵浦速率、损耗因子、温度对激光起振延迟时间的影响。为验证理论分析结果,在kW级重复频率运行V型腔Nd:YAG薄片激光器上开展了实验研究。在泵浦电流分别为34,40,50,70 A时测量了反应谐振腔内光子数和反转粒子数变化的弛豫振荡曲线。并测量了在泵浦电流为30~80 A情况下的激光器起振延迟时间。实验结果表明起振延迟时间随泵浦速率的增加而减少,与理论分析结果一致。     

哈密顿系统正则变换在时变最优控制中的应用

利用哈密顿系统正则变换和生成函数理论求解线性时变最优控制问题,构造了新的最优控制律形式并提出了控制增益计算的保结构算法. 利用生成函数求解最优控制导出的哈密顿系统两端边值问题,并构造线性时变系统的最优控制律,由第2类生成函数所构造的最优控制律避免了末端时刻出现无穷大反馈增益. 控制系统设计中需求解生成函数满足的时变矩阵微分方程组. 根据生成函数与哈密顿系统状态转移矩阵之间的关系,从正则变换的辛矩阵描述出发,导出了求解这组微分方程组的保结构递推算法.为了保持递推计算中的辛矩阵结构,哈密顿系统状态转移矩阵的计算中利用了Magnus级数.      

Decarboxylative Radical Sulfilimination via Photoredox,Copper, and Brønsted Base Catalysis

Sulfilimines, the aza-variants of sulfoxides, are key structural motifs in natural products, pharmaceuticals, and agrochemicals; and sulfilimine synthesis is therefore important in organic chemistry. However, methods for radical sulfilimination remain elusive, and as a result, the structural diversity of currently available sulfilimines is limited. Herein, we report the first protocol for decarboxylative radical sulfilimination reactions between sulfenamides and N-hydroxyphthalimide esters of primary, secondary, and tertiary alkyl carboxylic acids, which were achieved via a combination of photoredox, copper, and Brønsted base catalysis. This novel protocol provided a wide variety of sulfilimines, in addition to serving as an efficient route for the synthesis of S-alkyl/S-aryl homocysteine sulfilimines and S-(4-methylphenyl) homocysteine sulfoximine. Moreover, it could be used for late-stage introduction of a sulfilimine group into structurally complex molecules, thereby avoiding the need to preserve labile organosulfur moieties through multistep synthetic sequences. A mechanism involving photocatalytic substrate transformation and copper-mediated C(sp³)−S bond formation is proposed.