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81.
82.
83.
The following problem arose in a correspondence between the authors, concerning the exact location of the set of eigenvalues of special real matrices, arising from a problem of synchronization of chaotic oscillators. 相似文献
84.
Mihály Viktor Pilipecz Tamás Róbert Varga Pál Scheiber Zoltán Mucsi Amélie Fàvre-Mourgues Sándor Boros László Balázs Gábor Tóth Péter Nemes 《Tetrahedron》2012,68(27-28):5547-5553
Using different reducing methods unsaturated indolizidine and quinolizidine lactams substituted with a nitro group were transformed into various alkaloid-like derivatives. Hydrogen transfer and palladium catalyzed hydrogenation gave compounds of ketolactam or lactam type meanwhile the nitro group was eliminated. On the other hand, in presence of Raney-nickel catalyst the nitro compounds were reduced to diastereomeric amino derivatives whose stereochemistry was elucidated by NMR spectroscopy. Using sodium bis-dimethoxy-ethoxy-aluminum-hydride (Red-Al) as reducing agent an unexpected tricyclic azetidine was isolated and characterized. 相似文献
85.
Dongmei Jiang Dr. Atsushi Urakawa Dr. Maxim Yulikov Dr. Tamas Mallat Dr. Gunnar Jeschke Prof. Dr. Alfons Baiker Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(45):12255-12262
{Cu(bpy)(H2O)2(BF4)2(bpy)} (Cu‐MOF; MOF=metal–organic framework; bpy=4,4′‐bipyridine), with a 3D‐interpenetrated structure and saturated Cu coordination sites in the framework, possesses unexpectedly high activity in the ring‐opening reaction of epoxides with MeOH, although the reaction rate drops remarkably with more bulky alcohols. This (apparent) size selection and the single Cu2+ sites in an identical environment of the crystalline matrix resemble zeolites. The real nature of active sites was investigated by attenuated total reflection infrared (ATR‐IR), Raman, EPR, and UV/Vis spectroscopies. Cu‐MOF has highly dynamic structural properties that respond to MeOH; its framework dimensions change from 3D to 2D by restructuring to a symmetric coordination of four bpy units to Cu. This interaction is accompanied by the partial dissolution of Cu‐MOF as multi‐Cu clusters, in which Cu2+ ions are connected with bpy ligands. Although both molecular and surface catalysis contribute to the high rate of alcoholysis, the soluble oligomeric species (Cumbpyn) are far more active. Finally, addition of diethyl ether to the reaction mixture induces the reconstruction of dissolved and solid Cu‐MOF to the original framework structure, thereby allowing excellent recyclability of Cu‐MOF as an apparent heterogeneous catalyst. In contrast, the original Cu‐MOF structure is maintained upon contact with larger alcohols, such as iPrOH and tBuOH, thus leading to poor activity in epoxide ring opening. 相似文献
86.
87.
J. Ahrens S. Altieri J. R. M. Annand H. -J. Arends R. Beck A. Braghieri N. d'Hose H. Dutz S. Goertz P. Grabmayr S. Hasegawa E. Heid H. Holvoet L. Van Hoorebeke N. Horikawa T. Iwata O. Jahn P. Jennewein R. Kondratiev J. Krimmer M. Lang B. Lannoy K. Livingston J. C. McGeorge W. Meyer A. Panzeri P. Pedroni T. Pinelli I. Preobrajenski G. Reicherz G. Rosner M. Rost T. Rostomyan D. Ryckbosch M. Schumacher B. Seitz G. Tamas A. Thomas R. van de Vyver Th. Walcher F. Zapadtka 《The European Physical Journal A - Hadrons and Nuclei》2005,26(1):135-140
The G asymmetry of the γp↦Nπ reaction has been measured for the first time for Eγ = 340±14 MeV. This observable, for which very scarce published data exist, plays an important role to disentangle the contributions
of the various nucleon resonances. The experiment, performed at the Mainz microtron MAMI, used a 4π-detector system, a linearly
polarized, tagged photon beam, and a longitudinally polarized proton target. 相似文献
88.
Ion Grosu Lo?c Toupet Gerard Plé Sorin Mager Eugen Mesaros Andreea Varga Elena Bogdan 《Monatshefte für Chemie / Chemical Monthly》2000,54(5):277-286
The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means
of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of
the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in
the spiro skeleton. 相似文献
89.
90.
Structural effects in the chiral base and the influence of some key reaction parameters (catalyst type and solvent) in the Pd-induced enantioselective decarboxylation (cascade reaction) of three different ,-disubstituted benzyl β-ketoesters were explored. The reaction intermediate after debenzylation (β-keto-carboxylic acid) was synthesized and its decarboxylation studied independently. The highest ee (up to 60%) in the cascade reaction was achieved with those substrates that contained an aromatic ring system and with chiral amino alcohols that possessed an extended aromatic ring (quinine and quinidine). Polar solvents with weak H-bond donor and acceptor properties favor enantioselection. 相似文献