全文获取类型
收费全文 | 370篇 |
免费 | 10篇 |
国内免费 | 7篇 |
专业分类
化学 | 271篇 |
晶体学 | 4篇 |
力学 | 12篇 |
综合类 | 1篇 |
数学 | 40篇 |
物理学 | 59篇 |
出版年
2023年 | 2篇 |
2022年 | 28篇 |
2021年 | 13篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 18篇 |
2012年 | 25篇 |
2011年 | 32篇 |
2010年 | 10篇 |
2009年 | 8篇 |
2008年 | 14篇 |
2007年 | 23篇 |
2006年 | 24篇 |
2005年 | 18篇 |
2004年 | 9篇 |
2003年 | 12篇 |
2002年 | 14篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 7篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有387条查询结果,搜索用时 15 毫秒
41.
We establish the existence of infinitely many polynomial progressions in the primes; more precisely, given any integer-valued polynomials P
1, …, P
k
∈ Z[m] in one unknown m with P
1(0) = … = P
k
(0) = 0, and given any ε > 0, we show that there are infinitely many integers x and m, with
1 \leqslant m \leqslant xe1 \leqslant m \leqslant x^\varepsilon, such that x + P
1(m), …, x + P
k
(m) are simultaneously prime. The arguments are based on those in [18], which treated the linear case P
j
= (j − 1)m and ε = 1; the main new features are a localization of the shift parameters (and the attendant Gowers norm objects) to both coarse
and fine scales, the use of PET induction to linearize the polynomial averaging, and some elementary estimates for the number
of points over finite fields in certain algebraic varieties. 相似文献
42.
Yamin Feng Jinghua Chen Xintang Huang Weifeng Liu Yu Zhu Wei Qin Xiaoyuan Mo 《Crystal Research and Technology》2016,51(10):548-553
A dye‐sensitized solar cell (DSSC) based on ZnO/TiO2 composite nanorods (NRs) photoanode is fabricated. The power conversion efficiency (PCE) of the ZnO/TiO2 composite NRs film DSSC is 4.36%, which is obviously higher than that of DSSCs based on pure TiO2 NRs (0.6%) and ZnO NRs (3.10%). The enhanced performance of ZnO/TiO2 composite NRs film DSSC can be attributed to the combined effects of ZnO and TiO2 NRs. In this architecture, the thick ZnO NRs overlayer offers a large surface area for enough dye absorption, while the thin TiO2 NRs underlayer not only offers a direct and quick pathway for photoinjected electron transfer along the photoanode but also acts as a blocking layer, which effectively hinders the direct contact between the substrate and the electrolyte resulting in lower carrier recombination. 相似文献
43.
The paper considers various aspects of statistical quality control by means of sample data received on a ternary ordinal scale. A new method for evaluating quality level and dispersion, free of any latent numerical scale assumptions, is proposed. The emphasis is on working with large samples, which enable the statistical analysis, estimation and control by the use of approximate analytical expressions of these measures to be considerably simplified. Two complementary studies demonstrate the usage of the proposed approach. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
44.
Jannik Brückmann Dr. Carolin Müller Tamar Maisuradze Dr. Alexander K. Mengele Dr. Djawed Nauroozi Sven Fauth Andreas Gruber Prof. Dr. Stefanie Gräfe Prof. Dr. Kerstin Leopold Dr. Stephan Kupfer Prof. Dr. Benjamin Dietzek-Ivanšić Prof. Dr. Sven Rau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(51):e202200766
The synthesis and detailed characterization of a new Ru polypyridine complex containing a heteroditopic bridging ligand with previously unexplored metal-metal distances is presented. Due to the twisted geometry of the novel ligand, the resultant division of the ligand in two distinct subunits leads to steady state as well as excited state properties of the corresponding mononuclear Ru(II) polypyridine complex resembling those of prototype [Ru(bpy)3]2+ (bpy=2,2'-bipyridine). The localization of the initially optically excited and the nature of the long-lived excited states on the Ru-facing ligand spheres is evaluated by resonance Raman and fs-TA spectroscopy, respectively, and supported by DFT and TDDFT calculations. Coordination of a second metal (Zn or Rh) to the available bis-pyrimidyl-like coordination sphere strongly influences the frontier orbitals, apparent by, for example, luminescence quenching. Thus, the new bridging ligand motif offers electronic properties, which can be adjusted by the nature of the second metal center. Using the heterodinuclear Ru−Rh complex, visible light-driven reduction of NAD+ to NADH was achieved, highlighting the potential of this system for photocatalytic applications. 相似文献
45.
