全文获取类型
收费全文 | 1288篇 |
免费 | 98篇 |
国内免费 | 4篇 |
专业分类
化学 | 1148篇 |
晶体学 | 13篇 |
力学 | 16篇 |
数学 | 52篇 |
物理学 | 161篇 |
出版年
2023年 | 16篇 |
2022年 | 20篇 |
2021年 | 27篇 |
2020年 | 30篇 |
2019年 | 25篇 |
2018年 | 34篇 |
2017年 | 19篇 |
2016年 | 53篇 |
2015年 | 41篇 |
2014年 | 67篇 |
2013年 | 72篇 |
2012年 | 106篇 |
2011年 | 150篇 |
2010年 | 69篇 |
2009年 | 64篇 |
2008年 | 92篇 |
2007年 | 70篇 |
2006年 | 70篇 |
2005年 | 53篇 |
2004年 | 52篇 |
2003年 | 46篇 |
2002年 | 35篇 |
2001年 | 16篇 |
2000年 | 9篇 |
1999年 | 7篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 16篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1965年 | 1篇 |
1935年 | 2篇 |
排序方式: 共有1390条查询结果,搜索用时 15 毫秒
41.
Atsuhisa Mimoto Sojiro Kon Takuya Motomura Minoru Inaba 《Journal of fluorine chemistry》2005,126(7):1101-1110
The Ni-based alloys, such as Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si, prepared by hot isostatic pressing (HIP) at 1000 °C under 2 × 108 Pa for 2 h were employed as the anodes for electrolytic production of NF3. The current efficiencies for NF3 formation were 42-38, 52-40, 52-47, 63-62, 50 and 41% for Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si alloys, respectively. The current efficiencies only on Ni-Cu alloys with Cu concentrations lower than 10 mol% were almost the same as those on Ni sheet and HIPed Ni anodes, whereas those on the other alloys used in this study were smaller compared with those on both Ni anodes. On the other hand, the current losses caused by anodic dissolution of Ni-Co, Ni-Mn, Ni-Ag, Ni-Cu, Ni-Al and Ni-Si alloy electrodes were 7.95-4.42, 6.40-7.02, 5.60-6.30, 3.34-6.33, 5.10 and 0.18%, respectively. The anode consumptions of Ni-5 mol% Cu and Ni-5 mol% Si alloys were almost the same or smaller compared with those of Ni sheet and HIPed Ni electrodes, though those of other alloys used were large compared with those of both Ni anodes. Consequently, addition of Cu to the nickel matrix is available for a cheaper cost of anode with keeping a same current efficiency as that on the Ni anode and addition of Si to the nickel matrix is effective for decreasing anode consumption largely. A Ni sheet electrode containing a trace of impurities, such as Co, Mn, Ag and Al, is also favorable as the anode for electrolytic production of NF3. 相似文献
42.
Masaki Shimizu Prof. Dr. Takuya Kurahashi Dr. Katsuhiro Shimono Dr. Kei Tanaka Ikuhiro Nagao Shin‐ichi Kiyomoto Tamejiro Hiyama Prof. Dr. 《化学:亚洲杂志》2007,2(11):1400-1408
Treatment of 1,1‐bis(pinacolatoboryl)ethene with an excess of 1‐bromo‐1‐lithioethene gave 2,3‐bis(pinacolatoboryl)‐1,3‐butadiene in high yield. Palladium‐catalyzed cross‐coupling of the resulting diborylbutadiene with aryl iodides took place smoothly in the presence of a catalytic amount of Pd(OAc)2/PPh3 and aqueous KOH to give 2,3‐diaryl‐1,3‐butadienes in good yields. The coupling reaction with commercially available 4‐acetoxyphenylmethyl chloride under the same conditions followed by hydrolysis of the acetyl groups gave anolignan B in a one‐pot manner. A variety of [3]‐ to [6]dendralenes were synthesized by palladium‐catalyzed coupling of the diene or 1,1‐bis(pinacolato)borylethene with alkenyl or dienyl halides, respectively, in good yields. 相似文献
43.
44.
45.
46.
47.
Takuya Yamano 《Entropy (Basel, Switzerland)》2021,23(3)
An electron in a constant magnetic field has energy levels, known as the Landau levels. One can obtain the corresponding radial wavefunction of free-electron Landau states in cylindrical polar coordinates. However, this system has not been explored so far in terms of an information-theoretical viewpoint. Here, we focus on Fisher information associated with these Landau states specified by the two quantum numbers. Fisher information provides a useful measure of the electronic structure in quantum systems, such as hydrogen-like atoms and under some potentials. By numerically evaluating the generalized Laguerre polynomials in the radial densities, we report that Fisher information increases linearly with the principal quantum number that specifies energy levels, but decreases monotonically with the azimuthal quantum number m. We also present relative Fisher information of the Landau states against the reference density with , which is proportional to the principal quantum number. We compare it with the case when the lowest Landau level state is set as the reference. 相似文献
48.
49.
Yuichi Tominaga Takuya Kubo Kenji Sueyoshi Ken Hosoya Koji Otsuka 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3153-3158
To synthesize the novel molecular‐ and pH‐stimulus‐responsive hydrogel, we prepared poly(ethylene glycol)‐based hydrogel containing ionic groups. We evaluated the fundamental swelling/shrinking properties of the hydrogels synthesized by various conditions. Decreasing the molecular weight of a crosslinker provided the increasing of the equilibrium swelling ratio. Also, the equilibrium swelling ratio was changed by the introduction of functional ionic monomers and its compositions. Furthermore, the swelling/shrinking behaviors of the hydrogels were affected by the environmental condition of aqueous solution, in fact the hydrogels were considerably shrunk (to one‐fifth volume) using a di‐ionic solute in the aqueous solution through the ionic interactions between the hydrogel and the solutes. Additionally, the specific shrinking to diamine compounds was also observed in response to pH change. These results clearly show the swelling/shrinking responsibility of the hydrogels toward the molecular recognitions and its pH conditions. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3153–3158 相似文献
50.
For a spatial characteristic, there exist commonly fat-tail frequency distributions of fragment-size and -mass of glass, areas enclosed by city roads, and pore size/volume in random packings. In order to give a new analytical approach for the distributions, we consider a simple model which constructs a fractal-like hierarchical network based on random divisions of rectangles. The stochastic process makes a Markov chain and corresponds to directional random walks with splitting into four particles. We derive a combinatorial analytical form and its continuous approximation for the distribution of rectangle areas, and numerically show a good fitting with the actual distribution in the averaging behavior of the divisions. 相似文献