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91.
We have investigated the barrier energy for an ammonia molecule to penetrate into ice film by the use of infrared spectroscopy and Xe supersonic beam. After the ice film on a Pt(1 1 1) surface is exposed to ammonia molecules, an umbrella mode of ammonia molecules adsorbed on the ice film has been observed in infrared spectra. After the irradiation of accelerated Xe beam, we observed an energy shift of the mode of ammonia. The shifted mode is assigned to that of ammonia molecules at the interface between the ice film and the Pt(1 1 1) surface. This indicates that the collision with Xe beam induced the penetration of an ammonia molecule to the interface through the ice film. Using this feature, we estimate a barrier for penetration as 0.28 ± 0.03 eV which is much smaller than the one previously reported for bulk ice. 相似文献
92.
93.
We show that the Nomura algebra of the nonsymmetric Hadamard model coincides with the Bose–Mesner algebra of the directed Hadamard graph. 相似文献
94.
Kazuhiro Nagata Daisuke Sano Yu Shimizu Michiko Miyazaki Takuya Kanemitsu Takashi Itoh 《Tetrahedron: Asymmetry》2009,20(21):2530-2536
The catalytic asymmetric alkylation of α-cyanocarboxylates and acetoacetates with an alkyl halide was performed under phase-transfer conditions to afford compounds which have a chiral quaternary carbon with up to 97% and 94% ee, respectively. As applications of this method, chiral 2-oxindole derivatives and a β-lactam derivative were synthesized. 相似文献
95.
96.
97.
Kazuchika Ohta Hiroshi Ema Yasue Morizumi Takuya Watanabe Tetsuya Fujimoto Iwao Yamamoto 《Liquid crystals》1990,8(3):311-330
Two novel types of transition-metal-containing liquid crystals, bis(p-n-koxydithiobenzoato)nickel(II) (abbreviated as (CnO-DTB)2Ni), and (p-n-alkoxydithiobenzoato)(p-n-alkoxyperthiobenzoato)nickel(II) (abbreviated as (CnO-DTB)(CnO-PTB)Ni), were synthesized. It was found that the (CnO-DTB)2Ni complex for n = 8 has smectic H and C mesophases, and that the (CnO-DTB)2Ni complexes for n = 4 and 8 easily transform into the corresponding monoperthio complexes, nO-PTB)Ni, by heating at temperatures between 230°C and 285°C. It was confirmed that the transformation originates from an intermolecular reaction between the (CnO-DTB)2Ni complexes at high temperatures, and that the origin of the extra sulphurs in the resulting (CnO-DTB)(CnO-PTB)Ni complexes is the neighbouring (CnO-DTB)2Ni complexes. Interestingly, each of the (CnO-DTB)(CnO-PTB)Ni complexes (n = 4 and 8), has nematic mesophase and exhibits a unique double melting behaviour via the nematic phase, which is the first example in liquid crystals. The reversible transformation between the blue smectic rod-like (CnO-DTB)2Ni complex and the red nematic Λ-like (CnO-DTB)(CnO-PTB)Ni complex is possible. 相似文献
98.
We show that for any possible Weierstrass gap sequence L on a non-singular curve of genus 8 with twice the smallest positive non-gap is less than the largest gap there exists a pointed
non-singular curve (C, P) over an algebraically closed field of characteristic 0 such that the Weierstrass gap sequence at P is L. Combining this with the result in [6] we see that every possible Weierstrass gap sequence of genus 8 is attained by some
pointed non-singular curve.
*Partially supported by Grant-in-Aid for Scientific Research (17540046), Japan Society for the Promotion of Science.
**Partially supported by Grant-in-Aid for Scientific Research (17540030), Japan Society for the Promotion of Science. 相似文献
99.
Takuya Masuzawa 《International Journal of Game Theory》2008,37(2):185-201
In this paper, we discuss the computational complexity of the strategic cores of a class of n-person games defined by Masuzawa (Int J Game Theory 32:479–483, 2003), which includes economic situations with monotone externality.
We propose an algorithm for finding an α-core strategy of any game in this class which, counting the evaluation of a payoff
for a strategy profile as one step, terminates after O(n
3· M) operations, where M is the maximum size of a strategy set of any of the n players. The idea underlying this method is based on the property of reduced games.
This paper is based on a part of the doctoral dissertation of the author. The author thanks Mikio Nakayama, Masashi Umezawa,
William Thomson, an associate editor, and the anonymous referee for their helpful comments, suggestions, and advice. Thanks
are also due to Yukihiko Funaki for a comment that led the author to this subject. The author is responsible for errors and
inadvertencies. 相似文献
100.
Hiroki Hotta Kazuya Tatsuno Yoji Hattori Takuya Hashimoto Masayuki Uehara Kin-ichi Tsunoda 《Electrochemistry communications》2008,10(9):1351-1354
The H+ concentration change was monitored near an electrode surface through an electrolysis using a slab optical waveguide technique. Indium tin oxide transparent electrode modified by porous insulating polymer to which methyl red was covalently immobilized was used as a guiding layer, and the absorbance change of the polymer film was monitored. H+ generation at the vicinity of the electrode through the oxidation of ascorbic acid could be monitored by this technique. 相似文献