Tamar Shamai Yamin Hagit Prihed Moran Madmon Merav Blanca Avi Weissberg 《Journal of mass spectrometry : JMS》2020,55(10)
V‐nerve agents present information‐poor spectra, both in GC‐EI‐MS and LC‐ESI‐MS/MS, with dominant fragments/product ions corresponding to the amine‐containing residue. Hence, derivatives/isomers with the same amine residue exhibit similar mass spectral patterns, leading to ambiguity in the phosphonate structure. We present a simple approach for their structural elucidation based on two complementary experiments: ESI‐MS/MS of the original compound, which provides information about the amine moiety, and ESI‐MS/MS of the phosphonic acid hydrolysis products generated by N‐iodosuccinimide, which provides ions' characteristic of the phosphonate structure. This approach enables the structural elucidation of the original V‐agents with a higher degree of certainty. 相似文献
46.
47.
The usage of ordinal scales (sometimes called ‘semi-quantitative’ scales) for performing measurements in the area of applied
chemical metrology and quality assurance is widespread. This paper presents a method for handling actions such as calibration,
measuring systems’ capabilities comparison and reproducibility evaluation as a comparison between two measuring systems (MSs)
referring to a known/unknown reference standard. The strength of the agreement between these MSs is evaluated through two
known versions of Cohen’s kappa statistics (the traditional one and the modified one). The effectiveness of these statistics
from the metrological point of view is examined, and the preferability of the modified kappa statistics is demonstrated via
an example. 相似文献
48.
Yi L Zhang P Ji X Liang Y Wang Y Zhou Z Chen B 《Chemical & pharmaceutical bulletin》2011,59(7):839-843
The article reports a simple, sensitive and fast LC/MS method for the analysis of L-arginine (L-Arg), asymmetric dimethylarginine (ADMA) and symmetric dimethylarginine (SDMA) in human plasma. The homoarginine was used as the internal standard (IS). The chromatographic separation was achieved on C??(150 mm×2.1 mm, 5 μm) column with a mobile phase consisting of ammonium acetate (0.25 mmol/l) and methanol (93 : 7, v/v), at a flow rate of 0.2 ml/min. L-Arg, ADMA and SDMA were well separated by LC/MS with selective ion mode (SIM). The method was successfully applied to type 2 diabetes mellitus (T2DM) study. Twenty-one healthy controls and twenty-two T2DM patients before and after treatment two years were investigated. The results indicated that the level of ADMA in T2DM was significantly higher than that in healthy controls. Furthermore, ADMA has important association with the development of cardiovascular diseases. 相似文献
49.
We employ a one-electron, tight-binding model of an electrode-molecule-electrode junction to explore the fundamental relationship between adsorption geometry and electron transport, producing exact results (within this model). By varying the chemisorption location (e.g., atop a surface atom or in a hollow site between surface atoms) and the molecule-electrode coupling, we find that the largest currents are realized when the molecule (i) is highly coordinated by the surface and (ii) has favorable overlap with electrode states near the Fermi level. We also show the importance of electrode-induced molecular level shifting for certain adsorption geometries, which can cause molecular levels far from the Fermi level to conduct better than those near the Fermi level. Since all of these factors are greatly influenced by the chemical moiety used to link the molecule to an electrode, these results present a set of guidelines to help choose "alligator clips" for molecular electronic devices. 相似文献
50.
An efficient CO2 adsorbent with a hierarchically micro-mesoporous structure and a large number of amine groups was fabricated by a two-step synthesis technique. Its structural properties, surface groups, thermal stability and CO2 adsorption performance were fully investigated. The analysis results show that the prepared CO2 adsorbent has a specific hierarchically micro-mesoporous structure and highly uniformly dispersed amine groups that are favorable for the adsorption of CO2. At the same time, the CO2 adsorption capacity of the prepared adsorbent can reach a maximum of 3.32 mmol-CO2/g-adsorbent in the actual flue gas temperature range of 303–343 K. In addition, the kinetic analysis results indicate that both the adsorption process and the desorption process have rapid adsorption/desorption rates. Finally, the fitting of the CO2 adsorption/desorption experimental data by Avrami’s fractional kinetic model shows that the CO2 adsorption rate is mainly controlled by the intra-particle diffusion rate, and the temperature has little effect on the adsorption rate. 相似文献